Search results for "ddc:5"
showing 10 items of 1717 documents
Three-dimensional subnanoscale imaging of unit cell doubling due to octahedral tilting and cation modulation in strained perovskite thin films
2019
Determining the three-dimensional (3D) crystallography of a material with subnanometer resolution is essential to understanding strain effects in epitaxial thin films. A scanning transmission electron microscopy imaging technique is demonstrated that visualizes the presence and strength of atomic movements leading to a period doubling of the unit cell along the beam direction, using the intensity in an extra Laue zone ring in the back focal plane recorded using a pixelated detector method. This method is used together with conventional atomic resolution imaging in the plane perpendicular to the beam direction to gain information about the 3D crystal structure in an epitaxial thin film of La…
Forces between colloidal particles in aqueous solutions containing monovalent and multivalent ions
2017
The present article provides an overview of the recent progress in the direct force measurements between individual pairs of colloidal particles in aqueous salt solutions. Results obtained by two different techniques are being highlighted, namely with the atomic force microscope (AFM) and optical tweezers. One finds that the classical theory of Derjaguin, Landau, Verwey, and Overbeek (DLVO) represents an accurate description of the force profiles even in the presence of multivalent ions, typically down to distances of few nanometers. However, the corresponding Hamaker constants and diffuse layer potentials must be extracted from the force profiles. At low salt concentrations, double layer f…
Long-term ISO 23936-2 sweet oil ageing of HNBR
2021
Abstract A hydrogenated nitrile butadiene rubber (HNBR) compound is subjected to ageing in a simulated oil and gas environment in accordance with ISO 23936-2 standard at two elevated temperatures (130 °C and 150 °C) for a period of up to 9 months. Shore D hardness, thermal expansion, dynamic mechanical analysis (DMA), Fourier transform infrared (FTIR) spectroscopy, compression and compression set (CS) measurements are made before and after the chemical exposure. The hardness, modulus at short times, degree of relaxation and CS increases while the coefficient of thermal expansion in HNBR tends to decrease with ageing time and temperature. Temperature is shown to impose a greater effect on th…
Kapitza resistance of laser-annealed surfaces
1984
Our understanding of the phonon processes at the interfaces between two media is still quite rudimentary. Particularly notorious is the helium-solid interface, where the accoustic impedances differ by a large amount. It is well known that the Kapitza resistance, i.e. the thermal boundary resistance between helium and a solid, is usually up to 100 times smaller than predicted by the acoustic theory as formulated by Khalatnikov [1]. However, it was shown by J. WEBER et al. [2] that there was no discrepancy at surfaces of freshly cleaved crystals, i.e. at surfaces of exceptional good quality. Thus it is clear that surface irregularities must be responsible for the anomalous Kapitza resistance.…
Vacuum ultraviolet excitation of the 1.9-eV emission band related to nonbridging oxygen hole centers in silica
2004
Physical review / B 69, 153201 (2004). doi:10.1103/PhysRevB.69.153201
Manipulation of charge transfer and transport in plasmonic-ferroelectric hybrids for photoelectrochemical applications
2016
Utilizing plasmonic nanostructures for efficient and flexible conversion of solar energy into electricity or fuel presents a new paradigm in photovoltaics and photoelectrochemistry research. In a conventional photoelectrochemical cell, consisting of a plasmonic structure in contact with a semiconductor, the type of photoelectrochemical reaction is determined by the band bending at the semiconductor/electrolyte interface. The nature of the reaction is thus hard to tune. Here instead of using a semiconductor, we employed a ferroelectric material, Pb(Zr,Ti)O3 (PZT). By depositing gold nanoparticle arrays and PZT films on ITO substrates, and studying the photocurrent as well as the femtosecond …
Surface acceleration during dry laser cleaning of silicon
1999
We report on measurements of the surface acceleration for the application of dry laser cleaning. For that purpose, industrial silicon samples were irradiated by a frequency-doubled Q-switched Nd:YAG laser. The surface displacement was measured by a heterodyne interferometer and recorded by a digital storage oscilloscope. Several hundreds of shots were averaged to give smooth displacement curves which could be derived numerically. The experiments show that the highest accelerations, which are thought to be responsible for the cleaning, occur on the time scale of the laser pulse. Simple theoretical models are in good agreement with the experimental data. The maximal displacement depends only …
Chemical stability of the magnetic oxide EuO directly on silicon observed by hard x-ray photoemission spectroscopy
2011
We present a detailed study of the electronic structure and chemical state of high-quality stoichiometric EuO and O-rich ${\mathrm{Eu}}_{1}{\mathrm{O}}_{1+x}$ thin films grown directly on silicon without any buffer layer using hard x-ray photoemission spectroscopy (HAXPES). We determine the EuO oxidation state from a consistent quantitative peak analysis of $4f$ valence band and $3d$ core-level spectra. The results prove that nearly ideal, stoichiometric, and homogeneous EuO thin films can be grown on silicon, with a uniform depth distribution of divalent Eu cations. Furthermore, we identify the chemical stability of the EuO/silicon interface from Si $2p$ core-level photoemission. This work…
Simulating permeability reduction by clay mineral nanopores in a tight sandstone by combining computer X-ray microtomography and focussed ion beam sc…
2021
Solid earth 12(1), 1 - 14 (2021). doi:10.5194/se-12-1-2021
Photon assisted-inversion of majority charge carriers in molecular semiconductor-based organic heterojunctions
2021
International audience; Ambipolar molecular materials hold great promises as a building block of next generation highly efficient, less complex and low cost electronics devices. In this endeavor, the present work reports the fabrication of organic heterojunction devices based on halogenated copper Phthalocyanines (CuPc) and lutetium bisphthalocyanine (LuPc2) bilayer, investigates their structural and electrical properties and probes the ambipolar behavior by ammonia sensing. Microstructural analysis of the heterostructure thin films revealed compact and semicrystalline organization, depending on the number of halogen substituents in CuPc. The heterojunction devices reveal a non-linear I(V) …