Search results for "functional group"

POSS Grafting on Polyethylene and Maleic Anhydride-Grafted Polyethylene by One-Step Reactive Melt Mixing

2016

This study reports the one-step reactive melt mixing preparation of organic–inorganic hybrid based on maleic anhydride-grafted polyethylene and 3-(2-aminoethyl)aminopropyl-heptaisobutyl substituted polyhedral oligomeric silsesquioxane, (NPOSS), as well as on low-density polyethylene and allyl-heptaisobutyl-POSS (1POSS) in dicumyl peroxide presence, which is believed to activate the unsaturation of the reactive functional group of POSS itself. The successful grafting of POSS molecules onto polymeric backbones was probed through rheological and spectroscopic analysis. Grafting of POSS molecules enhances their dispersion in the polymeric matrix as shown by morphological analysis. Moreover, the…

Material valorisation of amorphous polylactide. Influence of thermo-mechanical degradation on the morphology, segmental dynamics, thermal and mechani…

2012

[EN] This paper reports the effects of multiple mechanical recycling on the structure and properties of amorphous polylactide (PLA). The influence of the thermo-mechanical degradation induced by means of five successive injection cycles was initially addressed in terms of macroscopic mechanical properties and surface modification. A deeper inspection on the structure and morphology of PLA was associated to the thermal properties and viscoelastic behaviour. Although FT-IR analysis did not show significant changes in functional groups, a remarkable reduction in molar mass was found by viscometry. PLA remained amorphous throughout the reprocessing cycles, but the occurrence of a cold-crystalli…

Amphiphilic dyes for nonlinear optics: Dependence of second harmonic generation on functional group substitution

2008

Red sky at night cyanobacteria delight: the role of climate in structuring phytoplankton assemblage in a shallow, Mediterranean lake (Biviere di Gela…

2009

The hypothesis that climate changes may strongly interfere with the peculiar hydrological patterns in the Mediterranean basin and alter the structure of the aquatic biota was tested in a shallow Sicilian lake. A phytoplankton survey, carried out monthly in the brackish and shallow Biviere di Gela, in 2005–2007, revealed a transformation in the structure of its phytoplankton assemblage as compared with similar data collected in 1987–1988. An analysis of the trends followed by precipitation and temperature over the last 40 years, showed reduced water inflows, due to increased air temperature and evapotranspiration rather than to a decrease in the amount of precipitation. A consequent reductio…

Morphological analysis of phytoplankton as a tool to assess ecological state of aquatic ecosystems: the case of Lake Arancio, Sicily, Italy

2013

Phytoplankton requires a sufficient supply of light and nutrients to grow. At the same time it is largely entrained in water motion and is subject to grazing from planktonic herbivores. The pelagic life of lake phytoplankton is based on 4 pillars: living in suspension, light harvesting, nutrient uptake, and escape from grazing. Environmental variability and the uneven distribution of resources among and within the different aquatic ecosystems exert a selective pressure on these organisms, which are formed by a single cell or by colonies with either relatively low or high numbers of cells. Phytoplankton displays an amazing morphological variability representing an adaptation to spatial and t…

Thioetherification of Chloroheteroarenes: A Binuclear Catalyst Promotes Wide Scope and High Functional-Group Tolerance

2014

A constrained binuclear palladium catalyst system affords selective thioetherification of a wide range of functionalized arenethiols with chloroheteroaromatic partners with the highest turnover numbers (TONs) reported to date and tolerates a large variety of reactive functions. The scope of this system includes the coupling of thiophenols with six- and five-membered 2-chloroheteroarenes (i.e., functionalized pyridine, pyrazine, quinoline, pyrimidine, furane, and thiazole) and 3-bromoheteroarenes (i.e., pyridine and furane). Electron-rich congested thiophenols and fluorinated thiophenols are also suitable partners. The coupling of unprotected amino-2-chloropyridines with thiophenol and the s…

Structural and Molecular Characterization of meso-Substituted Zinc Porphyrins: A DFT Supported Study

2011

Structural parameters of a range of over 100 meso-substituted zinc porphyrins were reviewed and compared to show how far the nature of the functional group may affect the interatomic distances and bond angles within the porphyrin core. It was proved that even despite evident deformations of the molecular structure, involving twisting of the porphyrin's central plane, the coupled π-bonding system remains flexible and stable. DFT calculations were applied to a number of selected porphyrins representative for the reviewed compounds to emphasize the relevance of theoretical methods in structural investigations of complex macrocyclic molecular systems. Experimental and DFT-simulated IR spectral …

Phytoplankton responses to human impacts at different scales

2012

This book: Deals with eutrophication impact on ecosystem functioning with a different focus and broader perspective. Takes into account the effects of multiple stressors on microalgal assemblages. Includes specific contributions on the autoecology and taxonomy of dinoflagellates and cyanobacteria. Features examples of applications of the morphology-, morpho-functional and functional groups (FG), (MFG) and (MBFG) Phytoplankton responses to human impact at different scales provides a state-of-the-art review of changes in the phytoplankton assemblages determined by human alterations of lakes and rivers. A wide spectrum of case studies describe the effects due to eutrophication and climate chan…

Building a Functionalizable, Potent Chemiluminescent Agent: A Rational Design Study on 6,8-Substituted Luminol Derivatives.

2021

Luminol is a prominent chemiluminescent (CL) agent, finding applications across numerous fields, including forensics, immunoassays, and imaging. Different substitution patterns on the aromatic ring can enhance or decrease its CL efficiency. We herein report a systematic study on the synthesis and photophysics of all possible 6,8-disubstituted luminol derivatives bearing H, Ph, and/or Me substituents. Their CL responses are monitored at three pH values (8, 10, and 12), thus revealing the architecture with the optimum CL efficiency. The most efficient pattern is used for the synthesis of a strongly CL luminol derivative, bearing a functional group for further, straightforward derivatization. …

Dynamics and reactivity in Thermus aquaticus N6-adenine methyltransferase.

2014

M.TaqI is a DNA methyltransferase from Thermus aquaticus that catalyzes the transfer of a methyl group from S-adenosyl-l-methionine to the N6 position of an adenine, a process described only in prokaryotes. We have used full atomistic classical molecular dynamics simulations to explore the protein–SAM–DNA ternary complex where the target adenine is flipped out into the active site. Key protein–DNA interactions established by the target adenine in the active site are described in detail. The relaxed structure was used for a combined quantum mechanics/molecular mechanics exploration of the reaction mechanism using the string method. According to our free energy calculations the reaction takes…