Search results for "engineering.material"
showing 10 items of 2352 documents
Freshening of the Mediterranean Salt Giant: controversies and certainties around the terminal (Upper Gypsum and Lago-Mare) phases of the Messinian Sa…
2021
The late Miocene evolution of the Mediterranean Basin is characterized by major changes in connectivity, climate and tectonic activity resulting in unprecedented environmental and ecological disruptions. During the Messinian Salinity Crisis (MSC, 5.97-5.33 Ma) this culminated in most scenarios first in the precipitation of gypsum around the Mediterranean margins (Stage 1, 5.97-5.60 Ma) and subsequently > 2 km of halite on the basin floor, which formed the so-called Mediterranean Salt Giant (Stage 2, 5.60-5.55 Ma). The final MSC Stage 3, however, was characterized by a "low-salinity crisis", when a second calcium-sulfate unit (Upper Gypsum; substage 3.1, 5.55-5.42 Ma) showing (bio)geochemica…
Carbonate precipitation in the alkaline lake Specchio di Venere (Pantelleria Island, Italy) and the possible role of microbial mats
2016
Abstract Alkaline lakes like the hydrothermally affected lake Specchio di Venere (Pantelleria Island, Central Mediterranean) are typical geological settings harbouring calcified microbial mats. The present work is focused on the discrimination between biotic and abiotic processes driving carbonate precipitation in this lake, using hydrochemical, mineralogical and isotopic data. Hydrochemical analyses demonstrate that the lake is nearly 10−fold supersaturated with regard to aragonite and seasonally reaches hydromagnesite supersaturation. Microscopic observations depict organosedimentary laminated structures consisting of microbial communities and aragonitic precipitates, which are rather dis…
Ages and stratigraphical architecture of late Miocene deposits in the Lorca Basin (Betics, SE Spain): New insights for the salinity crisis in margina…
2020
International audience; Unlike most Neogene basins of the Betic Cordillera where the Salinity Crisis is dated to the Messinian, a contradictory Tortonian dating was proposed for evaporites of the Lorca Basin. As a consequence, complex structural models have been proposed in the literature to explain this discrepancy in the timing of evaporites. In order to integrate the Lorca Basin into the geological context of the western Mediterranean domain during the Late Miocene, new sedimentological and stratigraphical studies coupled with new dating were performed, which allow us to propose a Messinian age for both diatomite-bearing deposits and evaporites of the Lorca Basin. These new ages challeng…
Pedogenic carbonates and carbon pools in gypsiferous soils of a semiarid Mediterranean environment in south Italy
2013
Abstract Soil carbonates are key features in soils of arid and semiarid environment, playing an important role from pedogenetic, landscape history, paleoclimatic and environmental points of view. The objectives of this work were (i) to study pathways of pedogenic carbonate (PC) formation, (ii) to distinguish between lithogenic and pedogenic inorganic C by using the natural C isotope abundance, and (iii) to estimate the soil C pools in a gypsiferous semiarid Mediterranean environment (Sicily, Italy). Five soil pedons developed on calcareous and non-calcareous parent materials from Holocene (10,000 years BP) to Upper Tortonian (7.2–5.3 Ma BP) in age were surveyed. During field soil descriptio…
Microstructure and phase composition of bronze Montefortino helmets discovered Mediterranean seabed to explain an unusual corrosion
2021
AbstractTwo Monterfortino helmets, recovered in the Mediterranean seabed, show unusual features with respect to the more common helmets of the same period and found in underwater environments. Hence, they were investigated by a multi-analytical approach, which allowed us to identify the compounds constituting the helmets and to make some considerations about their metallurgy, although all the metal was converted to degradation products. The helmets, originally made in bronze, have maintained their original shape because of copper sulphides formation. The observed differences in composition between the two helmets were attributed to the position modification, of one of them, into the seabed …
Biowaste in a circular bioeconomy in Mediterranean area: A case study of compost and vermicompost as growing substrates alternative to peat
2020
European policies are advocating a transition toward circular bio-economy, an economy aiming at reducing the dependence from fossil-based resources, limiting greenhouse gas emissions and environmental impacts. The aim of this paper is to assess the potential for circularity for bio-waste and related by-products, to highlight the role of compost and vermicompost in the circular bioeconomy and their use in the agricultural sector. Three different substrates were tested in the soilless cultivation of Salvia officinalis, a Mediterranean nutraceutical and healthy plant: vermicompost (40%), compost (40%) and peat (100%). The average values of the main biometric parameters were calculated and comp…
Environmental changes during the Upper Pleistocene–Holocene in Mediterranean NE Spain as recorded by the mineralogy and geochemistry of alluvial reco…
2013
Abstract Landscape evolution and environmental conditions from Last Glacial Maximum (LGM) to Late Holocene times were reconstructed from the mineralogical and geochemical characteristics of the alluvial morphochronostratigraphy, recorded in Bardenas Reales Natural Park (Ebro Basin, NE Spain). Alluvial architecture includes a LGM-Holocene gravelly unit (≈22–9 ka BP), a Lower Holocene silty–muddy unit (≈9–7 ka BP), and an Upper Holocene sandy unit (≈5–0.1 ka BP). Increases in illite–smectite mixed layers, kaolinite, chlorite and modified Chemical Index of Alteration (CIA*), as well as the decrease in illite FWHM(E), are indicators of minor increases in the chemical weathering of the alluvial …
Petrological characterization of the mantle source of Mediterranean lamproites: Indications from major and trace elements of phlogopite
2013
Lamproites are among the most enigmatic mantle generated melts, and are typically abundant in phlogopite. We investigated the major and trace element chemistry of phlogopite crystals from Mediterranean lamproite occurrences in Spain, Serbia and Turkey. The most primitive lamproite samples were selected in order to evaluate the generation of the different phlogopite populations in their distinct mantle setting(s). Phlogopite hosted in Mediterranean lamproites can be grouped into different compositional arrays on the basis of their major element chemistry using Al2O3, FeOT and TiO2 concentrations. Contents of Cr, F and presumably Ti allow discrimination of the macrocrysts into phlogopite phen…
Degassing vs. eruptive styles at Mt. Etna volcano (Sicily, Italy). Part I: Volatile stocking, gas fluxing, and the shift from low-energy to highly ex…
2018
International audience; Basaltic magmas can transport and release large amounts of volatiles into the atmosphere, especially in subduction zones, where slab-derived fluids enrich the mantle wedge. Depending on magma volatile content, basaltic volcanoes thus display a wide spectrum of eruptive styles, from common Strombolian-type activity to Plinian events. Mt. Etna, in Sicily, is a typical basaltic volcano where the volatile control on such a variable activity can be investigated. Based on a melt inclusion study in products from Strombolian or lava-fountain activity to Plinian eruptions, here we show that for the same initial volatile content, different eruptive styles reflect variable dega…
Volatile contents of mafic-to-intermediate magmas at San Cristóbal volcano in Nicaragua
2017
San Cristóbal volcano in northwest Nicaragua is one of the most active basaltic–andesitic stratovolcanoes of the Central American Volcanic Arc (CAVA). Here we provide novel constraints on the volcano's magmatic plumbing system, by presenting the first direct measurements of major volatile contents in mafic-to-intermediate glass inclusions from Holocene and historic-present volcanic activity. Olivine-hosted (forsterite [Fo] < 80; Fo< 80) glass inclusions from Holocene tephra layers contain moderate amounts of H2O (0.1–3.3 wt%) and S and Cl up to 2500 μg/g, and define the mafic (basaltic) endmember component. Historic-present scoriae and tephra layers exhibit more-evolved olivines (Fo69…