Search results for "element"
showing 10 items of 13601 documents
Geochemical characterization of water quality in karst systems of Greece
2021
Karst systems represent the main drinking water source for 20-25% of world’s population, although covering only 7-10% of the global land surface (Ford & Williams, 2007). Karst aquifers are highly vulnerable to external pollution, so their protection and management is of critical importance to sustain water resources. In Greece, starting from the 1970’s, water demands for agricultural, domestic and industrial use increased significantly, mainly in coastal areas (Daskalaki & Voudouris, 2008). The main Hellenic aquifers are hosted in alluvial deposits, in Neogene deposits and in carbonate rocks. The latter cover about 35% of the country and are located in Western, Central and Southern …
The S … Hal and Se … Hal chalcogen bonding in a series of thiourea, selenourea and their derivatives
2021
The chalcogen bonding (ChB) in a series of thiourea, selenourea and their derivatives has been investigated in the present paper. Thus, selenourea and dimethylselenourea undergo dimerization and trimerization processes in the presence of various halogen species (1–5). Selenourea and dimethylselenourea form trimers 3–4 in the presence of lighter halogens (chlorine and bromine) through Se⋯Se chalcogen bonding. When moving to heavier halogen (iodine), the dimers 1–2 are formed. Thiourea and its derivatives also tend to make very strong S⋯S bonds and form dimers in the case of lighter halogens chlorine and bromine (compounds 6–7). However, the monomers separated by the iodine species are formed…
Rapid self-healing and anion selectivity in metallosupramolecular gels assisted by fluorine-fluorine interactions.
2017
Simple ML2 [M = Fe(II), Co(II), Ni(II)] complexes obtained from a perfluoroalkylamide derivative of 4-aminophenyl-2,2′,6,2′-terpyridine spontaneously, yet anion selectively, self-assemble into gels, which manifest an unprecedented rapid gel strength recovery, viz. self-healing, and thermal rearrangement in aqueous dimethyl sulfoxide. The key factor for gelation and rheological properties emerges from the fluorine–fluorine interactions between the perfluorinated chains, as the corresponding hydrocarbon derivative did not form metallogels. The perfluoro-terpyridine ligand alone formed single crystals, while its Fe(II), Co(II) or Ni(II) complexes underwent rapid gelation leading to highly enta…
Dioxidomolybdenum(VI) and –tungsten(VI) complexes with tetradentate amino bisphenolates as catalysts for epoxidation
2017
Sixteen molybdenum and tungsten complexes with tripodal or linear tetradentate amino bisphenol ligands were studied as catalysts for the epoxidation of cis-cyclooctene, 1-octene, styrene, limonene and α-terpineol. These complexes can be divided into different categories upon key features, i.e. central metal (Mo versus W), side-arm donor (O versus N), hybridization of the N-donor (pyridine versus amine), ligand geometry (tripodal versus linear diamine) and sterical hindrance (Me versus tert-Bu substituents in the phenol part). All complexes can catalyse selectively the epoxidation of cis-cyclooctene by tert-butylhydroperoxide whereas the activities and selectivities towards other olefins (1-…
Cyclic Sulfoximine and Sulfonimidamide Derivatives by Copper‐Catalyzed Cross‐Coupling Reactions with Elemental Sulfur
2023
Copper-catalyzed cross-coupling reactions of α-bromoaryl NH-sulfoximines with elemental sulfur lead to benzo[d][1,3,2]dithiazole-1-oxides, which represent a new class of three-dimensional heterocycles. The reactions proceed under mild conditions showing good functional group and heterocycle tolerance. By imination/oxidation, the initial cross-coupling products can be converted to unprecedented cyclic sulfonimidamides derivatives. Furthermore, a seven-membered heterocycle was obtained by a ruthenium-catalyzed ring-expansion with ethyl propiolate. peerReviewed
Freeze-out radii extracted from three-pion cumulants in pp, p–Pb and Pb–Pb collisions at the LHC
2014
In high-energy collisions, the spatio-temporal size of the particle production region can be measured using the Bose-Einstein correlations of identical bosons at low relative momentum. The source radii are typically extracted using two-pion correlations, and characterize the system at the last stage of interaction, called kinetic freeze-out. In low-multiplicity collisions, unlike in high-multiplicity collisions, two-pion correlations are substantially altered by background correlations, e.g. mini-jets. Such correlations can be suppressed using three-pion cumulant correlations. We present the first measurements of the size of the system at freeze-out extracted from three-pion cumulant correl…
Omintakeisen kansankynttilän kintereillä
2015
Kirja-arvostelu teoksesta: Suni, Hannu: Röyhkeä opettaja. Esa Paavo-Kallion todellisuuskäsitykset, nälkävuodet ja maailmojen konflikti 1867–1913.. Suomen Kirkkohistoriallinen Seura, 2014. 200 sivua. Teologi Hannu Suni tarkastelee kirkkohistorian piiriin kuuluvassa tutkimuksessaan, kuinka erään kansakoulunopettajan toiminta kuvaa samalla hänen aikansa yhteiskunnallista ja hengellistä murrosta 1800-luvun lopulla. Tutkimuksen keskiössä oleva Esa Paavo-Kallio kyseenalaisti maallikkosaarnaajana perinteiset yhteiskuntarakenteet ja joutui sen vuoksi törmäyskurssille evankelis-luterilaisen kirkon edustajien kanssa. Jyväskylän kansakoulunopettajaseminaarin käynyt Esa Paavo-Kallio kiinnostui opiskelu…
Tribological properties of thin films made by atomic layer deposition sliding against silicon
2018
Interfacial phenomena, such as adhesion, friction, and wear, can dominate the performance and reliability of microelectromechanical (MEMS) devices. Here, thin films made by atomic layer deposition (ALD) were tested for their tribological properties. Tribological tests were carried out with silicon counterpart sliding against ALD thin films in order to simulate the contacts occurring in the MEMS devices. The counterpart was sliding in a linear reciprocating motion against the ALD films with the total sliding distances of 5 and 20 m. Al2O3 and TiO2 coatings with different deposition temperatures were investigated in addition to Al2O3-TiO2-nanolaminate, TiN, NbN, TiAlCN, a-C:H [diamondlike car…
Shape optimization for Stokes problem with threshold slip boundary conditions
2017
This paper deals with shape optimization of systems governed by the Stokes flow with threshold slip boundary conditions. The stability of solutions to the state problem with respect to a class of domains is studied. For computational purposes the slip term and impermeability condition are handled by a regularization. To get a finite dimensional optimization problem, the optimized part of the boundary is described by B´ezier polynomials. Numerical examples illustrate the computational efficiency. peerReviewed
O kilku aksjologicznych komponentach zasady fair play
2017
W 1975 r. na polecenie UNESCO został opublikowany przez Międzynarodową Radę Wychowania Fizycznego i Sportu (CIEPS) Manifest o fair play (Mannifeste sur le fair play). Jest on apelem o przywrócenie sportowi wierności zasadzie fair play. Tekst manifestu odwołuje się do określonych wartości. Można w nim wskazać kilka aksjologicznych komponentów, m.in.: poszanowanie reguł, troskę o kompetencje oraz odpowiedzialność za drugiego człowieka. Postawy te mają znaczenie nie tylko w sporcie, lecz także w innych dziedzinach życia i aktywności człowieka (życie zawodowe, polityka, relacje społeczne). Obowiązują tam różnego rodzaju normy (obyczajowe, tetyczne, moralne), wymagany jest rozwój i poszerzanie k…