Search results for "graphe"
showing 10 items of 563 documents
Bilayer graphene lattice-layer entanglement in the presence of non-Markovian phase noise
2018
The evolution of single particle excitations of bilayer graphene under effects of non-Markovian noise is described with focus on the decoherence process of lattice-layer (LL) maximally entangled states. Once that the noiseless dynamics of an arbitrary initial state is identified by the correspondence between the tight-binding Hamiltonian for the AB-stacked bilayer graphene and the Dirac equation -- which includes pseudovector- and tensor-like field interactions -- the noisy environment is described as random fluctuations on bias voltage and mass terms. The inclusion of noisy dynamics reproduces the Ornstein-Uhlenbeck processes: a non-Markovian noise model with a well-defined Markovian limit…
The fate of the resonating valence bond in graphene
2011
We apply a variational wave function capable of describing qualitatively and quantitatively the so called "resonating valence bond" in realistic materials, by improving standard ab initio calculations by means of quantum Monte Carlo methods. In this framework we clearly identify the Kekul\'e and Dewar contributions to the chemical bond of the benzene molecule, and we establish the corresponding resonating valence bond energy of these well known structures ($\simeq 0.01$eV/atom). We apply this method to unveil the nature of the chemical bond in undoped graphene and show that this picture remains only within a small "resonance length" of few atomic units.
Introduction to Spintronics
2015
Spintronics was born in 1988 with the discovery of GMR provided simultaneously by A. Fert and P. Grunberg and rewarded in 2007 with the Nobel Prize in Physics. This field has since been largely exploited on the market, for example it has been at the base of every hard disk read head. Spintronics field is extremely active and interesting from both a fundamental point of view and for technological applications. Currently, with the aim at new functionalities, there is an increased activity from materials research perspective to understand and develop spintronics devices using materials with new properties like carbon nanotubes, graphene, topological insulators and molecules. This chapter will …
Robust Two-Dimensional Electronic Properties in Three-Dimensional Microstructures of Rotationally Stacked Turbostratic Graphene
2017
We report on the electronic properties of turbostratic graphitic microdisks, rotationally stacked systems of graphene layers, where interlayer twisting leads to electronic decoupling resulting in charge-transport properties that retain the two dimensionality of graphene, despite the presence of a large number of layers. A key fingerprint of this reduced dimensionality is the effect of weak charge-carrier localization that we observe at low temperatures. The disks' resistivity measured as a function of magnetic field changes its shape from parabolic at room temperature to linear at a temperature of 2.7 K indicating further this type of two-dimensional transport. Compared to Bernal stacked gr…
Multi-frequency super-scattering from sub-wavelength graphene-coated nanotubes
2019
A cylindrical multilayered structure with three coupled graphene shells is shown to behave as a dual-band super-scatterer at mid-infrared frequencies. Under the 2D plasmonic nature of graphene material, multiple scattering resonances are attained in the deep subwavelength regime using an isotropic material. In the proposed structure, we efficiently exploit the existing three plasmonic resonances in each scattering channel. These resonances are tailored by dispersion engineering, which is simply displayed through the Bohr model applied to the associated planar structure. For the super-scatterer design, it is essential that the resonances of multiple channels coincide in a single frequency. H…
C3N4/reduced graphene oxide photocatalysts loaded with Ag or Ag/Pt for H2 evolution from aqueous solution of triethanolamine
2023
Composites of C3N4/reduced graphene oxide have been used as photocatalysts for triethanolamine photo- reforming with H2 generation in aqueous solution. The rate of H2 production over the Ag loaded best per- forming photocatalyst reached 525 μmol⋅h
Preparation and characterization of PCL/GO-g-PEG biocomposite nanofiber scaffolds
2016
Biocomposite nanofiber scaffolds of polycaprolactone (PCL) with different graphene oxide surface grafted with poly(ethylene glycol) (GO-g-PEG) concentrations were prepared by electrospinning. Morphological, mechanical as well as wettability characterization were carried out. Results showed that the average diameter of PLA/GO-g-PEG electrospun nanofibers increased by increasing the filler content. GO-g-PEG enhanced the electrospun PCL hydrophilicity as well as the Young modulus, in particular at low GO-g-PEG concentrations.
Advanced piezoresistive sensor achieved by amphiphilic nanointerfaces of graphene oxide and biodegradable polymer blends
2018
This work focuses on the preparation of a piezoresistive sensor device, by exploiting an amphiphilic sample of graphene oxide (GO) as a compatibilizer for poly (lactic acid) (PLA)-Poly (ethylene-glycol) (PEG) blends. The presence of GO determined a high stiffening and strengthening effect, without affecting toughness, and allowed a good stability of mechanical properties up to 40 days. Moreover, GO endowed the materials with electrical properties highly sensitive to pressure and strain variations: the biodegradable pressure sensor showed a responsivity of 35 μA/MPa from 0.6 to 8.5 MPa, a responsivity around 19 μA/MPa from 8.5 to 25 MPa. For lower pressure values (around 0.16–0.45 MPa), inst…
Biotin-Containing Reduced Graphene Oxide-Based Nanosystem as a Multieffect Anticancer Agent: Combining Hyperthermia with Targeted Chemotherapy
2015
Among the relevant properties of graphene derivatives, their ability of acting as an energy-converting device so as to produce heat (i.e., thermoablation and hyperthermia) was more recently taken into account for the treatment of solid tumors. In this pioneering study, for the first time, the in vitro RGO-induced hyperthermia was assessed and combined with the stimuli-sensitive anticancer effect of a biotinylated inulin-doxorubicin conjugate (CJ-PEGBT), hence, getting to a nanosystem endowed with synergic anticancer effects and high specificity. CJ-PEGBT was synthesized by linking pentynoic acid and citraconic acid to inulin. The citraconylamide pendants, used as pH reversible spacer, were …
Light-induced anomalous Hall effect in massless Dirac fermion systems and topological insulators with dissipation
2019
Employing the quantum Liouville equation with phenomenological dissipation, we investigate the transport properties of massless and massive Dirac fermion systems that mimics graphene and topological insulators, respectively. The massless Dirac fermion system does not show an intrinsic Hall effect, but it shows a Hall current under the presence of circularly-polarized laser fields as a nature of a optically-driven nonequilibrium state. Based on the microscopic analysis, we find that the light-induced Hall effect mainly originates from the imbalance of photocarrier distribution in momentum space although the emergent Floquet–Berry curvature also has a non-zero contribution. We further compute…