Search results for "elastic neutron scattering"
showing 10 items of 103 documents
Inelastic neutron and low-frequency Raman scattering in a niobium-phosphate glass for Raman gain applications
2011
Abstract We present measurements of the vibrational spectrum of a binary niobium-phosphate glass in the THz frequency range using inelastic neutron and Raman scattering. The spectra of these glasses show a low-frequency enhancement of the vibrational density of states (“boson peak”). Using a recently developed theory of vibrational excitations in disordered solids we are able to reconcile the measured neutron and Raman spectra using fluctuating elastic and Pockels constants as a model concept. As the spontaneous Raman susceptibility is a key parameter for Raman amplification our results suggest a significant gain profile for application of niobium-phosphate glasses in Raman amplifiers.
Inelastic neutron scattering measurements on Nd2Fe14B and Y2Fe14B single crystals
1992
Abstract Inelastic neutron scattering measurements have been carried out on Nd 2 Fe 14 B and Y 2 Fe 14 B single crystals. Temperature dependent acoustic magnon dispersion curves have been found along the high-symmetry directions [0,0,1] and [1,0,0] with a gap at (0,0,2). Soft mode behaviour at spin wave vector q = 0 was observed for Nd 2 Fe 14 B near the spin reorientation temperature. The inelastic scattering intensity decreases steeply for larger q . Therefore, the dispersion curves could be measured until the middle of the Brillouin zone only. The experimental results are discussed in the frame of a classical spin wave model.
Protein and solvent dynamics of the water-soluble chlorophyll-binding protein (WSCP)
2015
This study presents quasielastic neutron scattering data of the water-soluble chlorophyll-binding protein (WSCP) and the corresponding buffer solution at room temperature. The contributions of protein and buffer solution to the overall scattering are carefully separated. Otherwise, the fast water dynamics dominating the buffer contribution is likely to mask the slow protein dynamics. In the case of WSCP, the protein scattering can be described by two contributions: i) internal protein dynamics represented by a diffusion in a sphere with an average radius of 2.7 u A and ii) global (Brownian) diffusion of the WSCP macromolecule with an upper limit for the translational diffusion coefficient o…
Transport of Mobile Particles in an Immobile Environment: Computer Simulations of Sodium Silicates
2007
Molecular dynamics (MD) simulations of various sodium silicate melts, (Na2O)x(SiO2) with x=2, 3, 20, are presented. In these systems, the mobility of sodium ions is much higher, often by orders of magnitude, than that of the silicon and oxygen atoms forming a tetrahedral network structure. We show that the high mobility of sodium is intimately related to the chemical ordering in sodium silicates. A network of percolating sodium-rich channels is formed in the static structure that serve as diffusion channels for the sodium ions. This channel network is revealed in static structure factors by a prepeak at the wavenumber q=0.95 A-1. Inelastic neutron scattering experiments of sodium silicate m…
Surface Self-Diffusion and Mean Displacement of Hydrogen on Graphite and a PEM Fuel Cell Catalyst Support
2009
International audience; Quasielastic neutron scattering (QENS) measurements together with equilibrium molecular dynamic (EMD) simulations have been performed to investigate the surface interaction between hydrogen molecules and a carbon material commonly used in polymer electrolyte membrane fuel cells (PEMFC), called XC-72. Half a monolayer of molecular hydrogen was adsorbed on to the carbon material at 2 K. QENS spectra were recorded at the time-of-flight spectrometer IN5 at 40, 45, 50, 60, 70, 80, and 90 K. Simultaneously the pressure was measured as a function of time to monitor the equilibrium surface coverage at each temperature. By using the Chudley and Elliott model for jump diffusio…
Ferroelastic transition in Kbr:Kcn studied by neutrons, x-rays and ultrasonic
1986
The ferroelastic phase transition of (KBr) 0 27 (KNC) 0.73 has been studied by X-ray diffraction, ultrasonics and inelastic neutron scattering. It is the first example of a cubic crystal where the elastic shear constant C 44 softens completely corresponding to the m = 2 universality class. C 44 and the Bragg intensities show a non-classical critical behaviour.
A Switchable Molecular Rotator: Neutron Spectroscopy Study on a Polymeric Spin-Crossover Compound
2012
A quasielastic neutron scattering and solid-state 2H NMR spectroscopy study of the polymeric spin-crossover compound {Fe(pyrazine)[Pt(CN) 4]} shows that the switching of the rotation of a molecular fragment-the pyrazine ligand-occurs in association with the change of spin state. The rotation switching was examined on a wide time scale (10 -13-10 -3 s) by both techniques, which clearly demonstrated the combination between molecular rotation and spin-crossover transition under external stimuli (temperature and chemical). The pyrazine rings are seen to perform a 4-fold jump motion about the coordinating nitrogen axis in the high-spin state. In the low-spin state, however, the motion is suppres…
Antiferromagnetism and the node structure of the superconducting order parameter of UPd Al
2000
The node structure of the superconducting order parameter of the heavy-fermion system is analyzed within the weak-coupling theory. A pairing interaction induced by the exchange of antiferromagnetic spin excitations is assumed as suggested by recent inelastic neutron scattering experiments and tunneling spectroscopy. The multi-sheeted Fermi surface is taken into account. Based on a model susceptibility for the simple antiferromagnetic structure of , line nodes result at the rim of the magnetic Brillouin zone.
Superconductivity mediated by spin fluctuations in the heavy-fermion compound UPd2 Al3
1999
It is well known that any weak attractive electron–electron interaction in metals can in principle cause the formation of Cooper pairs, which then condense into a superconducting ground state1. In conventional superconductors, this attractive interaction is mediated by lattice vibrations (phonons). But for the heavy-fermion and high-temperature superconductors, alternative pairing interactions are considered to be possible2. For example, the low-temperature properties of heavy-fermion systems are dominated by antiferromagnetic spin fluctuations, which have been considered theoretically3 as a possible cause for Cooper-pair formation. This picture recently received some experimental support: …
Magnetic clusters from polyoxometalate complexes
1999
Abstract The present article highlights the increasing interest of polyoxometalates in molecular magnetism, providing at the same time a perspective of the state-of-the-art in this area. The main focus is the polyoxotungstates. The first aspect we discuss is that of the coordination chemistry of these metal–oxide ligands. We show that this chemistry leads to remarkable examples of well-insulated magnetic clusters of controlled nuclearity and topology. In these clusters detailed information on the nature of the magnetic exchange interactions can be extracted by using, in addition to the classical magnetic techniques (magnetic susceptibility, magnetization and EPR spectroscopy), other physica…