Search results for "force"
showing 10 items of 3423 documents
Brain Activity Characterization Induced by Alcoholic Addiction: Spectral and Causality Analysis of Brain Areas Related to Control and Reinforcement o…
2014
Addiction to drugs generates modifications in the brain structure and its functions. In this work, an experimental model is described, using rats to characterize the brain activity induced by alcohol addiction. Four records were obtained using electrodes located in brain areas related to impulsivity control and reinforcement, i.e. the prelimbic (PL) and infralimbic (IL) cortex, together with the hippocampus (HPC). In the records, three main events related to the drinking action were selected: in the previous minute (T1), the first minute while drinking (T2) and the first minute after stopping drinking (T3).
Breather Molecular Complexes in a Passively Mode‐Locked Fiber Laser
2021
International audience; Breathing solitons are nonlinear waves in which the energy concentrates in a localized and oscillatory fashion. Similarly to stationary solitons, breathers in dissipative systems can form stable bound states displaying molecule-like dynamics, which are frequently called breather molecules. So far, the experimental observation of optical breather molecules and the real-time detection of their dynamics are limited to diatomic molecules, that is, bound states of only two breathers. In this work, the observation of different types of breather complexes in a mode-locked fiber laser: multibreather molecules, and molecular complexes originating from the binding of two breat…
The complex formation of tetracyclohexylammonium C1-resorcinarene with various guests - an electrospray ionization Fourier transform ion cyclotron re…
2008
The complex formation of a tetraammonium C1-resorcinarene (R+4HCl) was studied using electrospray ionization Fourier transform ion cyclotron resonance (ESI-FTICR) mass spectrometry. Although R+4HCl easily loses its counter ions in the ESI process, a neutral self-assembled structure with an intramolecular circular hydrogen-bonded 16-membered -N(+)-H ... X(-) ... H-N(+)- array with ammonium ion as the charge-giving species was observed in the gas phase. In addition to chloride, several other counter ions were also studied. The size and basicity of the counter ion as well as the size of the charge-giving cation strongly affected the gas-phase stability of the self-assembled system. H/D exchang…
One-Pot Synthesis and AFM Imaging of a Triangular Aramide Macrocycle
2014
Macrocyclizations in exceptionally good yields were observed during the self-condensation of N-benzylated phenyl p-aminobenzoates in the presence of LiHMDS to yield three-membered cyclic aramides that adopt a triangular shape. An ortho-alkyloxy side chain on the N-benzyl protecting group is necessary for the macrocyclization to occur. Linear polymers are formed exclusively in the absence of this Li-chelating group. A model that explains the lack of formation of other cyclic congeners and the demand for an N-(o-alkoxybenzyl) protecting group is providedon the basis of DFT calculations.High-resolution AFM imaging of the prepared molecular triangles on a calcite(10.4) surface shows individual …
Case-studies of corroded reinforced concrete bridges in Southern Italy
2020
On Italian roads, a lot of reinforced concrete bridges were built in the 1950’s and 1960’s for short spans, before the advent of prefabricated structures. Many of these bridges, sited on principal or secondary roadways, show the effects of corrosion of reinforcements and high levels of damage, leading to the likelihood of achievement of the Ultimate Limit State, below the required performances of serviceability, especially in the case of Gerber saddles having strongly corroded reinforcements. Different case studies of bridges sited in Southern Italy (Sicily) are shown, allowing engineers to classify the main effects of damage in corroded structures with the Gerber static scheme (cantilever …
Emerging dynamics in surfactant-based liquid mixtures: octanoic acid/bis(2-ethylhexyl) amine systems.
2012
This work focuses on the dynamic phenomena emerging in self-assembled transient intermolecular networks formed when two different surfactants are mixed. In particular, the relaxation processes in liquid mixtures composed by bis(2-ethylhexyl)amine (BEEA) and octanoic acid (OA) in the whole composition range has been investigated by dielectric spectroscopy and Brillouin spectroscopy. A thorough analysis of all the experimental data consistently suggests that, mainly driven by acid-base interactions arising when the two surfactants are mixed, supra-molecular aggregates formation causes the slowing down of molecular dynamics. This, in turn, reflects to longer-range relaxations. These changes ha…
Giant Dzyaloshinskii-Moriya Interaction and Room-Temperature Nanoscale Skyrmions in CoFeB/MgO Heterostructures
2021
Magnetic skyrmions in heavy metal (HM)/CoFeB/MgO structures are of particular interest for skyrmion-based magnetic tunnel junction (MTJ) devices because of their reliable generation, stability and read-out through purely electrical methods. To optimize the properties, such as stability, a strong Dzyaloshinskii-Moriya interaction (DMI) is required at room temperature. Here, using first-principles calculations, we demonstrate that giant DMI can be obtained in Ir/CoFe structures with an Fe-terminated configuration. Moreover, Brillouin light scattering measurements show that indeed Ta/Ir/Co20Fe60B20/MgO thin films with perpendicular magnetic anisotropy exhibit a large DMI value (1.13 mJ/m2), wh…
OH–π and halogen–π interactions as driving forces in the crystal organisations of tri-bromo and tri-iodo trityl alcohols
2008
The trityl alcohols bearing three bromine or three iodine atoms at the para-positions of the aromatic units, have been known for more than a hundred years. In our case these compounds have been synthesized in one-pot sequence starting from the 1,4-dihalogenobenzenes via mono-lithiation and the successive reaction with diethylcarbonate. The compounds have been crystallized from different solvent mixtures leading to one structure of bromo- (A) and three structures of iodo trityl alcohols (B–D). The inclusion of dichloromethane (C) or benzene (D) in the crystalline lattices has been observed. In all cases the OH–π and halogen–π (and in one case the halogen-halogen and CH-O weak) contacts play …
Back EMF Sensorless-Control Algorithm for High-Dynamic Performance PMSM
2010
In this paper, a low-time-consuming and low-cost sensorless-control algorithm for high-dynamic performance permanent-magnet synchronous motors, both surface and internal permanent-magnet mounted for position and speed estimation, is introduced, discussed, and experimentally validated. This control algorithm is based on the estimation of rotor speed and angular position starting from the back electromotive force space-vector determination without voltage sensors by using the reference voltages given by the current controllers instead of the actual ones. This choice obviously introduces some errors that must be vanished by means of a compensating function. The novelties of the proposed estima…
Simplified technique for constitutive analysis of SFRC
2014
Steel fibre reinforced concrete (SFRC) has become widespread material in areas such as underground shotcrete structures and industrial floors. However, due to the absence of material models of SFRC reliable for numerical analysis, application fields of this material are still limited. Due to interaction of concrete with fibres, a cracked section is able to carry a significant portion of tensile stresses, called the residual stresses. In present practices, residual stresses used for strength, deflection and crack width analysis are quantified by means of standard tests. However, interpretation of these test results is based on approximation using empirically deduced relationships, adequacy o…