Search results for "element"
showing 10 items of 13601 documents
Total oxidation of propane using nanocrystalline cobalt oxide and supported cobalt oxide catalysts
2008
Abstract Supported and unsupported nanocrystalline cobalt oxides have been shown to be extremely efficient catalysts for the total oxidation of propane. Total conversion with a high stability has been achieved at reaction temperatures as low as 250 °C. In the present work, a comparison between the catalytic performance of bulk and alumina-supported nanocrystalline cobalt oxide catalysts has been made. The influence of crystallite size, nature of the support (alpha, gamma and mesoporous alumina) and cobalt loading, has been probed. Unsupported cobalt oxide catalysts were more active than any supported cobalt oxide catalysts. The catalytic activity was mainly dependent on the crystallite size…
Optimized bath for electroless deposition of palladium on amorphous alumina membranes
2006
A new bath for the electroless deposition of palladium on anodic alumina (AA) membranes is proposed. It was found that the optimal conditions for the uniform deposition of palladium, with minimal damage to the AA membranes, were under conditions of pH 8.4 and plating times shorter than 30 min. The deposited Pd layer was detected by X-ray diffraction (XRD) and energy dispersive X-ray (EDX) analysis. The morphology of the AA membrane before and after plating was examined by scanning electron microscopy (SEM). EDX analysis revealed that palladium was deposited only on the surfaces of the membrane and Sn ions, coming from the sensitizing bath, were incorporated into the palladium layer. EDTA in…
Calcium silicate hydrates: Solid and liquid phase composition
2015
© 2015 Elsevier Ltd. This paper presents a review on the relationship between the composition the structure and the solution in which calcium silicate hydrate (C S H) is equilibrated. The silica chain length in C S H increases with the silicon concentration and the calcium content in the interlayer space with the calcium concentrations. Sodium and potassium are taken up in the interlayer space preferentially at low calcium concentrations and thus by low Ca/Si C S H. Aluminium uptake in C S H increases strongly at higher aluminium concentrations in the solution. At low Ca/Si aluminium substitutes silica in the bridging position at Ca/Si. > 1 aluminium is bound in TAH. Recently developed ther…
Accelerated Light-Induced Defect Transformation Study of Elkem Solar Grade Silicon
2012
AbstractSolar cells made of silicon feedstock from a metallurgical route must qualify not only the initial efficiency, but must also be comparable to the solar cells made from reference polysilicon on the spectral response after light induced degradation. A detailed comparative study of light induced defects and its impact on cell performance is necessary for both materials. We have studied accelerated light induced degradation (ALID) defect transformation for Elkem Solar Silicon and polysilicon solar cells by selecting wafers from different positions from respective silicon bricks. Active boron-oxygen complexes and iron ions in multicrystalline silicon solar cells have been analyzed, and t…
Determination of the Boron/Lead Ratio in Ceramic Materials Based on Electrochemical Quartz Crystal Microbalance
2004
A method for quantitatively determining the relationship boron/lead in ceramic materials is presented. It is based on the attachment of microsamples of ceramic frits to an electrochemical quartz crystal microbalance (EQCM). After a reductive deposition step in the � 0.25 to � 0.85 V (vs. AgCl/Ag) potential range, well-defined stripping peaks are recorded in 0.10 M NaCl plus 0.10 M mannitol. The deposition of boron and lead from suspensions of solid materials, and its subsequent oxidative dissolution can be monitorized at the EQCM. The quotient between the maximum mass gain and the corresponding charge passed enables for a direct quantitation of the boron/lead molar ratio in ceramic material…
Laboratory measurements and astronomical search for the HSO radical
2016
[Context] Despite the fact that many sulfur-bearing molecules, ranging from simple diatomic species up to astronomical complex molecules, have been detected in the interstellar medium, the sulfur chemistry in space is largely unknown and a depletion in the abundance of S-containing species has been observed in the cold, dense interstellar medium. The chemical form of the missing sulfur has yet to be identified.
Studies of the initial oxidation of cobalt in alkaline solutions using scanning electrochemical microscope
1998
Studies of the initial oxidation of cobalt in alkaline solutions using scanning electrochemical microscope
Calcium Pre-Rinse: Effect on permeability of dentin tubules by fluoride rinse
2019
Background The aim of this study was to evaluate whether calcium (CaL) solution would enhance the capacity of sodium fluoride (NaF) solution in reducing the permeability of hypersensitive dentin. Material and Methods Thirty-two Wistar rats ingested for 45 days acidic isotonic drink (Gatorade, pH 2.7) ad libitum to induce dental erosion. Then, molar teeth received a cold stimulus to confirm the presence and score the intensity of dentin hypersensitivity based on body contraction and noise. Animals were allocated to four groups (n=8), according to the solution(s) applied in the oral cavity: NaF (12 mmol/L, 1 min); CaL (150 mmol/L, 1 min); CaL followed by NaF (CaF+NaF, 1 min each); distilled w…
Marine aerosols and iodine emissions (Reply)
2005
O'Dowd et al. reply - McFiggans raises some interesting, but partly speculative, issues about the possibility of additional condensable-iodine-vapour (CIV) precursors being involved in marine aerosol formation from biogenic iodine emissions, and about the relative roles of iodine oxide and sulphuric acid in the marine new-particle formation process.
From Mono- to Poly-Substituted Frameworks: A Way of Tuning the Acidic Character of C-c-H in o-Carborane Derivatives
2009
[EN] The incorporation of iodine atoms onto the boron vertices of the o-carborane framework causes, according to spectroscopic data, a uniform increase in the acidic character of the C-c-H (C-c= cluster carbon) vertices, whereas the incorporation of methyl groups onto the boron vertices of the o-carborane framework reduces their acidity. Methyl groups when attached to boron are electron-withdrawing in boron clusters, whereas iodine atoms bonded to boron act as electron donors. This has been proven on B-methyl and B-iodinated o-carboranes with NMR spectroscopy measurements and DFT calculations of natural bond orbital (NBO) charges. which show a Cumulative buildup of positive cluster only tot…