Search results for "functional"
showing 10 items of 4822 documents
An Efficient Method for the Visualization of Spectral Images Based on a Perception-Oriented Spectrum Segmentation
2010
We propose a new method for the visualization of spectral images. It involves a perception-based spectrum segmentation using an adaptable thresholding of the stretched CIE standard observer colormatching functions. This allows for an underlying removal of irrelevant channels, and, consequently, an alleviation of the computational burden of further processings. Principal Components Analysis is then used in each of the three segments to extract the Red, Green and Blue primaries for final visualization. A comparison framework using two different datasets shows the efficiency of the proposed method.
Motivation and Consequences of Internet and Mobile Phone Usage among the Urban Poor in Kampala, Uganda
2015
The Internet and mobile phones are rapidly diffusing throughout communities, and it is important to understand what people are actually doing with their access to these technologies. This study seeks to improve our understanding of the motivational factors and social and economic consequences of such use among the urban poor, which is examined through the Diffusion of Innovations Theory (DoI) and the Capability Approach (CA). The combined theoretical perspective was introduced to explore findings of an explorative case study conducted among the urban poor in Kampala, Uganda, where Internet access was found to be low due to high illiteracy and associated costs. On the other hand, mobile phon…
Dynamic Stabilization of the Ligand-Metal Interface in Atomically Precise Gold Nanoclusters Au68 and Au144 Protected by meta-Mercaptobenzoic Acid
2017
Ligand-stabilized, atomically precise gold nanoclusters with a metal core of a uniform size of just 1–3 nm constitute an interesting class of nanomaterials with versatile possibilities for applications due to their size-dependent properties and modifiable ligand layers. The key to extending the usability of the clusters in applications is to understand the chemical bonding in the ligand layer as a function of cluster size and ligand structure. Previously, it has been shown that monodispersed gold nanoclusters, stabilized by meta-mercaptobenzoic acid (m-MBA or 3-MBA) ligands and with sizes of 68–144 gold atoms, show ambient stability. Here we show that a combination of nuclear magnetic reson…
Differential proteomics of thyroid carcinoma cell lines
2011
Reliability and Validity of The Finnish Version of The Boston Carpal Tunnel Questionnaire among Surgically Treated Carpal Tunnel Syndrome Patients
2019
Background and Aims: The Boston Carpal Tunnel Questionnaire is the most commonly used outcome measure in the assessment of carpal tunnel syndrome. The purpose of this study was to translate the original Boston Carpal Tunnel Questionnaire into Finnish and validate its psychometric properties. Materials and Methods: We translated and culturally adapted the Boston Carpal Tunnel Questionnaire into Finnish. Subsequently, 193 patients completed the Finnish version of the Boston Carpal Tunnel Questionnaire, 6-Item CTS Symptoms Scale, and EuroQol 5 Dimensions 12 months after carpal tunnel release. The Boston Carpal Tunnel Questionnaire was re-administered after a 2-week interval. We calculated cons…
Density Functional Theory Investigation on the Nucleation and Growth of Small Palladium Clusters on a Hyper-Cross-Linked Polystyrene Matrix
2014
Density functional theory calculations were employed to investigate the nucleation and growth of small palladium clusters, up to Pd9, into a microcavity of the porous hyper-cross-linked polystyrene (HPS). The geometries and the electronic structures of the palladium clusters inside the HPS cavity, following the one-by-one atom addition, are affected by a counterbalance between the Pd–phenyl (Pd−Φ) and Pd–Pd interactions. The analysis performed on energetics, cavity distortions, and cluster geometries indeed suggest that the cluster growth is dominated by the Pd−Φ interactions up to the formation of Pd4 aggregates, whereas the metal–metal interactions actually rule the growth of the larger c…
Selective Acrolein Hydrogenation over Ligand-Protected Gold Clusters : A Venus Flytrap Mechanism
2022
The catalytic partial hydrogenation of α,β-unsaturated aldehydes is an ideal reaction to understand the selectivity between two different functional groups Here the two functional groups are C═C and C═O, and the hydrogenation of C═O is preferentially desired due to the importance of the issuing products, unsaturated alcohols, in fine-chemical industries. Using density functional theory calculations, we investigate the catalytic competency toward this reaction of a Au nanocluster in the presence of protecting ligands that offer higher stability and the possibility for the uniform distribution of size-selected clusters in the catalytic system. meta-Mercaptobenzoic-acid-protected-protected Au …
Variability of the Level of Development of Functopnal Urban Areas
2018
Miejskie obszary funkcjonalne mają istotne znaczenie w realizacji zarówno Krajowej Polityki Miejskiej 2023, jak i terytorialnej polityki rozwoju. Celem badania jest określenie poziomu rozwoju obszarów funkcjonalnych miast wojewódzkich Polski. Badania przeprowadzono z wykorzystaniem metody taksonomicznej w ujęciu dynamicznym obejmującym okres 2005-2015. Podstawę wyznaczenia wielkości taksonomicznych stanowił zestaw wskaźników diagnostycznych ujętych w trzech wymiarach rozwoju: społecznym, gospodarczym i środowiskowym. W ramach badania została podjęta ocena poziomu rozwoju miast centralnych MOF oraz oddzielnie miast i gmin ich otoczenia. Dodatkowo określono poziom rozwoju każdego z wymiarów r…
Reversible self-assembly of metal chalcogenide/metal oxide nanostructures based on Pearson hardness.
2010
Nanotechnology has reached a stage of development where not individual nanoparticles but rather systems of greater complexity are the focus of concern. These complex structures incorporate two or more types of materials, an example of which is the formation of metal–semiconductor hybrids, which effectively combine the properties of both materials. The assembly of multicomponent nanoparticles from constituents with different optical, electrical, magnetic, and chemical properties can lead to novel functionalities that are independent of the individual components and may be tailored to fit a specific application. These applications include such far-reaching challenges as solar energy conversio…
Zum Spannungsverhältnis zwischen ästhetischen und linguistischen Qualitätskriterien literarischer Übersetzungen
2017
Today, literary translation occupies a special place in the translation theory, despite the fact that some researchers consider the dichotomous division within the discipline into literary and non-literary texts as resolved and unjustified. This article is an attempt to present a breakdown of selected aesthetic and linguistic criteria for the quality assessment of literary translations in order to consider, on this basis, the validity of the interdisciplinary approach to the criticism of translation of literary texts. The analysis is focused in particular on the translation quality parameters established by Sigrid Kupsch-Losereit. It is then followed by the reflection on the possibilities t…