Search results for "equation"

Validation of the mass response of a quartz crystal microbalance coated with Prussian Blue film for ac electrogravimetry

2000

Prussian Blue (PB) films have been considerably studied for many research applications such as electrochromic material development, new material for batteries, etc. Many analytical techniques were employed for examining PB electrochemical behaviour in solution and the quartz crystal microbalance (QCM) used in the alternative regime (ac electrogravimetry) appeared as an attractive in situ mass sensor due to its low cost and its high mass sensitivity. Unfortunately, the validity of the common Sauerbrey equation was questionable with these films or in other terms if the QCM was used as a pure mass sensor. In this work PB film is examined through acoustic measurements and the response can be in…

Quantification of electrochromic kinetics by analysis of RGB digital video images

2018

A new, rapid, and practical procedure to obtain quantitative kinetic information of electrochromic materials is proposed. When the transition between two colors on a colored electrode surface is monitorized by digital video, the analysis of pixel color intensity (I) in sequential RGB digital images allows us to precise the half-life time (t1/2) of the color change since a maximum value of the standard deviation of the pixel intensity (σ(I)) is reached. We simulated and analyzed the evolution of standard deviation during an electrochromic transition in different circumstances (kinetic and diffusion control). As an example of application, electrochromic transitions of a thin film model, the P…

Improving the onset potential and Tafel slope determination of earth-abundant water oxidation electrocatalysts

2021

To date, a plethora of electrocatalysts for the Oxygen Evolution Reaction (OER) have been proposed. For evaluating their electrocatalytic behavior the determination of the onset potential in each studied electrolyte is a key parameter. Nevertheless, this evaluation becomes particularly problematic for first- transition metal catalysts as well as by the use of electroactive collectors ( e.g. Ni foams) whose redox peaks overlap the onset potential. A usual solution to detect the onset potential requires the availabil- ity of in-situ mass spectrometric determination of the generated oxygen. In this work, we present fast and easier available cyclic voltammetry and coulovoltammetric responses to…

Motivational Antecedents of Well-Being and Health Related Behaviors in Adolescents

2017

Abstract Grounded in the Achievement Goal Theory framework of motivation and optimal functioning, there were two objectives of this study: (a) to test a model hypothesizing links between personal theories of school achievement, indices of the quality of academic engagement, wellbeing, and health-related behaviors, and (b) to explore whether the hypothesized model was invariant across gender groups. A multisection questionnaire pack tapping the targeted variables was administered to 967 teenagers (475 boys and 492 girls) aged between 11 to 16 years old. Structural equation modeling analysis revealed that Task theory of achievement predicted positively satisfaction in school and negatively bo…

Using an integrated social cognition model to predict COVID‐19 preventive behaviours

2020

ObjectivesRates of novel coronavirus disease 2019 (COVID-19) infections have rapidly increased worldwide and reached pandemic proportions. A suite of preventive behaviours have been recommended to minimize risk of COVID-19 infection in the general population. The present study utilized an integrated social cognition model to explain COVID-19 preventive behaviours in a sample from the Iranian general population.DesignThe study adopted a three-wave prospective correlational design.MethodsMembers of the general public (N = 1,718, Mage = 33.34, SD = 15.77, male = 796, female = 922) agreed to participate in the study. Participants completed self-report measures of demographic characteristics, i…

The Relationship among Paternal and Maternal Psychological Control, Self-Esteem, and Indecisiveness across Adolescent Genders

2015

The purpose of this study was to examine the relationship among adolescents’ indecisiveness, adolescents’ self-esteem, and maternal and paternal psychological control by focusing on the differences in the relationship among these variables across adolescent genders. A total of 381 Italian adolescents (215 boys and 166 girls), aged from 13 to 17 years, completed self-report measures of parental psychological control, self-esteem and indecisiveness. Since previous studies have highlighted indirect relations between family characteristics and indecisiveness, structural equation modeling (SEM) methods were used for testing self-esteem as a possible mediator. In particular, a multiple group anal…

Warr's scale of job-related affective well-being: A longitudinal examination of its structure and relationship with work characteristics

2007

Abstract The aims of this 3-year follow-up study among Finnish managers (n=615) were first, to test the theoretically-based structure of the job-related affective well-being scale (Warr, 1990b), and second, to examine the linear and curvilinear longitudinal associations between work characteristics and job-related affective well-being. Confirmatory factor analysis showed that the hypothesized four-factor model best described the structure of the job-related affective well-being scale; that is, the scale included four interrelated factors of job-related anxiety, comfort, depression, and enthusiasm at both measurement times. Structural equation modelling showed that high feelings of comfort a…

The relationship between fundamental movement skills and self-reported physical activity during Finnish junior high school

2013

Background: Previous studies have shown that fundamental movement skills (FMS) and physical activity are related. Specifically, earlier studies have demonstrated that the ability to perform a variety of FMS increases the likelihood of children participating in a range of physical activities throughout their lives. To date, however, there have not been studies focused on the development of, or the relationship between, these variables through junior high school (that is, between the ages of 13 and 15). Such studies might provide important insights into the relationships between FMS and physical activity during adolescence, and suggest ways to design more effective physical education programm…

2016

Objective: The Emotional Cascade Model (ECM) by Selby et al. (2008) proposes that people often engage in dysregulated behaviors to end extreme, aversive emotional states triggered by a self-perpetuating vicious cycle of (excessive) rumination, negative affect and attempts to suppress negative thoughts. Method: Besides replicating the ECM, we introduced intrusions as a mediator between rumination and behavioral dysregulation and tested this extended ECM for compulsions as part of obsessive-compulsive disorders. A structural equation modeling approach was used to test this in a sample of N = 414, randomly recruited from the general population. Results: Intrusions were found to fully mediate t…

Contextual perceived group threat and radical right-wing populist party preferences: Evidence from Switzerland

2016

Existing studies suggest that perceived group threat is an important influence on radical right-wing populist party preferences. However, most have focused on perceived group threat at the individual level, overlooking the ideological climate. I examine how an ideological climate of group threat perception as a contextual factor can shape individual preferences for radical right-wing populist party preferences. I argue that above and beyond personal perceived group threat, the prevalence of local perceived group threat exerts a normative influence on personal preferences. Using voting preferences for the Swiss People’s Party, I employ multilevel structural equation modeling to examine the …