Search results for "gradient"

showing 10 items of 725 documents

Enhancement in the computation of gradient retention times in liquid chromatography using root-finding methods.

2019

Abstract Gradient elution may provide adequate separations within acceptably short times in a single run, by gradually increasing the elution speed. Similarly to isocratic elution, chromatograms can be predicted under any experimental condition, through strategies based on retention models. The most usual approach implies solving an integral equation (i.e., the fundamental equation of gradient elution), which has an analytical solution only for certain combinations of retention model and gradient programme. This limitation can be overcome by using numerical integration, which is a universal approach although at the cost of longer computation times. In this work, several alternatives to impr…

Work (thermodynamics)ChromatographyIsocratic elutionChemistryElutionComputation010401 analytical chemistryOrganic ChemistryGeneral Medicine010402 general chemistry01 natural sciencesBiochemistryIntegral equation0104 chemical sciencesAnalytical ChemistryNumerical integrationGradient elutionRoot-finding algorithmAlgorithmsChromatography LiquidJournal of chromatography. A
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Gradient estimates for solutions to quasilinear elliptic equations with critical sobolev growth and hardy potential

2015

This note is a continuation of the work \cite{CaoXiangYan2014}. We study the following quasilinear elliptic equations \[ -\Delta_{p}u-\frac{\mu}{|x|^{p}}|u|^{p-2}u=Q(x)|u|^{\frac{Np}{N-p}-2}u,\quad\, x\in\mathbb{R}^{N}, \] where $1<p<N,0\leq\mu<\left((N-p)/p\right)^{p}$ and $Q\in L^{\infty}(\R^{N})$. Optimal asymptotic estimates on the gradient of solutions are obtained both at the origin and at the infinity.

Work (thermodynamics)General Mathematicsmedia_common.quotation_subject010102 general mathematicsMathematical analysisGeneral Physics and AstronomyInfinity01 natural sciences010101 applied mathematicsSobolev spaceContinuationMathematics - Analysis of PDEs35J60 35B33FOS: Mathematics0101 mathematicsHardy's inequalityGradient estimateAnalysis of PDEs (math.AP)Mathematicsmedia_commonActa Mathematica Scientia
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The Performance of the Gradient-Like Influence Measure in Generalized Linear Mixed Models

2015

A gradient-like statistic, recently introduced as an influence measure, has been proven to work well in large sample, thanks to its asymptotic properties. In this work, through small-scale simulation schemes, the performance of such a diagnostic measure is further investigated in terms of concordance with the main influence measures used for outlier identification. The simulation studies are performed by using generalized linear mixed models (GLMMs).

Work (thermodynamics)Identification (information)GLMM outliers diagnostics gradient statisticOutlierEconometricsApplied mathematicsSettore SECS-S/01 - StatisticaMeasure (mathematics)StatisticGeneralized linear mixed modelMathematicsLarge sample
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Energy harvesting by waste acid/base neutralization via bipolar membrane reverse electrodialysis

2020

Bipolar Membrane Reverse Electrodialysis (BMRED) can be used to produce electricity exploiting acid-base neutralization, thus representing a valuable route in reusing waste streams. The present work investigates the performance of a lab-scale BMRED module under several operating conditions. By feeding the stack with 1 M HCl and NaOH streams, a maximum power density of ~17 W m−2 was obtained at 100 A m−2 with a 10-triplet stack with a flow velocity of 1 cm s−1, while an energy density of ~10 kWh m−3 acid could be extracted by a complete neutralization. Parasitic currents along feed and drain manifolds significantly affected the performance of the stack when equipped with a higher number of t…

Work (thermodynamics)Settore ING-IND/26 - Teoria Dello Sviluppo Dei Processi ChimiciControl and OptimizationMaterials scienceEnergy Engineering and Power TechnologySalt (chemistry)02 engineering and technology010501 environmental sciencespH gradient; waste to energy; ion-exchange membrane; wastewater valorization; controlled neutralization7. Clean energy01 natural scienceslcsh:TechnologyStack (abstract data type)Reversed electrodialysisWastewater valorizationElectrical and Electronic EngineeringIon-exchange membraneEngineering (miscellaneous)pH gradient0105 earth and related environmental sciencesPower densitychemistry.chemical_classificationRenewable Energy Sustainability and the Environmentlcsh:T021001 nanoscience & nanotechnology6. Clean waterWaste to energyMembraneSettore ING-IND/23 - Chimica Fisica ApplicatachemistryFlow velocityChemical engineeringAcid–base reaction0210 nano-technologyControlled neutralizationEnergy (miscellaneous)
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Effect of different aqueous solutions of pure salts and salt mixtures in reverse electrodialysis systems for closed-loop applications

2018

Abstract Reverse Electrodialysis (RED) in a closed-loop arrangement is a viable way to convert low-grade heat into electric power. The present work experimentally investigates the use of pure salt- and equimolar two salts-water solutions as feeds in a lab-scale RED unit. RED performances were analysed in terms of Open Circuit Voltage (OCV), stack resistance and corrected power density. The pure salts and the mixtures employed were chosen via a computational analysis. Effect of feed solution velocity and concentration was investigated. Results concerning the pure salt-water experiments show that NH4Cl is the most performing salt in the concentration range probed, while higher power density v…

Work (thermodynamics)Settore ING-IND/26 - Teoria Dello Sviluppo Dei Processi ChimiciMaterials scienceAnalytical chemistrySalt (chemistry)Filtration and Separation02 engineering and technology010402 general chemistry7. Clean energy01 natural sciencesBiochemistryStack (abstract data type)Electrical resistance and conductanceReversed electrodialysisGeneral Materials SciencePhysical and Theoretical ChemistryPower densitychemistry.chemical_classificationAqueous solutionOpen-circuit voltage021001 nanoscience & nanotechnology6. Clean water0104 chemical scienceschemistry0210 nano-technologyReverse Electrodialysis Heat Engine Closed loop RED Salt mixture Salinity Gradient PowerJournal of Membrane Science
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An Image Segmentation Algorithm based on Community Detection

2016

International audience; With the recent advances in complex networks, image segmentation becomes one of the most appropriate application areas. In this context, we propose in this paper a new perspective of image segmentation by applying two efficient community detection algorithms. By considering regions as communities, these methods can give an over-segmented image that has many small regions. So, the proposed algorithms are improved to automatically merge those neighboring regions agglomerative to achieve the highest modularity/stability. To produce sizable regions and detect homogeneous communities, we use the combination of a feature based on the Histogram of Oriented Gradients of the …

[ INFO ] Computer Science [cs]Computer scienceComputingMethodologies_IMAGEPROCESSINGANDCOMPUTERVISIONScale-space segmentation02 engineering and technology[INFO.INFO-AI]Computer Science [cs]/Artificial Intelligence [cs.AI]Minimum spanning tree-based segmentationImage texture0202 electrical engineering electronic engineering information engineeringcommunity detection[INFO.INFO-RB]Computer Science [cs]/Robotics [cs.RO]Segmentation[INFO]Computer Science [cs][ INFO.INFO-AI ] Computer Science [cs]/Artificial Intelligence [cs.AI]modularityImage segmentationSegmentation-based object categorizationbusiness.industry[ INFO.INFO-RB ] Computer Science [cs]/Robotics [cs.RO]Pattern recognitionImage segmentationcomplex networksHistogram of oriented gradientsRegion growing020201 artificial intelligence & image processingArtificial intelligencebusiness
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Noise estimation from digital step-model signal

2013

International audience; This paper addresses the noise estimation in the digital domain and proposes a noise estimator based on the step signal model. It is efficient for any distribution of noise because it does not rely only on the smallest amplitudes in the signal or image. The proposed approach uses polarized/directional derivatives and a nonlinear combination of these derivatives to estimate the noise distribution (e.g., Gaussian, Poisson, speckle, etc.). The moments of this measured distribution can be computed and are also calculated theoretically on the basis of noise distribution models. The 1D performances are detailed, and as our work is mostly dedicated to image processing, a 2D…

[ INFO.INFO-TS ] Computer Science [cs]/Signal and Image Processing[INFO.INFO-TS] Computer Science [cs]/Signal and Image Processingstep model02 engineering and technology[ SPI.SIGNAL ] Engineering Sciences [physics]/Signal and Image processingCCD sensornoise distributionsymbols.namesake[INFO.INFO-TS]Computer Science [cs]/Signal and Image Processingdigital signalsalt and pepper noiseStatistics0202 electrical engineering electronic engineering information engineeringMedian filterImage noisePoisson noiseValue noiseNoise estimationMathematics[SPI.SIGNAL] Engineering Sciences [physics]/Signal and Image processingedge modelmultiplicative noiseNoise measurementNoise (signal processing)020206 networking & telecommunicationsComputer Graphics and Computer-Aided DesignNoise floorGaussian white noiseGradient noiseimpulse noiseGaussian noisenonlinear modelsymbols020201 artificial intelligence & image processingnoise estimatorAlgorithm[SPI.SIGNAL]Engineering Sciences [physics]/Signal and Image processingSoftware
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Definition of a mutual reference shape based on information theory and active contours

2013

In this paper, we propose to consider the estimation of a reference shape from a set of different segmentation results using both active contours and information theory. The reference shape is then defined as the minimum of a criterion that benefits from both the mutual information and the joint entropy of the input segmentations. This energy criterion is here justified using similarities between information theory quantities and area measures, and presented in a continuous variational framework. This framework brings out some interesting evaluation measures such as the specificity and sensitivity. In order to solve this shape optimization problem, shape derivatives are computed for each te…

[ INFO.INFO-TS ] Computer Science [cs]/Signal and Image Processingsegmentation evaluation[ INFO.INFO-IM ] Computer Science [cs]/Medical Imaging[INFO.INFO-TS] Computer Science [cs]/Signal and Image Processingaverage shape[SDV.IB.IMA]Life Sciences [q-bio]/Bioengineering/Imaging[INFO.INFO-IM] Computer Science [cs]/Medical ImagingComputingMethodologies_IMAGEPROCESSINGANDCOMPUTERVISION[ SPI.SIGNAL ] Engineering Sciences [physics]/Signal and Image processingactive contours[SDV.IB.IMA] Life Sciences [q-bio]/Bioengineering/Imaging[INFO.INFO-TI] Computer Science [cs]/Image Processing [eess.IV]shape gradientsImage processingcardiac MRI.[INFO.INFO-TS]Computer Science [cs]/Signal and Image Processing[INFO.INFO-TI]Computer Science [cs]/Image Processing [eess.IV][ INFO.INFO-TI ] Computer Science [cs]/Image Processingshape optimizationcardiac MRI[INFO.INFO-IM]Computer Science [cs]/Medical Imaging[SPI.SIGNAL]Engineering Sciences [physics]/Signal and Image processing[ SDV.IB.IMA ] Life Sciences [q-bio]/Bioengineering/Imaging[SPI.SIGNAL] Engineering Sciences [physics]/Signal and Image processinginformation theory
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3-manifolds which are orbit spaces of diffeomorphisms

2008

Abstract In a very general setting, we show that a 3-manifold obtained as the orbit space of the basin of a topological attractor is either S 2 × S 1 or irreducible. We then study in more detail the topology of a class of 3-manifolds which are also orbit spaces and arise as invariants of gradient-like diffeomorphisms (in dimension 3). Up to a finite number of exceptions, which we explicitly describe, all these manifolds are Haken and, by changing the diffeomorphism by a finite power, all the Seifert components of the Jaco–Shalen–Johannson decomposition of these manifolds are made into product circle bundles.

[ MATH.MATH-GT ] Mathematics [math]/Geometric Topology [math.GT]Seifert fibrationsClass (set theory)Pure mathematicsGradient-like diffeomorphism[ MATH.MATH-DS ] Mathematics [math]/Dynamical Systems [math.DS]Dimension (graph theory)[MATH.MATH-DS]Mathematics [math]/Dynamical Systems [math.DS][MATH.MATH-DS] Mathematics [math]/Dynamical Systems [math.DS]Space (mathematics)01 natural sciences[MATH.MATH-GT]Mathematics [math]/Geometric Topology [math.GT]0103 physical sciencesAttractorJaco–Shalen–Johannson decomposition0101 mathematicsFinite setMathematics::Symplectic Geometry[MATH.MATH-GT] Mathematics [math]/Geometric Topology [math.GT]Mathematics010102 general mathematicsMathematical analysisMathematics::Geometric Topology3-manifoldsProduct (mathematics)010307 mathematical physicsGeometry and TopologyDiffeomorphismOrbit (control theory)
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Elaboration de matériaux à gradient de propriétés fonctionnelles pour les composants face au plasma des machines de fusion thermonucléaires

2014

The objective of this study was to develop a Functionally Graded Material (FGM) W / Cu to replace the compliance layer (Cu-OFHC) in the plasma facing components of thermonuclear fusion reactor like ITER. The peculiarity of this work is to elaborate these materials without exceeding the melting temperature of copper in order to control its microstructure. The co-sintering is the most attractive solution to achieve this goal.The first phase of this study has been to decrease the sintering temperature of the tungsten to achieve this co-sintering. The elaboration of a Functionally Graded Materials being delicate, thermo-mechanical calculations were performed in order to determine the number and…

[ PHYS.PHYS.PHYS-CHEM-PH ] Physics [physics]/Physics [physics]/Chemical Physics [physics.chem-ph]Métallurgie des poudresLoi des mélangesTungstèneCuivre[PHYS.PHYS.PHYS-CHEM-PH]Physics [physics]/Physics [physics]/Chemical Physics [physics.chem-ph]Finite Element ModelingPlasma facing componentsFusion thermonucléaire[PHYS.PHYS.PHYS-CHEM-PH] Physics [physics]/Physics [physics]/Chemical Physics [physics.chem-ph]Composants Face au PlasmaMatériaux à Gradient de propriétés FonctionnellesSpark Plasma Sintering
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