Search results for "gla"
showing 10 items of 4378 documents
Positron trapping defects in free-volume investigation of Ge–Ga–S–CsCl glasses
2016
Abstract Evolution of free-volume positron trapping defects caused by crystallization process in (80GeS 2 –20Ga 2 S 3 ) 100−х (СsCl) x , 0 ≤ x ≤ 15 chalcogenide-chalcohalide glasses was studied by positron annihilation lifetime technique. It is established that CsCl additives in Ge–Ga–S glassy matrix transform defect-related component spectra, indicating that the agglomeration of free-volume voids occurs in initial and crystallized (80GeS 2 –20Ga 2 S 3 ) 100−х (СsCl) x , 0 ≤ x ≤ 10 glasses. Void fragmentation in (80GeS 2 –20Ga 2 S 3 ) 85 (СsCl) 15 glass can be associated with loosing of their inner structure. Full crystallization in each of these glasses corresponds to the formation of defe…
High sensitivity characterization of the nonlinear electric susceptibility of a glass ceramic in the microwave range
2019
The nonlinear electric susceptibility of a glass ceramic is characterized in the microwave range by measuring intermodulation of two high-power signals. To achieve the necessary sensitivity for dielectric nonlinearities, the setup ensures that the measured intermodulation can be ascribed to the material under test while all other intermodulation sources are suppressed. This is achieved by coupling three dielectric resonators in a cut-off waveguide. The third order nonlinearity of the glass ceramic is found to be χ3/er = (1.6 ± 0.8) × 10−15 m2/V2 at 950 MHz. The magnitude is comparable to the previously measured high-end sintered ceramics. The power of the intermodulation signal as a functio…
Spark Plasma Sintering of Metallic Glasses
2019
Spark plasma sintering (SPS) of metallic glasses (MG) can be quite different from sintering crystalline metallic alloys. Indeed, MG behave differently with increasing temperature, as they encounter a glass transition and devitrification. Their shaping can thus be compared to what can be performed on thermoplastic polymers. SPS is a promising way to prepare bulk parts from amorphous powders, since it allows very fast heating and cooling rates. It gives an advantage to avoid or limit devitrification of the amorphous phase upon the thermal cycle. However, diffusion mechanisms, which generally control densification, are activated at temperatures that are not compatible with MG structural integr…
Reagent- and Metal-Free Anodic C-C Cross-Coupling of Aniline Derivatives.
2017
The dehydrogenative cross-coupling of aniline derivatives to 2,2′-diaminobiaryls is reported. The oxidation is carried out electrochemically, which avoids the use of metals and reagents. A large variety of biphenyldiamines were thus prepared. The best results were obtained when glassy carbon was used as the anode material. The electrosynthetic reaction is easily performed in an undivided cell at slightly elevated temperature. In addition, common amine protecting groups based on carboxylic acids were employed that can be selectively removed under mild conditions after the cross-coupling, which provides quick and efficient access to important building blocks featuring free amine moieties.
A Search for Ultra-high-energy Neutrinos from TXS 0506+056 Using the Pierre Auger Observatory
2020
Results of a search for ultra-high-energy neutrinos with the Pierre Auger Observatory from the direction of the blazar TXS 0506+056 are presented. They were obtained as part of the follow-up that stemmed from the detection of high-energy neutrinos and gamma rays with IceCube, Fermi-LAT, MAGIC, and other detectors of electromagnetic radiation in several bands. The Pierre Auger Observatory is sensitive to neutrinos in the energy range from 100 PeV to 100 EeV and in the zenith-angle range from θ = 60° to θ = 95°, where the zenith angle is measured from the vertical direction. No neutrinos from the direction of TXS 0506+056 have been found. The results were analyzed in three periods: One of 6 m…
Radiogenic isotopes: new tools help reconstruct paleocean circulation and erosion input
2001
Ocean and atmosphere circulation and continental weathering regimes have undergone great changes over thousands of years as well as tens of millions of years. During the glacial stages of the Pleistocene, ocean circulation was generally more sluggish and deep water circulation in the Atlantic had a shallower flow. At the same time, weathering on the continents was enhanced by glacial erosion, particularly in high northern latitudes, which increased the input of erosional detritus into the ocean. In addition, atmospheric pressure gradients were larger, leading to higher wind speeds and increased supply of aeolian dust to the ocean. Prior to the onset of Northern Hemisphere glaciation and pro…
Hydrological drivers of wetland vegetation community distribution within Everglades National Park, Florida
2010
The influence of hydrological dynamics on vegetation distribution and the structuring of wetland environments is of growing interest as wetlands are modified by human action and the increasing threat from climate change. Hydrological properties have long been considered a driving force in structuring wetland communities. We link hydrological dynamics with vegetation distribution across Everglades National Park (ENP) using two publicly available datasets to study the probability structure of the frequency, duration, and depth of inundation events along with their relationship to vegetation distribution. This study is among the first to show hydrologic structuring of vegetation communities at…
Eustasy and sea water Sr composition: application to high-resolution Sr-isotope stratigraphy of Miocene shallow-water carbonates
2007
Oceanic 87 Sr/ 86 Sr-isotope ratios are strongly influenced by rates of silicate weathering and therefore linked not only to glaciation but also to sea-level change. The present study combines analysis of sequence stratigraphy and basin architecture with Sr-isotope stratigraphy in Miocene shallow-water sediments in southern Portugal and Crete (Greece). The common method is to use smoothed global sea water Sr-isotope reference curves but here a different approach is chosen. Instead, measured Sr-isotope curves are correlated with unsmoothed reference curves by identification of similar fluctuations in the order of several 100 kyr. Transgressive intervals are characterized by increasing Sr-iso…
Holocene land-cover reconstructions for studies on land cover-climate feedbacks
2010
The major objectives of this paper are: (1) to review the pros and cons of the scenarios of past anthropogenic land cover change (ALCC) developed during the last ten years, (2) to discuss issues related to pollen-based reconstruction of the past land-cover and introduce a new method, REVEALS (Regional Estimates of VEgetation Abundance from Large Sites), to infer long-term records of past land-cover from pollen data, (3) to present a new project (LANDCLIM: LAND cover – CLIMate interactions in NW Europe during the Holocene) currently underway, and show preliminary results of REVEALS reconstructions of the regional land-cover in the Czech Republic for five selected time windows of the Holocene…
An improved understanding of the Alaska Coastal Current: the application of a bivalve growth-temperature model to reconstruct freshwater-influenced p…
2011
Shells of intertidal bivalve mollusks contain sub-seasonally to interannually resolved records of temperature and salinity variations in coastal settings. Such data are essential to understand changing land-sea interactions through time, specifically atmospheric (precipitation rate, glacial meltwater, river discharge) and oceanographic circulation patterns; however, independent temperature and salinity proxies are currently not available. We established a model for reconstructing daily water temperatures with an average standard error of ∼1.3 °C based on variations in the width of lunar daily growth increments of Saxidomus gigantea from southwestern Alaska, United States. Temperature explai…