Search results for "electrodes"
showing 10 items of 231 documents
Soil ionization of earth electrodes under high pulse transient currents
2007
This paper proposes a numerical model of soil ionization phenomena that can occur when earth electrodes are injected by high pulse transient currents. The model is solved by a finite difference time domain numerical scheme. It has been developed from a thorough analysis of the available studies in technical literature about the peculiar physical dynamics of soil ionization phenomena. As already underlined, soil ionization can occur, for example, when the earth electrode has to drain a lightning current into the soil. In this case, the electric field can overcome the electrical strength and conductive plasma paths can locally grow. The dimension of these ionized air channels are strictly dep…
Safety Concerns on Ground Fault Application Transfer Phenomenon in HV Installations
2007
When a fault to ground occurs in HV/MV substations supplied by a combined overhead-cable line, most of the fault current can be transferred and injected into the soil several kilometers far away from the fault location. This phenomenon is called "fault application transfer" and mostly concerns transition stations, where cables are connected to the overhead line. If the transition station is a dead-end steel pole structure, usually accessible to the general public, the local ground electrode could be inadequate to maintain ground potential rise within safety limits. Hence, dangerous touch and step voltages may appear at exposed locations. In the paper results of various computer simulations …
Results of the research on global earthing systems: A contribution to the problem of their identification
2013
The paper presents a study on the factors that can have influence on the rise of a Global Earthing System. The first part of the work deals with: - the definition of proximity, interconnection and quasi-equipotential; - the influence of the presence of HV/MV stations on the dangerous voltages and on the permissible voltage limits; - the dependence of the hazardous condition for persons on the different kind of fault; - the effects on safety of the coexistence of HV, MV and LV systems. In the second part, starting from the discussion on the themes above-mentioned and on the results of the studies, measurement campaigns and simulations on interconnected earthing systems done in the last fifte…
Earthing System's Design in presence of non-uniform soil
2007
The Authors propose a practical approach for facing the problem of the design of the earthing systems in two-layer soils. The approach is based on the calculation of an equivalent resistivity of the non-uniform soil through which the designer can treat this one as it was uniform. The purpose of the Authors is to provide an innovative simple method and some easy-to-use graphs for an easy earthing systems’ design in two-layer soils.
Electron transfer mechanism in Shewanella loihica PV-4 biofilms formed at graphite electrode
2012
Abstract Electron transfer mechanisms in Shewanella loihica PV-4 viable biofilms formed at graphite electrodes were investigated in potentiostat-controlled electrochemical cells poised at oxidative potentials (0.2 V vs. Ag/AgCl). Chronoamperometry (CA) showed a repeatable biofilm growth of S. loihica PV-4 on graphite electrode. CA, cyclic voltammetry (CV) and its first derivative shows that both direct electron transfer (DET) mediated electron transfer (MET) mechanism contributes to the overall anodic (oxidation) current. The maximum anodic current density recorded on graphite was 90 μA cm − 2 . Fluorescence emission spectra shows increased concentration of quinone derivatives and riboflavi…
TCO/Ag/TCO transparent electrodes for solar cells application
2014
Among transparent electrodes, transparent conductive oxides (TCO)/metal/TCO structures can achieve optical and electrical performances comparable to, or better than, single TCO layers and very thin metallic films. In this work, we report on thin multilayers based on aluminum zinc oxide (AZO), indium tin oxide (ITO) and Ag deposited by RF magnetron sputtering on soda lime glass at room temperature. The TCO/Ag/TCO structures with thicknesses of about 50/10/50 nm were deposited with all combinations of AZO and ITO as top and bottom layers. While the electrical conductivity is dominated by the Ag intralayer irrespective of the TCO nature, the optical transmissions show a dependence on the natur…
Source localization of event-related potentials to pitch change mapped onto age-appropriate MRIs at 6 months-of-age
2010
Auditory event-related potentials (ERPs) have been used to understand how the brain processes auditory input, and to track developmental change in sensory systems. Localizing ERP generators can provide invaluable insights into how and where auditory information is processed. However, age-appropriate infant brain templates have not been available to aid such developmental mapping. In this study, auditory change detection responses of brain ERPs were examined in 6-month-old infants using discrete and distributed source localization methods mapped onto age-appropriate magnetic resonance images. Infants received a passive oddball paradigm using fast-rate non-linguistic auditory stimuli (tone do…
Sub-threshold signal processing in arrays of non-identical nanostructures
2011
Weak input signals are routinely processed by molecular-scaled biological networks composed of non-identical units that operate correctly in a noisy environment. In order to show that artificial nanostructures can mimic this behavior, we explore theoretically noise-assisted signal processing in arrays of metallic nanoparticles functionalized with organic ligands that act as tunneling junctions connecting the nanoparticle to the external electrodes. The electronic transfer through the nanostructure is based on the Coulomb blockade and tunneling effects. Because of the fabrication uncertainties, these nanostructures are expected to show a high variability in their physical characteristics and…
Electronic structure and energy decomposition analyses as a tool to interpret the redox potential ranking of naphtho-, biphenyl- and biphenylenequino…
2016
By calling on modelling approaches we have performed a comparative study on the redox properties of various naphtho-, biphenyl- and biphenylene-quinone isomers. These different compounds exhibit as a whole a redox potential range between 2.09 and 2.90 V vs. Li+/Li. A specific methodology was used to decrypt the interplay among isomerism, aromaticity and antiaromaticity modifications and the stabilization/destabilization effects due to other molecular components on this key electrochemical feature for electrode materials of batteries. In particular, energy decomposition analysis, within the Quantum Theory of Atoms in Molecules, along with the electron and electron spin population changes upo…
Electrochemical impedance spectroscopy of polyelectrolyte multilayer modified gold electrodes: influence of supporting electrolyte and temperature.
2005
Electrochemical impedance spectroscopy and cyclic voltammetry are employed to characterize poly(styrenesulfonate)/poly(allylamine hydrochloride) multilayers assembled onto cysteamine-modified gold surfaces. The influence of the supporting electrolyte and temperature on the impedance response is studied because of both its practical interest and the need to test further the capillary membrane model recently developed by Barreira et al. [J. Phys. Chem. B 2004, 108, 17973]. The results obtained are interpreted quite satisfactorily in terms of this model, thus providing additional support to its usefulness for the description of ionic transport through polyelectrolyte multilayers. It is observe…