Search results for "deviation"
showing 10 items of 367 documents
Speciation of chromium in natural waters by micropumping multicommutated light emitting diode photometry.
2007
Abstract A simple and sensitive multicommutated flow procedure, implemented by employing a homemade light emitting diode (LED) based photometer, has been developed for the determination of chromium (VI) and total chromium in water. The flow system comprised a set of four solenoid micro-pumps, which were assembled to work as fluid propelling and as commutating devices. The core of the detection unit comprised a green LED source, a photodiode and a homemade flow cell of 100 mm length and 2 mm inner diameter. The photometric procedure for the speciation of chromium in natural waters was based on the reaction of Cr (VI) with 1,5-diphenylcarbazide. Cr (III) was previously oxidized to Cr (VI) and…
On the Consistent Use of VaR in Portfolio Performance Evaluation: A Cautionary Note
2010
The portfolio performance measures based on the Value-at-Risk (VaR) concept have gained widespread popularity and are often used in empirical studies. Unfortunately, we have noticed that in majority of empirical studies a VaR-based performance measure is used inconsistently. The goal of this paper is, therefore, to emphasize how to consistently use VaR in portfolio performance evaluation. We also elaborate on a simple framework that allows to derive a general formula for a portfolio performance measure which is not limited to the use of VaR-based reward and risk measures, but is valid for all reward and risk measures that satisfy a few plausible properties.
Effect of cobalt doping on the dielectric response of $B_{0.95}Pb_{0.05}TiO_3$ ceramics
2013
Dielectric response of Ba 0.95 Pb 0.05 TiO 3 ceramics doped with 0.1 and 1 wt.% of Co 2 O 3 , synthesized by conven- tional high-temperature method, wa s studied in wide temperature and frequency range. The temperature dependences of the real and the imaginary parts of dielectric permittivity of the ceramics were compared with those of BaTiO 3 and Ba 0.95 Pb 0.05 TiO 3. The addition of Co 3+ ions results in a broadening of dielectric anom- alies related to the transition to p araelectric cubic phase, and the structural transition between the tetragonal and the orthorhombic phases. At low temperatures (125 – 200 K) the dielectric absorp- tion of Co-doped Ba 0.95 Pb 0.05 TiO 3 ceramics was fo…
Calcification is not the Achilles'heel of cold-water corals in an acidifying ocean
2015
Ocean acidification is thought to be a major threat to coral reefs: laboratory evidence and CO2 seep research has shown adverse effects on many coral species, although a few are resilient. There are concerns that cold-water corals are even more vulnerable as they live in areas where aragonite saturation (Omega ara) is lower than in the tropics and is falling rapidly due to CO2 emissions. Here, we provide laboratory evidence that net (gross calcification minus dissolution) and gross calcification rates of three common cold-water corals, Caryophyllia smithii, Dendrophyllia cornigera, and Desmophyllum dianthus, are not affected by pCO2 levels expected for 2100 (pCO2 1058 µatm, Omega ara 1.29),…
Forecasting the pulse
2013
Purpose – The steady increase of data on human behavior collected online holds significant research potential for social scientists. The purpose of this paper is to add a systematic discussion of different online services, their data generating processes, the offline phenomena connected to these data, and by demonstrating, in a proof of concept, a new approach for the detection of extraordinary offline phenomena by the analysis of online data. Design/methodology/approach – To detect traces of extraordinary offline phenomena in online data, the paper determines the normal state of the respective communication environment by measuring the regular dynamics of specific variables in data documen…
Quantitative prediction of gas-phase F19 nuclear magnetic shielding constants
2008
Benchmark calculations of (19)F nuclear magnetic shielding constants are presented for a set of 28 molecules. Near-quantitative accuracy (ca. 2 ppm deviation from experiment) is achieved if (1) electron correlation is adequately treated by employing the coupled-cluster singles and doubles (CCSD) model augmented by a perturbative correction for triple excitations [CCSD(T)], (2) large (uncontracted) basis sets are used, (3) gauge-including atomic orbitals are used to ensure gauge-origin independence, (4) calculations are performed at accurate equilibrium geometries [obtained from CCSD(T)/cc-pVTZ calculations correlating all electrons], and (5) vibrational averaging and temperature corrections…
Scalable and Privacy-Preserving Admission Control for Smart Grids
2015
International audience; Energy demand and production need to be constantly matched in the power grid. The traditional paradigm to continuously adapt the production to the demand is challenged by the increasing penetration of more variable and less predictable energy sources, like solar photovoltaics and wind power. An alternative approach is the so called direct control of some inherently flexible electric loads to shape the demand. Direct control of deferrable loads presents analogies with flow admission control in telecommunication networks: a request for network resources (bandwidth or energy) can be delayed on the basis of the current network status in order to guarantee some performanc…
Video-Based Heartbeat Rate Measuring Method Using Ballistocardiography
2017
International audience; Video-based heartbeat rate measurement is a rapidly growing application in remote health monitoring. Video-based heartbeat rate measuring methods operate mainly by estimating photoplethysmography or ballistocardiography signals. These methods operate by estimating the microscopic color change in the face or by estimating the microscopic rigid motion of the head/facial skin. However, the robustness to motion artifacts caused by illumination variance and motion variance of the subject poses main challenge. We present a video-based heartbeat rate measuring framework to overcome these problems by using the principle of ballistocardiography. In this paper, we proposed a b…
A Robustness Approach to Reliability
2012
Reliability of products is here regarded with respect to failure avoidance rather than probability of failure. To avoid failures, we emphasize variation and suggest some powerful tools for handling failures due to variation. Thus, instead of technical calculation of probabilities from data that usually are too weak for correct results, we emphasize the statistical thinking that puts the designers focus on the critical product functions. Making the design insensitive to unavoidable variation is called robust design and is handled by (i) identification and classification of variation, (ii) design of experiments to find robust solutions, and (iii) statistically based estimations of proper safe…
Influence of Welding Time on Tensile-Shear Strength of Linear Friction Welded Birch (Betula pendula L.) Wood
2015
Linear friction welding of wood is a bonding process applied to wood and during which a stiff bond line is formed by the softening and rehardening of wood components to form a composite material composed mainly of wood fibres embedded in a modified lignin matrix. Unfortunately, the bonds tend to spontaneously delaminate or lose their strength when exposed to moist conditions. Some approaches were previously applied to overcome this problem, but so far a suitable solution has not been found. This paper presents results of applying post-welding thermal modification to reduce the moisture sensitivity of welded wood. The experiments included welding of birch wood, thermal modification under sup…