Search results for "ethers"

showing 10 items of 151 documents

Effects of sevoflurane on cognitive deficit, motor function, and histopathology after cerebral ischemia in rats.

2009

Background: The volatile anesthetic sevoflurane exhibits neuroprotective properties when assessed for motor function and histopathology after cerebral ischemia in rats. Damage of hippocampal neurons after ischemia relates to a number of cognitive deficits that are not revealed by testing animals for motor function. Therefore, the present study evaluates cognitive and behavioral function as well as hippocampal damage in rats subjected to cerebral ischemia under sevoflurane compared with fentanyl/nitrous oxide (N 2 O)/O 2 anesthesia. Methods: Thirty-four rats were trained for 10 days using a hole-board test to detect changes in cognitive and behavioral function. Rats were randomly assigned to…

MaleMethyl EthersIschemiaNitrous OxideSevofluraneFentanylBrain IschemiaBrain ischemiaRats Sprague-DawleySevofluranemedicineAnimalsAnesthesiaCognitive deficitAnestheticsbusiness.industryBrainGeneral Medicinemedicine.diseaseImmunohistochemistryRatsFentanylAnesthesiology and Pain MedicineBlood pressureCerebral blood flowAnesthesiaData Interpretation StatisticalArterial bloodmedicine.symptomBlood Gas AnalysisbusinessCognition DisordersAnesthetics IntravenousPsychomotor Performancemedicine.drugActa anaesthesiologica Scandinavica
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Low-Flow Desflurane and Sevoflurane Anesthesia Minimally Affect Hepatic Integrity and Function in Elderly Patients: Retracted

2000

UNLABELLED Hepatic blood flow is reduced in a dose-related manner by all inhaled anesthetics now in use. We assessed hepatic function in elderly patients anesthetized with desflurane or sevoflurane. We measured the cytosolic liver enzyme alpha glutathione S-transferase (alpha GST), the formation of the lidocaine metabolite monoethylglycinexylidide (MEGX), and gastric mucosal tonometry-derived variables as sensitive markers of hepatic function and splanchnic perfusion. Thirty patients, 70 to 90 yr old, were allocated randomly to receive desflurane or sevoflurane anesthesia. Anesthetic exposure ranged from 2.1-4.5 minimum alveolar concentration hours. No significant changes in standard liver …

MaleMethyl EthersMinimum alveolar concentrationLidocaineSevofluraneSevofluraneDesfluranemedicineHumansAgedGlutathione TransferaseAged 80 and overIsofluranebusiness.industryLidocaineAnesthesiology and Pain MedicineLiverGastric MucosaAnesthesiaAnesthetics InhalationAnestheticFemaleLiver functionSplanchnicbusinessDesfluranePerfusionmedicine.drugAnesthesia & Analgesia
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Impact of inhalation vs. intravenous anaesthesia on autonomic nerves and internal anal sphincter tone.

2014

Background Pelvic intraoperative neuromonitoring (pIONM) aims to identify and spare the autonomic nerves and maintain patients’ quality of life. The effect of anaesthetic agents on the pIONM signal is unknown; therefore, the aim of the present study was to compare the influences of inhalation anaesthesia (IA) and total intravenous anaesthesia (TIVA). Methods Twenty rectal cancer patients undergoing open nerve-sparing total mesorectal excision (TME) were assigned to pIONM under either IA or TIVA (n = 10 per group). IA was maintained with sevoflurane and TIVA with propofol. During surgery, pelvic autonomic nerves were electrically stimulated under electromyography (EMG) of the internal anal s…

MaleMethyl Ethersmedicine.medical_specialtyAnal CanalElectromyographySevofluraneInternal anal sphincterSevofluraneInterquartile rangemedicineHumansAutonomic PathwaysPropofolAgedAged 80 and overmedicine.diagnostic_testInhalationbusiness.industryElectromyographyGeneral MedicineMiddle AgedTotal mesorectal excisionSurgeryAutonomic nervous systemAnesthesiology and Pain MedicineAnesthesiaAnesthetics InhalationAnesthesia IntravenousFemalePropofolbusinessAnesthesia InhalationAnesthetics Intravenousmedicine.drugActa anaesthesiologica Scandinavica
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Putative role of nitric oxide synthase isoforms in the changes of nitric oxide concentration in rat brain cortex and cerebellum following sevoflurane…

2005

We have previously observed an increase in nitric oxide (NO) content in rat brain cortex following halothane, sevoflurane or isoflurane anaesthesia. This study was undertaken in order to determine whether isoform-specific nitric oxide synthase (NOS) inhibitors and inducers could modify these increases in NO contents. Rats were subjected to isoflurane and sevoflurane anaesthesia with concomitant administration of neuronal nitric oxide synthase (nNOS) inhibitor 7-Nitro-indazole (7-NI), inducible nitric oxide synthase (iNOS) inhibitor 2-amino-5,6-dihydro-6-methyl-4H-1,3-thiazine (AMT) or lipopolysaccharide. NO concentration in different organs was measured by electron paramagnetic resonance (E…

MaleMethyl Ethersmedicine.medical_specialtyCentral nervous systemNitric Oxide Synthase Type IINerve Tissue ProteinsNitric Oxide Synthase Type INitric OxideSevofluraneNitric oxidechemistry.chemical_compoundSevofluraneInternal medicineCortex (anatomy)CerebellummedicineAnimalsRats WistarPharmacologyCerebral CortexbiologyIsofluraneRecombinant ProteinsRatsNitric oxide synthaseIsoenzymesmedicine.anatomical_structureEndocrinologyIsofluranechemistryBiochemistryCerebral cortexAnesthetics Inhalationbiology.proteinHalothaneNitric Oxide Synthasemedicine.drugEuropean journal of pharmacology
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The Long-Term Effect of Sevoflurane on Neuronal Cell Damage and Expression of Apoptotic Factors After Cerebral Ischemia and Reperfusion in Rats

2006

We investigated the long-term effects of sevoflurane on histopathologic injury and key proteins of apoptosis in a rat hemispheric ischemia/reperfusion model. Sixty-four male Sprague-Dawley rats were randomly assigned to Group 1 (fentanyl and N2O/O2; control) and Group 2 (2.0 vol% sevoflurane and O2/air). Ischemia (45 min) was produced by unilateral common carotid artery occlusion plus hemorrhagic hypotension (mean arterial blood pressure 40 mm Hg). Animals were killed after 1, 3, 7, and 28 days. In hematoxylin and eosin-stained brain sections eosinophilic hippocampal neurons were counted. Activated caspase-3 and the apoptosis-regulating proteins Bax, Bcl-2, Mdm-2, and p53 were analyzed by i…

MaleMethyl Ethersmedicine.medical_specialtyH&E stainIschemiaCell CountHippocampal formationHippocampusNeuroprotectionSevofluraneBrain IschemiaRats Sprague-DawleySevofluraneInternal medicineEosinophilicmedicineAnimalsNeuronsCaspase 3business.industrymedicine.diseaseImmunohistochemistryRatsEnzyme ActivationNeuroprotective AgentsAnesthesiology and Pain MedicineBlood pressureEndocrinologyCaspasesCerebrovascular CirculationReperfusion InjuryAnesthesiaAnesthetics InhalationApoptosis Regulatory ProteinsbusinessBlood Flow VelocityImmunostainingmedicine.drugAnesthesia & Analgesia
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Volatile Anesthetics Influence Blood-Brain Barrier Integrity by Modulation of Tight Junction Protein Expression in Traumatic Brain Injury

2012

Disruption of the blood-brain barrier (BBB) results in cerebral edema formation, which is a major cause for high mortality after traumatic brain injury (TBI). As anesthetic care is mandatory in patients suffering from severe TBI it may be important to elucidate the effect of different anesthetics on cerebral edema formation. Tight junction proteins (TJ) such as zonula occludens-1 (ZO-1) and claudin-5 (cl5) play a central role for BBB stability. First, the influence of the volatile anesthetics sevoflurane and isoflurane on in-vitro BBB integrity was investigated by quantification of the electrical resistance (TEER) in murine brain endothelial monolayers and neurovascular co-cultures of the B…

MaleMouse610 MedizinBrain EdemaPharmacologyCardiovascularMiceAnesthesiology610 Medical sciencesEdemaMolecular Cell BiologyClaudin-5MultidisciplinaryIsofluraneQRAnimal ModelsHead Injurymedicine.anatomical_structureNeurologyBlood-Brain BarrierAnesthesiaAnesthetics InhalationMedicineCellular Typesmedicine.symptomResearch Articlemedicine.drugMethyl EthersTraumatic brain injuryCerebrovascular DiseasesScienceBrain damageBlood–brain barrierSevofluraneCell LineTight JunctionsCerebral edemaSevofluraneModel OrganismsVascular BiologymedicineAnimalsBiologybusiness.industryEndothelial Cellsmedicine.diseaseCoculture TechniquesIsofluraneBrain InjuriesAnestheticZonula Occludens-1 ProteinMolecular NeurosciencebusinessNeurosciencePLoS ONE
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Vitamin K epoxide reductase activity in the metabolism of epoxides

1985

Abstract The importance of vitamine K epoxide reductase for the metabolism of a range of structurally diverse epoxides has been investigated. Vitamin K 1 epoxide is reduced by rat liver microsomes at a rate of 0.47 nmoles/g liver/min. The rate of menadione oxide reduction is not significantly higher than the non-enzymatic reduction rate. No measurable reduction of benzo[ a ]pyrene 4,5-oxide, benzo[ a ]pyrene 7,8-oxide, phenanthrene 9,10-oxide, styrene 7,8-oxide, and dieldrin has been detected, nor could trichothecene T-2 toxin inhibit reduction of vitamin K 1 epoxide. Thus, vitamin K epoxide reductase is very specific for vitamin K 1 epoxide. Taking into account the range of structurally di…

MaleStereochemistryEpoxideIn Vitro TechniquesReductaseBiochemistryMixed Function Oxygenaseschemistry.chemical_compoundMenadioneEthers CyclicVitamin K Epoxide ReductasesAnimalsEpoxide hydrolaseTrichloroepoxypropaneEpoxide HydrolasesPharmacologyRats Inbred StrainsVitamin K 1MetabolismRatschemistryBiochemistryMicrosomal epoxide hydrolaseMicrosomes LiverMicrosomeEpoxy CompoundsVitamin K epoxide reductaseBiochemical Pharmacology
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Cerebral haemodynamic changes during propofol-remifentanil or sevoflurane anaesthesia: transcranial Doppler study under bispectral index monitoring

2006

Background. Sevoflurane or propofol–remifentanil-based anaesthetic regimens represent modern techniques for neurosurgical anaesthesia. Nevertheless, there are potential differences related to their activity on the cerebrovascular system. The magnitude of such difference is not completely known. Methods. In total 40 patients, treated for spinal or maxillo-facial disorders, were randomly allocated to either i.v. propofol–remifentanil or inhalational sevoflurane anaesthesia. Transcranial Doppler was used to assess changes in cerebral blood flow velocity, carbon dioxide reactivity, cerebral autoregulation and the bispectral index to assess the depth of anaesthesia. Results. Time-averaged mean f…

MaleUltrasonography Doppler TranscranialHemodynamicsBlood PressurePiperidinesHeart RateMedicineHomeostasisProspective StudiesPropofolUltrasonographyIntraoperativeAdult Anesthetics; Combined; pharmacology Anesthetics; Inhalation; Intravenous; pharmacology Blood Flow Velocity; drug effects Blood Pressure; drug effects Carbon Dioxide; physiology Cerebrovascular Circulation; drug effects Electroencephalography Female Heart Rate; drug effects Homeostasis; drug effects Humans Male Methyl Ethers; pharmacology Middle Aged Monitoring; Intraoperative; methods Piperidines; pharmacology Propofol; pharmacology Prospective Studies Ultrasonography; Doppler; TranscranialCombineddrug effectDopplerElectroencephalographyMiddle AgedAnesthetics CombinedCerebral blood flowInhalationBispectral indexAnesthesiaCerebrovascular CirculationAnesthetics InhalationmethodFemaleIntravenousPropofolAnesthetics IntravenousBlood Flow Velocitymedicine.drugHumanMethyl EthersAdultMonitoringRemifentanilIntravenouTranscranialCerebral autoregulationtranscranial DopplerSevofluranemethodsRemifentanilSevofluranePiperidineMonitoring IntraoperativeHomeostasiHumansAnestheticsbusiness.industryAnestheticCarbon DioxideTranscranial DopplerProspective StudieAnesthesiology and Pain MedicineMethyl Etherdrug effectsphysiologypharmacologybusiness
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New concepts and applications in macromolecular chemistry of fullerenes

2010

A new classification on the different types of fullerene-containing polymers is presented according to their different properties and applications they exhibit in a variety of fields. Because of their interest and novelty, water-soluble and biodegradable C(60)-polymers are discussed first, followed by polyfullerene-based membranes where unprecedented supramolecular structures are presented. Next are compounds that involve hybrid materials formed from fullerenes and other components such as silica, DNA, and carbon nanotubes (CNTs) where the most recent advances have been achieved. A most relevant topic is still that of C(60)-based donor-acceptor (D-A) polymers. Since their application in pho…

Materials scienceFullereneMacromolecular SubstancesPolymersSupramolecular chemistryNanotechnologyCarbon nanotubeFullerene macromolecules polymers materials chemistry synthesis hybrid materials photovoltaic deviceslaw.inventionlawGeneral Materials Sciencechemistry.chemical_classificationNanotubes CarbonNanowiresPhenyl EthersMechanical EngineeringMolecular electronicsDNAPolymerSettore CHIM/06 - Chimica OrganicaSilicon DioxideSupramolecular polymerschemistryMechanics of MaterialsFullerenesHybrid materialMacromolecule
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Thioether-Bearing Hyperbranched Polyether Polyols with Methionine-Like Side-Chains: A Versatile Platform for Orthogonal Functionalization

2016

The synthesis of thioether-bearing hyperbranched polyether polyols based on an AB/AB2 type copolymerization (cyclic latent monomers) is introduced. The polymers are prepared by anionic ring-opening multibranching copolymerization of glycidol and 2-(methylthio)ethyl glycidyl ether (MTEGE), which is conveniently accessible in a single etherification step. Slow monomer addition provides control over molecular weights. Moderate dispersities (Đ = 1.48–1.85) are obtained, given the hyperbranched structure. In situ 1H NMR copolymerization kinetics reveal reactivity ratios of rG = 3.7 and rMTEGE = 0.27. Using slow monomer addition, copolymer composition can be systematically varied, allowing for th…

Materials sciencePolymers and PlasticsPolymersAllyl glycidyl ether02 engineering and technology010402 general chemistryBranching (polymer chemistry)01 natural sciencesPolymerizationchemistry.chemical_compoundMethionineThioetherPolymer chemistryMaterials ChemistryCopolymerOrganic chemistrySulfhydryl CompoundsPropylene oxideMolecular StructureOrganic ChemistryTemperatureGlycidol021001 nanoscience & nanotechnologyIsocyanate0104 chemical sciencesMonomerchemistry0210 nano-technologyEthersMacromolecular Rapid Communications
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