Search results for "electron"
showing 10 items of 24810 documents
Copper Induces a Core Plasmon in Intermetallic Au(144,145)–xCux(SR)60 Nanoclusters
2015
The electronic structure and optical absorption spectra of intermetallic thiol-stabilized gold-copper clusters, having 144-145 metal atoms and 60 thiols, were studied by ab initio computations. The widely known icosahedral-based cluster model from the work of Lopez-Acevedo et al. (2009) was used, and clusters doped with one to 30 copper atoms were considered. When doped inside the metal core, copper induces dramatic changes in the optical spectrum as compared to the previously studied all-gold Au144(SR)60. An intense broad absorption peak develops in the range 535-587 nm depending on the amount of doping and doping sites. This result agrees very well with recent experiments by the Dass grou…
Single Crystal Sub‐Nanometer Sized Cu6(SR)6 Clusters: Structure, Photophysical Properties, and Electrochemical Sensing
2016
Organic ligand-protected metal nanoclusters have attracted extensively attention owing to their atomically precise composition, determined atom-packing structure and the fascinating properties and promising applications. To date, most research has been focused on thiol-stabilized gold and silver nanoclusters and their single crystal structures. Here the single crystal copper nanocluster species (Cu6(SC7H4NO)6) determined by X-ray crystallography and mass spectrometry is presented. The hexanuclear copper core is a distorted octahedron surrounded by six mercaptobenzoxazole ligands as protecting units through a simple bridging bonding motif. Density functional theory (DFT) calculations provide…
Optical Absorption of Excimer Laser‐Induced Dichlorine Monoxide in Silica Glass and Excitation of Singlet Oxygen Luminescence by Energy Transfer from…
2021
An optical absorption (OA) band of interstitial dichlorine monoxide molecules with peak at 4.7 eV and halfwidth 0.94 eV is identified in F2 laser - irradiated (photon energy=7.9 eV) synthetic silica glass bearing both interstitial O2 and Cl2 molecules. Alongside with intrinsic defects, this OA band can contribute to solarization of silica glasses produced from SiCl4. While the formation of ClClO is confirmed by its Raman signature, its structural isomer ClOCl may also contribute to this induced OA band. Thermal destruction of this band between 300C and 400C almost completely restores the pre-irradiation concentration of interstitial Cl2. An additional weak OA band at 3.5 eV is tentatively a…
Etude spectroscopique de fibres durcies pour un environnement radiatif sévère
2013
Les nouveaux environnements radiatifs, comme LMJ, ITER, ILE/ELI, HiPER, réacteurs nucléaires des générations III+ et IV, nécessitent le développement de nouveaux composants pour le transport et le traitement des signaux. A cause de l’impossibilité d’utiliser les composants électroniques, la recherche est orientée vers les composants à fibres optiques comme vecteur d’information et aussi comme élément de diagnostic. Ils présentent de nombreux avantages, comme leur relative immunité électromagnétique, faible pois, large bande passante, mais les rayonnements gamma et les neutrons dégradent leur transmission. La dégradation dépend principalement de la composition de la fibre. Ainsi, il a été mo…
Radioluminescence Response of Ce-, Cu-, and Gd-Doped Silica Glasses for Dosimetry of Pulsed Electron Beams
2021
Radiation-induced emission of doped sol-gel silica glass samples was investigated under a pulsed 20-MeV electron beam. The studied samples were drawn rods doped with cerium, copper, or gadolinium ions, which were connected to multimode pure-silica core fibers to transport the induced luminescence from the irradiation area to a signal readout system. The luminescence pulses in the samples induced by the electron bunches were studied as a function of deposited dose per electron bunch. All the investigated samples were found to have a linear response in terms of luminescence as a function of electron bunch sizes between 10−5 Gy/bunch and 1.5×10−2 Gy/bunch. The presented results show that these…
O2-Loading Treatment of Ge-Doped Silica Fibers: A Radiation Hardening Process
2016
International audience; The effects of a high-pressure O2-loading treatment on the radiation response of Ge-doped optical fibers (OFs) were investigated. We found that the incorporation of high concentration of interstitial molecular oxygen remarkably enhances the resistance to ionizing radiation of Ge-doped OFs in the UV-Visible domain and, at the same time, improves the transmission of UV light in the unirradiated OF sample. By comparison with previously reported results, the O2-loading treatment turned out to increase the radiation resistance of Ge-doped OFs more efficiently than F or Ce codoping. The understanding of such amelioration relies in basic radiation-induced mechanisms that we…
Optical properties and photosensitivity of vacuum synthesized Ge-doped sol-gel amorphous SiO/sub 2/
2005
We report optical and electron paramagnetic resonance investigations of gamma ray irradiation effects in sol-gel Ge-doped amorphous SiO/sub 2/. The studied materials have Ge-doping levels up to 10/sup 4/ molar part per million and were densified by two routes differing for the atmosphere: O/sub 2/+N/sub 2/ or vacuum. The obtained results evidence that irradiation affects matrix sites inducing paramagnetic defects. Furthermore, the comparison between the two densification procedures shows that vacuum atmosphere induces higher radiation sensitivity.
Radiation Response of Ce-Codoped Germanosilicate and Phosphosilicate Optical Fibers
2016
We report an experimental investigation on the effects of Ce-codoping in determining the radiation response of germanosilicate and phosphosilicate Optical Fibers (OFs) in the UV-Visible domain and up to doses of $1~\hbox{MGy}({\rm SiO}_{2})$ . We show that the addition of Ce strongly impacts the Radiation Induced Attenuation (RIA) of both types of fibers. In the first case the radiation induced losses increase, whereas in the second one decrease. By combining the online RIA measurements with the Electron Paramagnetic Resonance (EPR) ones, we are able to infer the basic microscopic mechanisms taking place under irradiation, which involve the cerium codopant and some of the known Ge-related o…
On-Line Characterization of Gamma Radiation Effects on Single-Ended Raman Based Distributed Fiber Optic Sensor
2016
We report distributed temperature measurements based on Raman scattering performed during steady state $\gamma $ -ray irradiation at a dose rate of 1 kGy( ${\rm SiO}_{2}$ )/h and up to a total ionizing dose (TID) of $\sim 0.1\ \hbox{MGy}$ . We characterize on-line the evolution of the performances of a single-ended Raman distributed temperature sensor (RDTS) during the $\gamma $ -ray exposure of different classes of commercial multimode fibers (MMFs) acting as the sensing element. RDTS is influenced by the radiation-induced attenuation (RIA) phenomena leading to both large errors in the temperature measurements and a diminution of the useful sensing length. The amplitude of the radiation-in…
Temporal spying and concealing process in fibre-optic data transmission systems through polarization bypass
2014
Recent research has been focused on the ability to manipulate a light beam in such a way to hide, namely to cloak, an event over a finite time or localization in space. The main idea is to create a hole or a gap in the spatial or time domain so as to allow for an object or data to be kept hidden for a while and then to be restored. By enlarging the field of applications of this concept to telecommunications, researchers have recently reported the possibility to hide transmitted data in an optical fibre. Here we report the first experimental demonstration of perpetual temporal spying and blinding process of optical data in fibre-optic transmission line based on polarization bypass. We succes…