Search results for "ferrocenylpolyphosphine"

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Ultra-Low Catalyst Loading as a Concept in Economical and Sustainable Modern Chemistry: The Contribution of Ferrocenylpolyphosphane Ligands

2007

The challenge of sustainability in modern chemistry will be met with new technologies and processes provided significant progress is made in several key research areas, such as the expansion of chemistry from renewable feedstock, the design of environmentally benign chemicals and solvents, the minimization of depletive resources, and the development of high-performance catalysis. In this prospect, ligand chemistry is a pivotal science that links modern-organic,-inorganic, -organometallic, and -coordination chemistry through a vast number of valuable applications, precisely associated to catalysis. We review in this article our recent work on catalysis promoted by original ferrocenyl tetra-,…

Green chemistryaminesSonogashira couplingHomogeneous catalysisvinylation catalystsultra-low010402 general chemistry01 natural sciencesCatalysisCoordination complexInorganic Chemistry[ CHIM.CATA ] Chemical Sciences/Catalysischemistry.chemical_compoundcross-couplingferrocenylpolyphosphineOrganic chemistrycatalyzedDiphosphaneReactivity (chemistry)ComputingMilieux_MISCELLANEOUSAminationchemistry.chemical_classificationalkynylationligands010405 organic chemistryChemistryLigandSonogashira[CHIM.CATA]Chemical Sciences/CatalysisGeneral MedicinepalladiumCombinatorial chemistry0104 chemical sciencesHeckcoupling reactionChemInform
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On the mechanistic behavior of highly efficient palladium-tetraphosphine catalytic systems for cross-coupling reactions: first spectroscopic and elec…

2008

Electrochemical studies carried out in conjunction with 31P NMR spectroscopy on the palladium(II)/palladium(0) halogeno complexes of the tetraphosphine 1,1′,2,2′-tetrakis(diphenylphosphino)-4,4′-di...

crystal structureDenticityredox reactionoxidative additiontetraphosphinechemistry.chemical_elementmechanism010402 general chemistryElectrochemistryPhotochemistry01 natural sciencesCoupling reactionCatalysisInorganic Chemistry[ CHIM.CATA ] Chemical Sciences/Catalysiscross-coupling reactionsferrocenylpolyphosphine complexesPhysical and Theoretical ChemistryComputingMilieux_MISCELLANEOUSelectrochemical studies010405 organic chemistryChemistryOrganic Chemistry[CHIM.CATA]Chemical Sciences/CatalysispalladiumCombinatorial chemistryOxidative addition0104 chemical sciences3. Good healthcatalytic systemsreaction kinetics31p nmr spectroscopyPalladium
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