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showing 10 items of 11436 documents

Application of polydopamine functionalized zinc oxide for glucose biosensor design

2021

Zinc oxide (ZnO) nanostructures are widely used in optical sensors and biosensors. Functionalization of these nanostructures with polymers enables optical properties of ZnO to be tailored. Polydopamine (PDA) is a highly biocompatible polymer, which can be used as a versatile coating suitable for application in sensor and biosensor design. In this research, we have grown ZnO-based nanorods on the surface of ITO-modified glass-plated optically transparent electrodes (glass/ITO). Then the deposition of the PDA polymer layer on the surface of ZnO nanorods was performed from an aqueous PDA solution in such a way glass/ITO/ZnO-PDA structure was formed. The ZnO-PDA composite was characterized by S…

polydopamine (PDA)ITO modified glass electrodeMaterials sciencePolymers and PlasticsOrganic chemistrypolydopamine (PDA) ; ZnO-PDA nanocomposite ; photo-electrochemical glucose biosensor ; ITO modified glass electrodeengineering.materialArticleQD241-441CoatingGlucose oxidasechemistry.chemical_classificationbiologyGeneral ChemistryPolymerAmperometrychemistryChemical engineeringphoto-electrochemical glucose biosensorbiology.proteinengineeringSurface modificationZnO-PDA nanocompositeNanorodCyclic voltammetryBiosensor
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A supported titanium postmetallocene catalyst: Effect of selected conditions on ethylene polymerization

2011

Ethylene polymerization with a titanium complex [N,N-ethylenebis(3-methoxysalicylideneiminato)titanium dichloride] immobilized on the magnesium support with the formula MgCl2(THF)0.32(Et2AlCl)0.36 was studied. In particular, the effects of polymerization temperature, monomer pressure, and polymerization time on the activity of the catalyst and on the polyethylene properties (molecular weight and its distribution, melting point, crystallinity, and bulk density) were evaluated. The findings of investigations prove that the studied supported titanium catalyst is highly active in ethylene polymerization, and its activity increases with increasing temperature and monomer pressure. Moreover, stab…

polyethyleneMaterials sciencePolymers and PlasticsBulk polymerizationsupportsmelting pointtechnology industry and agriculturechemistry.chemical_elementSolution polymerizationGeneral Chemistrymolecular weight distributionPolyethylenecatalystsSurfaces Coatings and Filmschemistry.chemical_compoundChain-growth polymerizationchemistryPolymerizationPolymer chemistryMaterials ChemistryPrecipitation polymerizationCoordination polymerizationTitaniumJournal of Applied Polymer Science
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Weathering of low-density polyethylene grafted with itaconic acid in laboratory tests

2011

Polyethylene grafted with itaconic acid was subjected to weathering under laboratory accelerated conditions. The course of the photo-oxidative degradation process of that material was studied by FTIR spectroscopy both through quantitative measurements of changes in absorbance values at selected wave numbers and through measurements of surface area values for absorption bands which were separated by means of deconvolution. The use of both those procedures of quantitative determinations resulted in a general conclusion that the oxidation process was initiated from the very first moment of irradiation, and it produced ketones, acids, esters (intramolecular and of acetate type), peracids, peres…

polyethylenechemistry.chemical_classificationPolymers and PlasticsInorganic chemistryGeneral ChemistryPolymeritaconic acidPolyethylenepolymer structural changesSurfaces Coatings and FilmsAbsorbancechemistry.chemical_compoundLow-density polyethyleneFTIRchemistryageingPolymer chemistryMaterials ChemistryItaconic acidIrradiationAbsorption (chemistry)Fourier transform infrared spectroscopyJournal of Applied Polymer Science
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Polygonal mesh segmentation by surface curvature diffusion.

2011

polygonal mesh segmentationSettore INF/01 - Informaticasurface curvature diffusion.
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Recycling ground tire rubber (GTR) scraps as high-impact filler of in-situ produced polyketone matrix

2014

polymer-matrix compositein situ polymerizationpolyketonesinterfaceGTR
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Embeddings of Danielewski hypersurfaces

2008

In this thesis, we study a class of hypersurfaces in $\mathbb{C}^3$, called \emph{Danielewski hypersurfaces}. This means hypersurfaces $X_{Q,n}$ defined by an equation of the form $x^ny=Q(x,z)$ with $n\in\mathbb{N}_{\geq1}$ and $\deg_z(Q(x,z))\geq2$. We give their complete classification, up to isomorphism, and up to equivalence via an automorphism of $\mathbb{C}^3$. In order to do that, we introduce the notion of standard form and show that every Danielewski hypersurface is isomorphic (by an algorithmic procedure) to a Danielewski hypersurface in standard form. This terminology is relevant since every isomorphism between two standard forms can be extended to an automorphism of the ambiant …

polynomial automorphisms.Danielewski surfacespolynômes équivalentsequivalent polynomialslocally nilpotent derivations[MATH] Mathematics [math]dérivations localement nilpotentesstable equivalence problemDanielewski hypersurfacessurfaces de Danielewskihypersurfaces de Danielewskiproblème de l'équivalence stableautomorphismes polynomiaux
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Physical Processes and Chemical Processes guiding polyoxomatalates self-structuring on surfaces

2010

polyoxometalate nanotechnology surfacesSettore CHIM/02 - Chimica Fisica
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Preparation of tungstophosphoric acid/cerium-doped NH2-UiO-66 Z-scheme photocatalyst: a new candidate for green photo-oxidation of dibenzothiophene a…

2021

International audience; The goal of this study was to introduce an effective visible-light induced photocatalytic system with a good ability for photocatalytic oxidative desulfurization (PODS) and denitrogenation (PODN) using molecular oxygen (O2) as an oxidant. In this regard, tungestophosphoric acid (PW12) was supported onto cerium-doped NH2-UiO-66 (PW12/Ce-NUiO-66) and employed for the photo-oxidation of dibenzothiophene (DBT) and quinoline (Qu). Herein, using cerium (Ce) as a “mediator” facilitated the separation of charge carriers, while NH2-UiO-66 remarkably enhanced the surface area with plentiful adsorption sites and shifted the adsorption edge of PW12to the visible region. The sum …

pore volumeAdsorption edgesLight02 engineering and technology01 natural scienceschemistry.chemical_compound[SPI]Engineering Sciences [physics]quinolineVisible-light irradiationMaterials Chemistryoxidizing agentOxidative desulfurizationirradiationQuinolineCerium021001 nanoscience & nanotechnologyOxidantsFlue-gas desulfurizationCeriumDibenzothiophenePhotocatalysisCharge carrierCarrier mobility0210 nano-technologychemistry.chemical_element010402 general chemistryMaximum EfficiencyCatalysisArticleuraniumAdsorptionphosphotungstic acidpore size distributiondibenzothiophene derivativegreen chemistryphotooxidationDopingdesulfurizationGeneral Chemistrysurface areaPhotocatalytic systems0104 chemical sciencesVisible light inducedDibenzothiophenesTungstophosphoric acidMolecular oxygenPhotocatalytic activitychemistryadsorptiondesorptionoxygenphotocatalysisNuclear chemistrycatalyst
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Comparison of the Properties of Activated Carbons Produced in One-Stage and Two-Stage Processes

2018

Activated carbons (ACs) can be produced from biomass in a thermal process either in a direct carbonization-activation process or by first carbonizing the biomass and later activating the bio-chars into activated carbons. The properties of the ACs are dependent on the type of process used for production. In this study, the properties of activated carbons produced in one-stage and two-stage processes are considered. Activated carbons were produced by physical activation of two types of starting materials: bio chars produced from spruce and birch chips in a commercial carbonization plant and from the corresponding raw chips. The activated carbons produced were characterized regarding specific …

porosity020209 energychemistry.chemical_elementBiomass02 engineering and technologyThermal treatment010501 environmental sciencesphysical activation01 natural sciencesspecific surface areaslcsh:QD241-441huokoisuuslcsh:Organic chemistryspecific surface areasBiochar0202 electrical engineering electronic engineering information engineeringmedicineactivated carbonbiomassa (teollisuus)Porosityta1160105 earth and related environmental sciencesbio-charbiomassCarbonizationOne stageGeneral MedicineaktivointichemistryChemical engineeringaktiivihiiliactivationCarbonthermal treatmentActivated carbonmedicine.drugC
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Positron Surface States on Clean and Oxidized Al and in Surface Vacancies

1983

This Letter reports on the first discrete-lattice calculation of positron surface states on the surfaces of Al. The authors reproduce the observed values and anisotropy of the binding energies on clean surfaces, and predict the surface-state lifetimes. The temperature-independent lateral diffusion constant is calculated. Monovacancies on surfaces are predicted not to trap positrons. The effect of ordered chemisorbed monolayers of oxygen is investigated: Oxidation makes the surface state unstable with respect to positronium emission. Peer reviewed

positronsSurface (mathematics)Materials sciencePositronPhysicsaluminiumGeneral Physics and AstronomysurfacesAtomic physicsSurface statesPhysical Review Letters
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