Search results for "entropic"

A Simple Entropic-Driving Separation Procedure of Low-Size Silver Clusters, Through Interaction with DNA

2021

Abstract Synthesis and purification of metal clusters without strong binding agents by wet chemical methods are very attractive for their potential applications in many research areas. However, especially challenging is the separation of uncharged clusters with only a few number of atoms, which renders the usual techniques very difficult to apply. Herein, we report the first efficient separation of Ag2 and Ag3 clusters using the different entropic driving forces when such clusters interact with DNA, into which Ag3 selectively intercalates. After sequential dialysis of the samples and denaturalizing the DNA‐Ag3 complex, pure Ag2 can be found in the dialysate after extensive dialysis. Free Ag…

Volumetric properties, viscosities and refractive indices of binary liquid mixtures of tetrafluoroborate-based ionic liquids with methanol at several…

2015

Abstract Densities, speeds of sound, viscosities and refractive indices of two binary systems 1-butyl-3-methylimidazolium tetrafluoroborate [bmim][BF4] + methanol and 1-ethyl-3-methylimidazolium tetrafluoroborate [emim][BF4] + methanol, as well as of all pure components, have been measured covering the whole range of compositions at T = (278.15 to 318.15) K and p = 101 kPa. From this data, excess molar volumes, excess isentropic compressibilities, viscosity deviations and refractive index deviations were calculated and fitted to extended versions of the Redlich–Kister equation. Estimated coefficients of these equations taking into account the dependence on composition and temperature simult…

Energetic analysis of succinic acid in water droplets: insight into the size-dependent solubility of atmospheric nanoparticles

2021

<p>Size-dependent solubility is prevalent in atmospheric nanoparticles, but a molecular level understanding is still insufficient, especially for organic compounds. Here, we performed molecular dynamics simulations to investigate the size dependence of succinic acid solvation on the scale of ~1-4 nm with the potential of mean forces method. Our analyses reveal that the surface preference of succinic acid is stronger for a droplet than the slab of the same size, and the surface propensity is enhanced due to the curvature effect as the droplet becomes smaller. Energetic analyses show that such surface preference is primarily an enthalpic effect in both systems, while the entropi…

Integration of flow meter devices for optimal discharge estimation during floods.

2009

Entropic model application to identify cross-sectional flow effect on velocity distribution in a large amplitude meandering channel

2020

Abstract Literature shows the application of the entropy concept in open channels flow. No existing research has been addressed to the application of the entropy concept for evaluating the effect of secondary flow which especially develops in curved channels. The purpose of this paper is to explore the possibility to evaluate the effect of the secondary flow on the stream-wise velocity distribution starting only from the knowledge of the surface velocity and the entropic concept application. The analysis is conducted with the aid of data collected in a large-amplitude meandering laboratory flume for two different values of the width-to-depth ratio. Results show that the location of the maxi…