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showing 10 items of 2432 documents
Structure–property relationship of isomeric diphenylethenyl-disubstituted dimethoxycarbazoles
2015
Isomeric 3,6-dimethoxy- and 2,7-dimethoxycarbazoles containing diphenylethenyl moieties were synthesized by condensation of the appropriate dimethoxycarbazoles with diphenylacetaldehyde. The solid-state structures and the molecular order of the compounds were proven by X-ray crystallography. Both compounds were found to be capable of glass formation with comparable glass transition temperatures (70–71 °C). They exhibited high thermal stabilities, with the 5% weight loss temperatures exceeding 375 °C. The isomer having diphenylethenyl groups at C-3 and C-6 positions and methoxy groups at C-2 and C-7 positions (3a) exhibited aggregation-induced emission (AIE), while its counterpart having dip…
Switching nuclearity and Co(II) content through stoichiometry adjustment: {Co(II)6Co(III)3} and {Co(II)Co4(III)} mixed valent complexes and a study o…
2015
We are reporting two new mixed valent Co(ii)/Co(iii) polynuclear complexes, {Co II 6 Co III 3 } and {Co II Co III 4 }, bearing different amount of Co(ii) ions in their cores, through the employment of the multidentate triethanolamine (teaH 3 ) ligand in different stoichiometric ratios. We present a complete picture of the magnetic behaviour of both complexes through a combined usage of the susceptibility, magnetization and X-band EPR data as well as broken-symmetry DFT calculations. Compound 1 shows an atypical spin-only behaviour, probably due to the presence of four and five coordinated Co(ii) sites as well as highly distorted six coordinated Co(ii) ions, promoting a high degree of orbita…
Ruralità mediate Costruzione simbolica della ruralità nello studio delle rappresentazioni dell’offerta agrituristica nella provincia di Palermo
2006
I Gruppi ospitanti (hosts) e i gruppi ospiti (guests) sono da considerarsi pertanto come poli dialogici di una simbolica della ruralità radicata nel desiderio nostalgico del ritorno alle radici e all’idillio, costruita sulle rappresentazioni di forme alternative di consumo e produzione, di standard di vita, e di valori che offrono nuove relazioni morali, estetiche e sociali. Queste immagini, proiettate da e su una certa località, concorrono a divenire nuove fonti di definizione dell’identità spesso costruite sulla dialettica autenticità-inautenticità quale istanza che contribuisce alla negoziazione e ri-negoziazione dei siti turistici (rurali). Il par. 1.6 passa in rassegna le principali te…
Intermolecular potential and rovibrational states of the H2O–D2 complex
2012
International audience; A five-dimensional intermolecular potential for H2O-D-2 was obtained from the full nine-dimensional ab initio potential surface of Valiron et al. [P. Valiron, M. Wernli, A. Faure, L. Wiesenfeld, C. Rist, S. Kedzuch, J. Noga, J. Chem. Phys. 129 (2008) 134306] by averaging over the ground state vibrational wave functions of H2O and D-2. On this five-dimensional potential with a well depth D-e of 232.12 cm (1) we calculated the bound rovibrational levels of H2O-D-2 for total angular momentum J = 0-3. The method used to compute the rovibrational levels is similar to a scattering approach-it involves a basis of coupled free rotor wave functions for the hindered internal r…
Electron paramagnetic resonance of doped and undoped BaFBr detected by recombination luminescence
1998
Abstract The recombination processes in the X-ray storage phosphor BaFBr:Eu2+ was investigated by measuring the microwave-induced changes in the recombination luminescence in a (high) magnetic field. Besides the resonances of the F(Br−) centre, of the VK(Br−2) centre and of the Eu2+ ground state we observed a line of a hitherto unknown hole centre. The maximum of the luminescence band in which the VK(Br−2) centre could be detected was about 400 nm. The resonance of the unknown hole centre belongs to a luminescence band peaking at about 350 nm.
Magnetooptical studies of defects and recombination luminescence in LiBaF3
2004
Abstract Optically detected EPR investigations have been performed on the recombination luminescence (RL-EPR) of LiBaF3 crystal, X-irradiated at T=4.2 K . RL-EPR lines of VK- centres were found, as well as further lines of a defect with S= 1 2 and an axial g-tensor with its main axis along a [1 0 0] direction of the crystal. Measurements of the magnetic circular dichroism of the absorption (MCDA) have been performed on LiBaF3 crystals X-irradiated at two temperatures ( 4.2 K and RT). After irradiation at T=4.2 K , the main MCDA bands peak at 453 and 500 nm , but after irradiation at T=300 K , the main bands peak at 444 and 390 nm , there is a change of the sign between the peaks in both cas…
Localised transitions in luminescence of AlN ceramics
2014
Abstract The photoluminescence (PL) and thermoluminescence (TL) properties of AlN ceramics revealed under UV irradiation are determined mainly by oxygen-related centres, giving rise to the UV (around 3.18 eV) and the Blue (2.58 eV) bands. It was found that the UV irradiation-generated donor–acceptor pairs (DAPs), responsible for the UV emission band, are randomly distributed with regard to separation distance. Luminescence properties of AlN are interpreted basing on the model of localised recombination involving electron tunnel transitions from the excited state of D to the ground state of A, proposed by Jain et al. (2012) . The observed features of PL, afterglow and TL of AlN ceramics are …
The CoSMOS L-band experiment in Southeast Australia
2007
The CoSMOS (Campaign for validating the Operation of the Soil Moisture and Ocean Salinity mission) campaign was conducted during November of 2005 in the Goulburn River Catchment, in SE Australia. The main objective of CoSMOS was to obtain a series of L-band measurements from the air in order to validate the L-band emission model that will be used by the SMOS (Soil Moisture and Ocean Salinity) ground segment processor. In addition, the campaign was designed to investigate open questions including the Sun-glint effect over land, the application of polarimetric measurements over land, and to clarify the importance of dew and interception for soil moisture retrievals. This paper summarises the …
Nanoparticles and their influence on radionuclide mobility in deep geological formations
2012
International audience; This article gives an overview of the current status of knowledge concerning the role of nanoparticles (inorganic and organic) in deep geological host rocks and the potential influence of these nanoparticles on radionuclide migration in far-field systems. The manuscript is not intended to be a full review paper or overview paper concerning nanoparticles, here the intention is to refer to recent publications but to highlight the progress made in the 6th framework project IP FUNMIG (Fundamental processes of radionuclide migration) and the open literature over the past 5 a concerning the process understanding of nanoparticle related issues in the three host rock formati…
Radon and material radiopurity assessment for the NEXT double beta decay experiment
2015
Artículo escrito por un elevado número de autores, solo se referencian el que aparece en primer lugar, el nombre del grupo de colaboración, si le hubiere, y los autores pertenecientes a la UAM