Search results for "electromagnetic"
showing 10 items of 1595 documents
X-ray irradiation influence on prototype Er3+-optical fibers: confocal luminescence study
2010
International audience; The integration of rare-earth doped optical fibers as part of fiber-based systems in space implies the development of waveguides tolerant to the radiation levels associated with the space missions. We report the spatial distribution, the photoluminescence (PL) properties of color centers and the related changes induced by X-rays radiation at different doses (50, 500 and 1000 krad) for two different prototypes of Er-doped optical fibers. Each sample (in the version pristine, X-irradiated and H2 loaded prior to radiation exposure) was characterized by confocal microscopy luminescence (CML) measurements in Visible range with Visible (488 nm) or UV (325 nm) laser light e…
Excitation and characterization of dielectric-loaded surface plasmon-polariton waveguides at telecommunication wavelengths - art. no. 69880T
2008
International audience; The excitation of surface plasmon-polariton (SPP) waveguide modes in 500-nm-wide and 550-nm-high dielectric ridges deposited on a thin gold film is characterized at telecommunication wavelengths, by application of a scanning near-field optical microscope (SNOM), and by utilizing the finite element method (FEM). Different tapering structures for coupling in SPPs, excited at the bare gold-air interface, are investigated with a SNOM, and the dependence of in coupling efficiency on tapering length is characterized by means of FEM calculations. The performance of this in coupling method is compared to an alternative excitation scheme, where the effective index of SPPs in …
Spectroscopic studies of the origin of the radiation-induced degradation in phosphorous-doped optical fiber and preforms
2010
In this paper, we study the radiation-induced point defects related to the phosphorus element that is commonly used to improve the optical properties of silica-based glasses but is responsible of a dramatic increase in their radiation sensitivity. To this aim, the influence of x-ray irradiation on prototype phosphorus-doped canonical fibers and their related preforms was investigated by in situ radiation induced attenuation (RIA), optical absorption, and electron spin resonance (ESR) spectroscopy. The RIA spectra in the (1.5-5 eV) range, can be explained by the presence of at least three absorption bands induced by radiation exposure. Additionally the X-dose dependence of such bands was stu…
Effect of irradiation temperature on the radiation induced attenuation of Ge-doped fibers
2016
International audience; The UV-visible radiation induced attenuation (RIA) was studied in Ge-doped optical fibers, during X-ray (10 keV) irradiations at different temperatures. By comparing the spectra recorded in dissimilarly irradiated samples we evidenced the impact of the irradiation temperature. In details, we highlighted that, from a certain dose, increasing the temperature the RIA decreases for wavelengths lower than 470 nm, whereas at higher wavelengths the RIA depends only on the dose. Such findings suggest that it is possible to distinguish the irradiation temperature by comparing the signal at two different wavelengths. From the microscopic point of view, it appears that the RIA …
Charge-transfer driven by ultrafast spin-transition in a CoFe Prussian blue analogue
2020
Photoinduced charge-transfer is an important process in nature and technology and is responsible for the emergence of exotic functionalities, such as magnetic order for cyanide-bridged bimetallic coordination networks. Despite its broad interest and intensive developments in chemistry and material sciences, the atomic-scale description of the initial photoinduced process, which couples intermetallic charge-transfer and spin transition, has been debated for decades; it has been beyond reach due to its extreme speed. Here we study this process in a prototype cyanide-bridged CoFe system by femtosecond X-ray and optical absorption spectroscopies, enabling the disentanglement of ultrafast electr…
Modelling the optical properties of fresh biomass burning aerosol produced in a smoke chamber: results from the EFEU campaign
2007
A better characterisation of the optical properties of biomass burning aerosol as a function of the burning conditions is required in order to quantify their effects on climate and atmospheric chemistry. Controlled laboratory combustion experiments with different fuel types were carried out at the combustion facility of the Max Planck Institute for Chemistry (Mainz, Germany) as part of the "Impact of Vegetation Fires on the Composition and Circulation of the Atmosphere" (EFEU) project. The combustion conditions were monitored with concomitant CO<sub>2</sub> and CO measurements. The mass scattering efficiencies of 8.9&plusmn;0.2 m<sup>2</sup> g<sup>…
Redshifted Cherenkov Radiation for in vivo Imaging: Coupling Cherenkov Radiation Energy Transfer to multiple Förster Resonance Energy Transfers
2017
AbstractCherenkov Radiation (CR), this blue glow seen in nuclear reactors, is an optical light originating from energetic β-emitter radionuclides. CR emitter 90Y triggers a cascade of energy transfers in the presence of a mixed population of fluorophores (which each other match their respective absorption and emission maxima): Cherenkov Radiation Energy Transfer (CRET) first, followed by multiple Förster Resonance Energy transfers (FRET): CRET ratios were calculated to give a rough estimate of the transfer efficiency. While CR is blue-weighted (300–500 nm), such cascades of Energy Transfers allowed to get a) fluorescence emission up to 710 nm, which is beyond the main CR window and within t…
On the Schwarzschild Effect in 3D Two‐Photon Laser Lithography
2019
International audience; The two‐photon Schwarzschild effect in photoresists suitable for 3D laser lithography is revisited. The study ranges over seven orders of magnitude in exposure time (from 1 µs to 10 s) and investigates a wide variety of different photoresist compositions. For short exposure times (“regime I”), the laser power at the polymerization threshold can scale with the inverse square root of the exposure time, as naively to be expected for two‐photon absorption. Substantial deviations occur, however, for low photoinitiator concentrations. For intermediate exposure times (“regime II”), a Schwarzschild‐type of behavior is found, as discussed previously. For very long exposure ti…
Optical force rectifiers based on PT-symmetric metasurfaces
2018
We introduce here the concept of optical force rectifier based on parity-time symmetric metasurfaces. Directly linked to the properties of non-Hermitian systems engineered by balanced loss and gain constituents, we show that light can exert asymmetric pulling or pushing forces on metasurfaces depending on the direction of the impinging light. This generates a complete force rectification in the vicinity of the exceptional point. Our findings have the potential to spark the design of applications in optical manipulation where the forces, strictly speaking, act unidirectionally. R.A. and B.G. would like to acknowledge financial support from the Max Planck Society. J.C. acknowledges the suppor…
A critical size for emergence of nonbulk electronic and geometric structures in dodecanethiolate-protected Au clusters.
2014
We report on how the transition from the bulk structure to the cluster-specific structure occurs in n-dodecanethiolate-protected gold clusters, Au(n)(SC12)m. To elucidate this transition, we isolated a series of Au(n)(SC12)m in the n range from 38 to ∼520, containing five newly identified or newly isolated clusters, Au104(SC12)45, Au(∼226)(SC12)(∼76), Au(∼253)(SC12)(∼90), Au(∼356)(SC12)(∼112), and Au(∼520)(SC12)(∼130), using reverse-phase high-performance liquid chromatography. Low-temperature optical absorption spectroscopy, powder X-ray diffractometry, and density functional theory (DFT) calculations revealed that the Au cores of Au144(SC12)60 and smaller clusters have molecular-like elec…