Search results for "ether"

showing 10 items of 986 documents

Tetra-μ-chlorido-bis(18-crown-6)platinum(II)dipotassium(I)

2010

In the title compound, [K(2)PtCl(4)(C(12)H(24)O(6))(2)], the Pt(II) ion is located on an inversion centre and is coordinated by four Cl atoms, forming a square-planar geometry. The K(I) ion is coordinated by six O atoms of the crown ether and two bridging Cl atoms. The K(I) ion is displaced by 0.756 (2) Å from the mean plane of the six O atoms of the crown ether. The mol-ecules are connected by weak C-H⋯O hydrogen bonds, forming an infinite two-dimensional network parallel to the (10) plane. Intra- and inter-molecular C-H⋯Cl hydrogen bonds are also observed.

Metal-Organic Paperschemistry.chemical_classificationbiologyHydrogen bond18-Crown-6chemistry.chemical_elementGeneral ChemistryCondensed Matter Physicsbiology.organism_classificationBioinformaticsIonchemistry.chemical_compoundCrystallographychemistryTetraGeneral Materials SciencePlatinumCrown etherActa Crystallographica Section E Structure Reports Online
researchProduct

Sevoflurane Impairs Cerebral Blood Flow Autoregulation in Rats: Reversal by Nonselective Nitric Oxide Synthase Inhibition

2005

UNLABELLED In this study, we investigated the effects of 1.0 and 2.0 minimum alveolar anesthetic concentration (MAC) sevoflurane on cerebral blood flow (CBF) autoregulation before and after nonselective inhibition of nitric oxide (NO) synthase in rats. Rats were randomly assigned as follows: Group 1 (n = 8): 1.0 MAC sevoflurane; Groups 2 and 3 (n = 8 per group): 2.0 MAC sevoflurane. Assessment of autoregulation within a mean arterial blood pressure range of 140-60 mm Hg was performed by graded hemorrhage before and after administration of l-arginine methyl ester (l-NAME, 30 mg/kg IV, Groups 1 and 2) or during hypocapnia (Group 3). In 10 additional animals, brain tissue NO(2)(-) concentratio…

Methyl EthersBlood PressureVasodilationPharmacologyNitric OxideSevofluraneNitric oxideRats Sprague-DawleySevofluranechemistry.chemical_compoundHypocapniaAnimalsHomeostasisHyperventilationMedicineAutoregulationEnzyme InhibitorsCerebral HemorrhageBrain ChemistryBlood VolumeDose-Response Relationship Drugbiologybusiness.industrymedicine.diseaseRatsNitric oxide synthaseNG-Nitroarginine Methyl EsterAnesthesiology and Pain MedicineCerebral blood flowchemistryCerebrovascular CirculationAnesthesiaAnesthetics InhalationAnestheticbiology.proteinNitric Oxide Synthasebusinessmedicine.drugAnesthesia & Analgesia
researchProduct

Aliphatic polycarbonates based on carbon dioxide, furfuryl glycidyl ether, and glycidyl methyl ether: reversible functionalization and cross-linking.

2014

Well-defined poly((furfuryl glycidyl ether)-co-(glycidyl methyl ether) carbonate) (P((FGE-co-GME)C)) copolymers with varying furfuryl glycidyl ether (FGE) content in the range of 26% to 100% are prepared directly from CO2 and the respective epoxides in a solvent-free synthesis. All materials are characterized by size-exclusion chromatography (SEC), (1)H NMR spectroscopy, and differential scanning calorimetry (DSC). The furfuryl-functional samples exhibit monomodal molecular weight distributions with Mw/Mn in the range of 1.16 to 1.43 and molecular weights (Mn) between 2300 and 4300 g mol(-1). Thermal properties reflect the amorphous structure of the polymers. Both post-functionalization and…

Methyl EthersMaterials scienceMagnetic Resonance SpectroscopyPolymers and PlasticsPolymersEtherMaleimideschemistry.chemical_compoundDifferential scanning calorimetryPolymer chemistryMaterials ChemistryCopolymerOrganic chemistryFuransMaleimidechemistry.chemical_classificationPolycarboxylate CementCalorimetry Differential ScanningCycloaddition ReactionMolecular StructureOrganic ChemistryTemperaturePolymerCarbon DioxideAmorphous solidchemistryModels ChemicalProton NMRChromatography GelSurface modificationEpoxy CompoundsMacromolecular rapid communications
researchProduct

Sevoflurane-induced reduction of bispectral index does not affect human cerebral microcirculation

2015

Methyl EthersTime FactorsIntraoperative Neurophysiological Monitoringmedicine.medical_treatmentAffect (psychology)SevofluraneSevoflurane03 medical and health sciencesConsciousness Monitors0302 clinical medicinePredictive Value of Tests030202 anesthesiologyGermanymedicineHumansAnesthesiaCerebral microcirculationReduction (orthopedic surgery)Cross-Over Studiesbusiness.industryMicrocirculationReproducibility of ResultsElectroencephalographySignal Processing Computer-AssistedBrain WavesAnesthesiology and Pain MedicineCerebrovascular CirculationBispectral indexAnesthesiaAnesthetics InhalationbusinessAlgorithmsCraniotomy030217 neurology & neurosurgerymedicine.drugEuropean Journal of Anaesthesiology
researchProduct

Inhalational or intravenous anesthetics for craniotomies? Pro inhalational.

2006

In neurosurgery, anesthesiologists and surgeons focus on the same target - the brain. The nature of anesthetics is to interact with brain physiology, leading to favorable and adverse effects. Research in neuroanesthesia over the last three decades has been dedicated to identifying the optimal anesthetic agent to maintain coupling between cerebral blood flow and metabolism, keep cerebrovascular autoregulation intact, and not increase cerebral blood volume and intracranial pressure.Sevoflurane is less vasoactive than halothane, enflurane, isoflurane, or desflurane. The context sensitive half-life is short and similar to that of desflurane, which translates into fast on and offset. Compared wi…

Methyl Ethersmedicine.medical_specialtyIntracranial PressureMEDLINESevofluraneCardiovascular Physiological PhenomenaSevofluraneMedicineHomeostasisHumansAdverse effectPropofolMonitoring PhysiologicEpilepsybusiness.industryPatient SelectionIntravenous AnestheticsBrainElectroencephalographyAnesthesiology and Pain MedicineNeuroprotective AgentsAnesthesiaCerebrovascular CirculationAnesthesia Recovery PeriodAnesthetics InhalationPostoperative Nausea and VomitingNeurosurgeryAnesthesia Recovery PeriodbusinessAnesthetics IntravenousCraniotomymedicine.drugCurrent opinion in anaesthesiology
researchProduct

Isoflurane is associated with a similar incidence of emergence agitation/delirium as sevoflurane in young children ? a randomized controlled study

2006

Summary Background:  Children may be agitated or even delirious especially when recovering from general anesthesia using volatile anesthetics. Many trials have focused on the newer agents sevoflurane and desflurane but for the widely used isoflurane little is known about its potential to generate agitation. We investigated the emergence characteristics of small children after sevoflurane or isoflurane with caudal anesthesia for postoperative pain control. Methods:  After institutional approval and parental consent, anesthesia was randomly performed with sevoflurane (n = 30) or isoflurane (n = 29) in children at the age of 3.8 ± 1.8 years during surgical interventions on the lower part of th…

Methyl Ethersmedicine.medical_specialtyTime FactorsAnesthesia GeneralSevofluranePacuSevofluraneDesfluranePostoperative ComplicationsmedicineHumansAnesthetics LocalChildBupivacaineIsofluranebiologybusiness.industryIncidenceDeliriumInfantbiology.organism_classificationmedicine.diseaseBupivacaineSurgeryAnesthesiology and Pain MedicineIsofluraneEmergence deliriumChild PreschoolAnesthesiaAnesthesia Recovery PeriodAnesthetics InhalationPediatrics Perinatology and Child HealthShiveringmedicine.symptomAnesthesia Recovery PeriodbusinessAnesthesia CaudalAkathisia Drug-Inducedmedicine.drugPediatric Anesthesia
researchProduct

Economic Considerations of the Use of New Anesthetics

1998

UNLABELLED: Cost control in anesthesia is no longer an option; it is a necessity. New anesthetics have entered the market, but economic differences in comparison to standard anesthetic regimens are not exactly known. Eighty patients undergoing either subtotal thyroidectomy or laparoscopic cholecystectomy were randomly divided into four groups, with 20 patients in each group. Group 1 received propofol 1%/sufentanil, Group 2 received desflurane/sufentanil, Group 3 received sevoflurane/sufentanil, and Group 4 received isoflurane/sufentanil (standard anesthesia) for anesthesia. A fresh gas flow of 1.5-2 L/min and 60% N2O in oxygen was used for maintenance of anesthesia, and atracurium was given…

Methyl Ethersmedicine.medical_specialtyTime FactorsSevofluranePacuSufentanilSevofluraneDesfluranemedicineHumansCholecystectomyProspective StudiesPropofolIsofluranebiologybusiness.industryMiddle Agedbiology.organism_classificationSurgeryAnesthesiology and Pain MedicineMuscle relaxationIsofluraneAnesthesiaAnesthetics InhalationAnestheticCosts and Cost AnalysisThyroidectomyPropofolbusinessDesfluranemedicine.drugAnesthesia & Analgesia
researchProduct

Identification of Resistance Genes and Response to Arsenic in Rhodococcus aetherivorans BCP1

2019

This is the accepted manuscript of the paper "Identification of Resistance Genes and Response to Arsenic in Rhodococcus aetherivorans BCP1", published as final paper in "Frontiers in Microbiology Volume 10, 07 May 2019, Pages 888 https://doi.org/10.3389/fmicb.2019.00888”. Arsenic (As) ranks among the priority metal(loid)s that are of public health concern. In the environment, arsenic is present in different forms, organic or inorganic, featured by various toxicity levels. Bacteria have developed different strategies to deal with this toxicity involving different resistance genetic determinants. Bacterial strains of Rhodococcus genus, and more in general Actinobacteria p…

Microbiology (medical)arsenic resistance geneThioredoxin reductaselcsh:QR1-502chemistry.chemical_elementMicrobiologylcsh:MicrobiologyNO03 medical and health scienceschemistry.chemical_compoundR. aetherivorans BCP1Gene clusterRhodococcusArsenic030304 developmental biologyArseniteOriginal Research0303 health sciencesbiology030306 microbiologyarsenate reductionarsenic resistance genesbiology.organism_classificationActinobacteriaArsenate reductaseBiochemistrychemistryarsenic resistance genes arsenate reduction Rhodococcus R. aetherivorans BCP1 ActinobacteriaThioredoxinEnergy sourceRhodococcusRhodococcuFrontiers in Microbiology
researchProduct

The use of phage FCL-2 as an alternative to chemotherapy against columnaris disease in aquaculture

2015

Flavobacterium columnare, the causative agent of columnaris disease in fish, causes millions of dollars of losses in the US channel catfish industry alone, not to mention aquaculture industry worldwide. Novel methods are needed for the control and treatment of bacterial diseases in aquaculture to replace traditionally used chemotherapies. A potential solution could be the use of phages, i.e., bacterial viruses, host-specific and self-enriching particles that can be can easily distributed via water flow. We examined the efficacy of phages to combat columnaris disease. A previously isolated phage, FCL-2, infecting F. columnare, was characterized by sequencing. The 47 142 bp genome of the phag…

Microbiology (medical)phage therapyanimal structuresPhage therapyWater flowvirusesFish farmingmedicine.medical_treatmentPopulationlcsh:QR1-502BiologyMicrobiologylcsh:MicrobiologyMicrobiologyFlavobacterium columnareAquaculturemedicine14. Life underwatereducation1183 Plant biology microbiology virologyOriginal Researchfishdiseaseeducation.field_of_studybiologybusiness.industryta1183biology.organism_classification6. Clean wateraquacultureFlavobacterium columnareRainbow troutBacterial virusbusinessphagetherapyFrontiers in Microbiology
researchProduct

A high-yielding modular access to the lamellarins: synthesis of lamellarin G trimethyl ether, lamellarin η and dihydrolamellarin η.

2013

Microwave chemistryMolecular StructureChemistryLamellarin G trimethyl etherCoumarinsOrganic ChemistryOrganic chemistryTotal synthesisGeneral ChemistryIsoquinolinesHeterocyclic Compounds 4 or More RingsCatalysisChemistry (Weinheim an der Bergstrasse, Germany)
researchProduct