Search results for "dextrin"

showing 10 items of 297 documents

Liposomes as nonspecific nanocarriers for 5-Fluorouracil in the presence of cyclodextrins

2021

Abstract 5-Fluorouracil (5-FU) is one of anticancer drugs with broad activity. Due to its severe side effects, recent studies concentrate on new ways of directed 5-FU delivery and its release in ill tissue. One of selective carriers could be cyclodextrins and liposomes. The combination of novel methods, leading to formation of inclusion complexes (IC) between host molecule of β-cyclodextrin (β-CD) or 2-hydroxypropyl-β-cyclodextrin (HP-β-CD) and 5-FU guest and its subsequent encapsulation in dipalmitoylphosphatidylcholine (DPPC) liposomes is studied experimentally in the present work. Several methods are applied to proof the encapsulation of the analysed drug and its release over time at 37 …

Release mechanismLiposomeCyclodextrins5-Fluorouraciltechnology industry and agricultureCondensed Matter PhysicsCombinatorial chemistryAtomic and Molecular Physics and OpticsFluorescence spectroscopyElectronic Optical and Magnetic MaterialsNMR spectra databasechemistry.chemical_compoundDifferential scanning calorimetrychemistryDipalmitoylphosphatidylcholineLiposomesMaterials ChemistryProton NMRMoleculelipids (amino acids peptides and proteins)Physical and Theoretical ChemistryNanocarriersSpectroscopyControlled drug deliveryJournal of Molecular Liquids
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Enantioresolution in electrokinetic chromatography-complete filling technique using sulfated gamma-cyclodextrin. Software-free topological anticipati…

2016

Few papers have tried to predict the resolution ability of chiral selectors in capillary electrophoresis for the separation of the enantiomers of chiral compounds. In a previous work, we have used molecular information available on-line to establish enantioresolution levels of basic compounds using highly sulfated β-CD (HS-β-CD) as chiral selector in electrokinetic chromatography-complete filling technique (EKC-CFT). The present study is a continuation of this previous work, introducing some novelties. In this work, the ability of sulfated γ-cyclodextrin (S-γ-CD) as chiral selector in EKC-CFT is modelled for the first time. Thirty-three structurally unrelated cationic and neutral compounds …

Resolution (mass spectrometry)02 engineering and technologyTopology01 natural sciencesBiochemistryAnalytical ChemistryElectrokinetic phenomenaCapillary electrophoresisCationsMoleculeLeast-Squares AnalysisPesticidesTopology (chemistry)Chromatography Micellar Electrokinetic CapillaryChromatographyChemistry010401 analytical chemistryOrganic ChemistryCationic polymerizationDiscriminant AnalysisStereoisomerismGeneral Medicine021001 nanoscience & nanotechnology0104 chemical sciencesPharmaceutical PreparationsAsymmetric carbonIndicators and ReagentsEnantiomer0210 nano-technologySoftwaregamma-CyclodextrinsJournal of Chromatography A
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Silica Materials Containing Cyclodextrin for Pollutant Removal

2018

This chapter reviews the use of cyclodextrin-silica hybrid systems and cyclodextrin-functionalized silica used as adsorbents or filters for the removal of inorganic and organic pollutants from aqueous solutions in solid-phase extraction and adsorption-oriented processes. Actually, there is a need to develop efficient processes for the synthesis and application of multifunctional silica-based materials for pollutant removal by adsorption or filtration, and for sample purification and concentration using solid-phase extraction.

Sample purificationchemistry.chemical_classificationPollutantAqueous solutionCyclodextrinChemistryExtraction (chemistry)02 engineering and technology010402 general chemistry021001 nanoscience & nanotechnology01 natural sciences0104 chemical scienceslaw.inventionAdsorptionChemical engineeringlaw0210 nano-technologyFiltration
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Scopolamine Derivatives as Potential Pharmaceuticals with Calixarene-CyclodextrineNanosponges as Drug Carriers

2017

Tropane alkaloids are molecules with a strong biological activity, which are mainly produced by the members offamily Solanaceae, but also found inother plant families (Convolvulaceae, Brasicaceae, Erythroxylaceae andEuphorbiaceae).1 More than 20 active pharmaceutical substances containingthetropane moiety have been industrially produced and applied as mydriatics, antiemetics, antispasmodics, anesthetics and bronchodilators.Nearly all of them are based on the Scopolamine structure.2 In recent years, several researchers aimed their work to the use of supramolecular systems for the inclusion of organic species, such as complex systems based on cyclodextrines or calixarenes.3They have attracted…

ScopolamineCalixareneCyclodextrinSettore CHIM/06 - Chimica OrganicaSettore BIO/15 - Biologia FarmaceuticaNanosponge
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Acid-base properties and sequestering abilities towards toxic metal ions of cyclodextrin-calixarene co-polymers

Smart materials with stimuli-responsive properties represent an interesting research area considering both their potential applications and the conceptual issues implied. They might be successfully employed in various fields, such as drug carrier/delivery devices to sensors, environment remediation, active packaging [1-2]. In this contest, we have recently synthesized various pH-responsive pre- and post-modified cyclodextrin-calixarene nanosponges (CyCaNSs) with 1,2,3-triazole linker units (ACNSs) able to vary their sequestering abilities towards organic and inorganic compounds. In particular, their adsorption properties were varied changing the molar ratio between the co-monomers, and the …

Settore CHIM/01 - Chimica AnaliticaSettore CHIM/06 - Chimica Organicasequestering abilities cyclodextrin calixarene copolymers
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Complexes of amphiphilic cyclodextrins and tributiltin(IV) porphyrin derivatives as potential nanotherapeutics against melanoma.

2013

Settore CHIM/03 - Chimica Generale E Inorganicamelanoma cyclodextrins trybutyltin porphyrin
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Porphyrin tributyltin(IV) complexes for a novel approach in the tratment of human melanoma

2012

Melanoma is the most deadly form of skin cancer, largely refractory to existing therapies. The study of porphyrin derivatives as potential anti-tumor drugs has been an interesting field of investigation in the last years. Recently, a photo-independent cytotoxic effect of (Bu3Sn)4TPPS in the blocking melanoma cell proliferation an inducing a morphology cell change was investigated.[1] Amphiphilic CD (ACyD) provides more water soluble and adaptable nanovectors through modulation of the balance between hydrophobic and hydrophilic chains at both CD sides. ACyD can be conveniently tailored by covalently appending fluorescent label or receptor-targeting glycosyl- groups and can encapsulate conven…

Settore CHIM/03 - Chimica Generale E Inorganicameso-Tetra(4-sulfonatophenyl)porphine anphiphylic cyclodextrins melanoma
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As the change in ternary agent structure influence the chiral recognition ability of pyrene/heptakis-(6-amino)-(6-deoxy)-b-cyclodextrin

Settore CHIM/06 - Chimica OrganicaCyclodextrin fullerene
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Polarimetry as a useful tool for the study of binding equilibria between cyclodextrins and some suitably sized and structured organic molecules

Settore CHIM/06 - Chimica OrganicaCyclodextrin host-guest complexes polarimetry
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Polarimetric study of binding equilibria between cyclodextrins and some suitable organic guests

Settore CHIM/06 - Chimica OrganicaCyclodextrins host-guest complexes polarimetry
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