Search results for "engineering.material"
showing 10 items of 2352 documents
Eclogite xenoliths from the Kuruman kimberlites, South Africa: geochemical fingerprinting of deep subduction and cumulate processes☆
2004
The mineralogically diverse eclogite xenolith suite sampled by the >1.6 Ga Zero kimberlite in the Kuruman group, close to the western edge of the Kaapvaal craton consists of bimineralic eclogites, orthopyroxene-bearing eclogites with and without sanidine, and kyanite eclogites. Garnet exsolutions in clinopyroxene occur in all Zero eclogite types, and orthopyroxene and, where present, sanidine are also exsolved from clinopyroxene in orthopyroxene-bearing eclogites. Mineral thermobarometry indicates that the last P–T condition prior to the kimberlite eruption was 900–950 °C at 3.5–4.0 GPa. However, inclusions of quartz, rutile and rarely K-feldspar, plus former fluid inclusions in garnets, in…
Integrating Ultramafic Lamprophyres into the IUGS Classification of Igneous Rocks: Rationale and Implications
2005
RECEIVED JULY 16, 2004; ACCEPTED MARCH 16, 2005ADVANCE ACCESS PUBLICATION APRIL 29, 2005We introduce a modification to the current IUGS classificationsystem for igneous rocks to include ultramafic lamprophyres, whicharecurrentlyentirelyomitted.Thisisdonebyincludinganewstepinthe sequential system, after the assignment of pyroclastic rocks andcarbonatites, that considers ultramafic inequigranular textured rockswith olivine and phlogopite macrocrysts and/or phenocrysts. At thisstepultramaficlamprophyresareconsideredtogetherwithkimberlites,orangeites (former Group 2 kimberlites) and olivine lamproites.This proposal allows the correct identification and classificationof ultramafic lamprophyres w…
Cooling and crystallization recorded in trachytic enclaves hosted in pantelleritic magmas (Pantelleria, Italy): Implications for pantellerite petroge…
2015
Abstract This study focuses on the comenditic trachyte enclaves hosted in pantelleritic lava and pumices emplaced during one of the most recent eruptive events at Pantelleria (~ 6 ka). Enclaves range from mm-sized fragments to dm-sized blocks with spheroidal to amoeboid shapes and characteristic globular surfaces; they are crystal-rich with ~ 30 vol% large anorthoclase, less abundant Fe-rich olivine, clinopyroxene and Fe–Ti oxides. Vesicles ranging from a few mm to 1–2 cm in size are distributed throughout the enclave and are commonly filled with microlite-free vesicular glass. The groundmass presents spectacular textures, including fine to coarse spherulites and hopper and skeletal microli…
The lithium and magnesium isotope signature of olivine dissolution in soil experiments
2021
Abstract This study presents lithium and magnesium isotope ratios of soils and their drainage waters from a well-characterised weathering experiment with two soil cores, one with olivine added to the surface layer, and the other a control core. The experimental design mimics olivine addition to soils for CO2 sequestration and/or crop fertilisation, as well as natural surface addition of reactive minerals such as during volcanic deposition. More generally, this study presents an opportunity to better understand how isotopic fractionation records weathering processes. At the start of the experiment, waters draining both cores have similar Mg isotope composition to the soil exchangeable pool. …
Detection of a Ca-rich lithology in the Earth's deep (>300 km) convecting mantle
2005
Earth's deep convecting upper mantle is believed to represent a rather homogenous geochemical reservoir of spinel or garnet lherzolite with primitive major element and moderately depleted trace element composition. Only where subduction occurs is this homogeneity disrupted by a suite of rocks ranging from eclogites/garnet pyroxenites (former oceanic crust) to residual harzburgites. In addition to these well documented peridotitic and metabasaltic rocks we have now discovered the presence of a chemically distinct reservoir in the deep convecting upper mantle. In situ structural analyses (micro X-ray diffraction and micro Raman spectroscopy) and three-dimensional trace element mapping (confoc…
Relationship of Mediterranean type lamproites to large shoshonite volcanoes, Miocene of Lesbos, NE Aegean Sea
2014
Abstract Shoshonites, which are high-K trachyandesitic rocks, are found in many orogenic belts and are commonly of post-collisional origin. The petrogenesis of shoshonites has been widely debated. Small lava flows and dykes of lamproite and related lamproitic rocks of early Miocene age in Lesbos are coeval with voluminous shoshonite volcanoes. Their distinctive petrology and isotope geochemistry provide an exceptional opportunity to assess the petrogenetic relationship between lamproites and shoshonites. The lamproitic rocks contain phenocrysts of forsteritic olivine (as high as Fo93) and clinopyroxene, both with inclusions of chrome spinel (Cr# ~ 0.9 or ~ 0.6) and carbonate melt inclusions…
Molar masses and structure in solution of haemoglobin hyperpolymers--a common calibration of size exclusion chromatography of these artificial oxygen…
1997
We are developing artificial oxygen carriers for medical use, based on synthetic polymers--so-called hyperpolymers--obtained by cross-linking mammalian haemoglobins. One requirement with respect to the polymers is that they should not increase the oncotic pressure of blood remarkably--this can be realized by high molecular weights of the polymers with a narrow distribution. They may act as a oxygen transporting blood additive, and--in combination with a plasma expander--as a blood substitute. Another important and desired property of the artificial oxygen carrier is a low viscosity, which--first--is due to a high degree of uniformity of the polymer size (or molar mass) distribution and--sec…
Mechanical behavior and limits to the microhardness testing of hard multilayer coatings on soft substrates
2000
Multilayer coatings of (Ti, Al) N x , (Ti, C)N x and (Nb, C)N x with bilayer thickness of 0.8-8 nm have been deposited by reactive sputtering on stainless steel substrates. Vickers microhardness measurements in the load range of 3.10 -3 to 1 N were performed using a self-adjusting tester. It has been shown that in order to obtain the true hardness of multilayer coatings on a softer substrate, the indentation depth should not exceed about 10% of the coating thickness. Indentation criteria for polycrystalline, amorphous and nanostructured multilayer coatings are compared. The obtained criterion for multilayer coatings is close to that for amorphous films.
Performance Analysis of a Prototype High‐Concentration Photovoltaic System Coupled to Silica Optical Fibers
2021
High-concentration photovoltaic (HCPV) systems are one of the most promising technologies for the generation of renewable energy with high-conversion efficiency. Their development is still at an early stage, but the possibility of integrating high-concentration systems into buildings offers new opportunities to achieve the net-zero-energy building goal. Herein, the optical and energetic performance of a hybrid daylighting−HCPV prototype based on pure- or doped-silica optical fibers (OFs) to guide 2000× concentrated sunlight inside the buildings is evaluated. There, the light can either be used to illuminate interior spaces or projected on solar cells to generate electricity. The system equi…
Optical Fibre NO2 Sensor Based on Lutetium Bisphthalocyanine in a Mesoporous Silica Matrix
2018
International audience; In this article, we describe a NO2 sensor consisting of a coating based on lutetium bisphthalocyanine (LuPc2) in mesoporous silica. The sensor exploits the absorption spectrum change of this material which strongly and reversibly decreases in contact with NO2. NO2 is measured by following the amplitude change in the reflected spectrum of the coating deposited on the tip of a silica fibre. As diffusion of NO2 in LuPc2 is slow, the response time could be slow. To reduce it, the active molecules are dispersed in a mesoporous silica matrix deposited by a sol-gel process (Evaporation Induced Self Assembly) avoiding the formation of large crystals. Doing so, the response i…