Search results for "freedom"
showing 10 items of 458 documents
Analysis of multi degree of freedom systems with fractional derivative elements of rational order
2014
In this paper a novel method based on complex eigenanalysis in the state variables domain is proposed to uncouple the set of rational order fractional differential equations governing the dynamics of multi-degree-of-freedom system. The traditional complex eigenanalysis is appropriately modified to be applicable to the coupled fractional differential equations. This is done by expanding the dimension of the problem and solving the system in the state variable domain. Examples of applications are given pertaining to multi-degree-of-freedom systems under both deterministic and stochastic loads.
Strongly confined fluids: Diverging time scales and slowing down of equilibration
2016
The Newtonian dynamics of strongly confined fluids exhibits a rich behavior. Its confined and unconfined degrees of freedom decouple for confinement length $L \to 0$. In that case and for a slit geometry the intermediate scattering functions $S_{\mu\nu}(q,t)$ simplify, resulting for $(\mu,\nu) \neq (0,0)$ in a Knudsen-gas like behavior of the confined degrees of freedom, and otherwise in $S_{\parallel}(q,t)$, describing the structural relaxation of the unconfined ones. Taking the coupling into account we prove that the energy fluctuations relax exponentially. For smooth potentials the relaxation times diverge as $L^{-3}$ and $L^{-4}$, respectively, for the confined and unconfined degrees of…
Differential geometric least angle regression: a differential geometric approach to sparse generalized linear models
2013
Summary Sparsity is an essential feature of many contemporary data problems. Remote sensing, various forms of automated screening and other high throughput measurement devices collect a large amount of information, typically about few independent statistical subjects or units. In certain cases it is reasonable to assume that the underlying process generating the data is itself sparse, in the sense that only a few of the measured variables are involved in the process. We propose an explicit method of monotonically decreasing sparsity for outcomes that can be modelled by an exponential family. In our approach we generalize the equiangular condition in a generalized linear model. Although the …
(H,ρ)-induced dynamics and large time behaviors
2018
Abstract In some recent papers, the so called ( H , ρ ) -induced dynamics of a system S whose time evolution is deduced adopting an operatorial approach, borrowed in part from quantum mechanics, has been introduced. Here, H is the Hamiltonian for S , while ρ is a certain rule applied periodically (or not) on S . The analysis carried on throughout this paper shows that, replacing the Heisenberg dynamics with the ( H , ρ ) -induced one, we obtain a simple, and somehow natural, way to prove that some relevant dynamical variables of S may converge, for large t , to certain asymptotic values. This cannot be so, for finite dimensional systems, if no rule is considered. In this case, in fact, any …
Stochastic seismic analysis of multidegree of freedom systems
1984
Abstract A unconditionally stable step-by-step procedure is proposed to evaluate the mean square response of a linear system with several degrees of freedom, subjected to earthquake ground motion. A non-stationary modulated random process, obtained as the product of a deterministic time envelope function and a stationary noise, is used to simulate earthquake acceleration. The accuracy of the procedure and its extension to nonlinear systems are discussed. Numerical examples are given for a hysteretic system, a duffing oscillator and a linear system with several degrees of freedom.
An Approximate Technique for Dynamic Elastic-Plastic Analysis
1994
The possibility of obtaining an approximate sufficiently reliable response for elasticplastic discretized structures subjected to dynamic load (kinematical and/or mechanical), with alow computational effort, has been considered. A suitable technique to this effect comes from the form of the dynamic influence matrix of imposed plastic strains on self-stresses, which is shaped by adding up a sparse time-dependent matrix and a block diagonal time-independent matrix (which is the sum of two block diagonal matrices). Several cases of practical interest have been studied, among these cases a special one where all the degrees-of-freedom are dynamic. The technique is compared to other approximate t…
Skyrmion formation due to unconventional magnetic modes in anisotropic multiband superconductors
2018
Multiband superconductors have a sufficient number of degrees of freedom to allow topological excitations characterized by Skyrmionic topological invariants. In the most common, clean s-wave multiband, systems the interband magnetic coupling favours composite vortex solutions, without a Skyrmionic topological charge. It was discussed recently that certain kinds of anisotropies lead to hybridisation of the interband phase difference (Leggett) mode with magnetic modes, dramatically changing the hydromagnetostatics of the system. Here we report this effect for a range of parameters that substantially alter the nature of the topological excitations, leading to solutions characterized by a nontr…
Time-domain analysis of electronic spectra in superfluid 4He
2004
Abstract Electronic absorption spectra of impurities in superfluid helium is developed in time domain, using time-dependent density functional theory to describe liquid 4 He and time-dependent perturbation theory to describe the electronic degrees of freedom of the impurity. Angularly isotropic potentials are used to describe the molecule–helium interactions in the ground and excited electronic states. The calculations rationalize experimentally observed phonon side-bands in 4 He droplets and in bulk helium, and allow assignments of spectral features to specific motions of the liquid.
Reaction coordinates and transition states in enzymatic catalysis
2017
Enzymatic reactions are complex chemical processes taking place in complex dynamic environments. Theoretical characterization of these reactions requires the determination of the reaction coordinate and the transition state ensemble. This is not an easy task because many degrees of freedom may be involved in principle. We present recent efforts to find good enzymatic reaction coordinates and the implications of these findings in the interpretation of enzymatic efficiency. In particular, we analyze different strategies based on the use of minimum free energy paths and direct localization of the dividing surface on multidimensional free energy surfaces. Another strategy is based on the genera…
Quantifying the limits of transition state theory in enzymatic catalysis
2017
Significance Transition state theory (TST) is the most popular theory to calculate the rates of enzymatic reactions. However, in some cases TST could fail due to the violation of the nonrecrossing hypothesis at the transition state. In the present work we show that even for one of the most controversial enzymatic reactions—the hydride transfer catalyzed by dihydrofolate reductase—the error associated to TST represents only a minor correction to the reaction rate. Moreover, this error is actually larger for the reaction in solution than in the enzymatic active site. Based on this finding and on previous studies we propose an “enzymatic shielding” hypothesis which encompasses various aspects …