Search results for "harvest"

showing 10 items of 418 documents

Metal Dependence on the Bidirectionality and Reversibility of the Singlet Energy Transfer in Artificial Special Pair-Containing Dyads

2017

International audience; The demetalation of a precursor dyad, 3, built upon a zinc(II)-containing artificial special pair and free-base antenna, leads to a new dyad, 4, for singlet energy transfer composed of cofacial free-base porphyrins (acceptor), [Fb](2) bridged by a 1,4-C6H4 group to a free-base antenna (donor), [Fb]. This dyad exhibits the general structure [M](2)-C6H4-[Fb], where [M](2) = [Fh](2), and completes a series reported earlier, where [M](2) = [Mg](2) (2) and [Zn](2) (3). The latter dyads exhibit a bidirectional energy-transfer process at 298 K for 2 and at 77 K for 3. Interestingly, a very scarce case of cycling process is observed for the zinc-containing dyad at 298 K. The…

cofacial bisporphyrin dyadsStereochemistryEnergy transferchemistry.chemical_elementZinc[CHIM.INOR]Chemical Sciences/Inorganic chemistry010402 general chemistry01 natural sciencesphotoinduced electron-transferInorganic ChemistryMetalmolecular-orbital methodsMolecular orbitalSinglet statePhysical and Theoretical Chemistryphotosynthetic reaction-centerdensity-functional theoryvalence basis-setsbase hybrid diporphyrins010405 organic chemistry[ CHIM.INOR ] Chemical Sciences/Inorganic chemistryResonance (chemistry)Acceptor0104 chemical sciencesCrystallographychemistrylight-harvesting systemsvisual_artpolarizable continuum modelvisual_art.visual_art_mediumDensity functional theoryextended basis-sets
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Emergent ultrafast phenomena in correlated oxides and heterostructures

2017

The possibility of investigating the dynamics of solids on timescales faster than the thermalization of the internal degrees of freedom has disclosed novel non-equilibrium phenomena that have no counterpart at equilibrium. Transition metal oxides (TMOs) provide an interesting playground in which the correlations among the charges in the metal $d$-orbitals give rise to a wealth of intriguing electronic and thermodynamic properties involving the spin, charge, lattice and orbital orders. Furthermore, the physical properties of TMOs can be engineered at the atomic level, thus providing the platform to investigate the transport phenomena on timescales of the order of the intrinsic decoherence ti…

coherent transportFOS: Physical sciences02 engineering and technologySettore FIS/03 - FISICA DELLA MATERIA01 natural sciencesCondensed Matter - Strongly Correlated ElectronsPhysics and Astronomy (all)electronic coherenceTransition metalAtomic and Molecular PhysicsLattice (order)0103 physical sciencesMesoscale and Nanoscale Physics (cond-mat.mes-hall)coherent transport; electronic coherence; heterostructures; photon harvesting; pump probe; transition metal oxides; ultrafast dynamics; Atomic and Molecular Physics and Optics; Mathematical Physics; Condensed Matter Physics; Physics and Astronomy (all)transition metal oxides010306 general physicsAnisotropyQuantumMathematical PhysicsPhysicsCondensed Matter - Materials ScienceCondensed Matter - Mesoscale and Nanoscale PhysicsStrongly Correlated Electrons (cond-mat.str-el)Mott insulatorMaterials Science (cond-mat.mtrl-sci)Heterojunction021001 nanoscience & nanotechnologyCondensed Matter PhysicsAtomic and Molecular Physics and Opticsultrafast dynamicsThermalisationheterostructuresChemical physicsphoton harvestingpump probeand Optics0210 nano-technologyTransport phenomenacoherent transport; electronic coherence; heterostructures; photon harvesting; pump probe; transition metal oxides; ultrafast dynamics;
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Coherent Light Harvesting through Strong Coupling to Confined Light

2018

When photoactive molecules interact strongly with confined light modes, new hybrid light-matter states may form: the polaritons. These polaritons are coherent superpositions of excitations of the molecules and of the cavity photon. Recently, polaritons were shown to mediate energy transfer between chromophores at distances beyond the Förster limit. Here we explore the potential of strong coupling for light-harvesting applications by means of atomistic molecular dynamics simulations of mixtures of photoreactive and non-photo-reactive molecules strongly coupled to a single confined light mode. These molecules are spatially separated and present at different concentrations. Our simulations sug…

confined lightcoherent light harvestingstrong couplingvalokemiaPhysics::Chemical Physicspolaritonit
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Use of a portable VIS NIR device to predict table olives quality

2019

There is a growing interest today in high-quality and sustainable production especially in the agro-food sector where the use of automated, precise and non-destructive monitoring analytical systems is spreading more and more. In table olives consumption colour and texture are very important quality attributes deriving from ripening, size of the cell wall, middle lamella and fibrous tissues that can be compromised by bruising during harvest operations or postharvest handling. Mechanical damage also accelerates physiological processes, which lead to senescence, spoilage and loss of nutritional value. Nocellara del Belice cultivar is one of the most important table olive varieties in Italy bot…

damage fruit firmness postharvestSettore AGR/09 - Meccanica Agraria
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Combined dynamics of the 500–600 nm leaf absorption and chlorophyll fluorescence changes in vivo: Evidence for the multifunctional energy quenching r…

2021

Carotenoids (Cars) regulate the energy flow towards the reaction centres in a versatile way whereby the switch between energy harvesting and dissipation is strongly modulated by the operation of the xanthophyll cycles. However, the cascade of molecular mechanisms during the change from light harvesting to energy dissipation remains spectrally poorly understood. By characterizing the in vivo absorbance changes (Delta A) of leaves from four species in the 500-600 nm range through a Gaussian decomposition, while measuring passively simultaneous Chla fluorescence (F) changes, we present a direct observation of the quick antenna adjustments during a 3-min dark-to-high-light induction. Underlying…

delta-pH0106 biological sciencesBiophysicsxanthophyll cyclesXanthophyllslight-harvesting complex01 natural sciencesBiochemistryFluorescenceEnergy quenchingAbsorbanceabsorbency changes03 medical and health scienceschemistry.chemical_compoundSpectroscopyChlorophyll fluorescenceantheraxanthin030304 developmental biologychemistry.chemical_classification4112 Forestrya fluorescence0303 health sciencesChlorophyll AAntheraxanthincarotenoidsdissipationCell BiologyFluorescencephotoprotectionzeaxanthinchemistrysinglet excited chlaChemical physicsExcited stateXanthophylldynamic quenchingleavesspectral fittinglutein epoxide cycle010606 plant biology & botanyBiochimica et Biophysica Acta (BBA) - Bioenergetics
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Hydrolate and EO Application to Reduce Decay of Carica papaya during Storage

2023

Postharvest fruit loss is caused by the absence of advanced handling and storage technologies and the quiescent presence of fungal pathogens. Therefore, there is a growing demand for sustainable decisions for the planet. This study focused on the use of two types of edible coatings: one was based on the essential oil of Origanum vulgare L. subsp. viridulum with Aloe arborescens Mill. gel (EC1), and the other was based on the hydrolate only (EC2). These treatments were applied to provide defense against fungal infections in papaya (Carica papaya L. cv Solo), and the storage time was 25 days (T5 ± 1 °C). Fruits coated with EC1 were more contaminated with fungal pathogens than both control (CT…

edible coatingsfood wastedecay indexactive compounds edible coatingactive compoundsPlant ScienceHorticulturefood qualitypostharvest
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Implementation of a wireless instrumented sphere for fruit processing

2020

The aim of this study was to implement a wireless instrumented sphere to study the critical points in a citrus packing line by real-time measuring the impacts experienced by fruits. The noncommercial device was based on a MEMS (microelectro-mechanical system) sensor node with a sensing range from ±1 g to ±400 g (g = 9.8 m s-2), a ferroelectric RAM (FRAM) memory, a radio frequency (RF) transmitter, a microcontroller, and a 75 mAh lithium battery. The sensor node was placed inside an appropriate case with a total weight of 100 g to represent a 'Tardivo di Ciaculli' mandarin. An FR receiver allowed real-time transmission of the measured data. Total acceleration values, representing the stresse…

electronic fruit post harvest triaxial accelerometerSettore AGR/09 - Meccanica Agraria
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Transmission Optimization and Resource Allocation for Wireless Powered Dense Vehicle Area Network With Energy Recycling

2022

The wireless-powered communication paradigm brings self-sustainability to the on-vehicle sensors by harvesting the energy from radiated radio frequency (RF) signals. This paper proposes a novel transmission and resource allocation strategy for the scenario where multiple wireless powered vehicle area networks (VAN) co-existed with high density. The considered multi-VAN system consists of a remote master access point (MAP), multiple on-vehicle hybrid access points (HAPs) and sensors. Unlike previous works, we consider that the sensors can recycle the radiated radio frequency energy from all the HAPs when HAPs communicate with MAP, so the dedicated signals for energy harvesting (EH) are unnec…

energy harvestingComputer Networks and Communicationskulkuneuvotekniikkasensoriverkotdense networkAerospace Engineeringresursointienergian kerääminenwireless powered networklangaton tiedonsiirtooptimointithroughput maximizationAutomotive EngineeringElectrical and Electronic Engineeringlangattomat verkotIEEE Transactions on Vehicular Technology
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A New Solution for Sea Wave Energy Harvesting, the Proposal of an Ironless Linear Generator

2020

The paper investigates an innovative ironless linear generator, installable inside a wave energy converter, in order to produce electricity from sea waves. This energy source is considered strategic for the future, especially in small islands

energy harvestingComputer scienceStator020209 energyMechanical engineeringOcean Engineering02 engineering and technologySettore ING-IND/32 - Convertitori Macchine E Azionamenti Elettricilaw.inventionlcsh:Oceanographylcsh:VM1-989lawLinear congruential generatorpoint absorber0202 electrical engineering electronic engineering information engineeringlcsh:GC1-1581sea waveWater Science and TechnologyCivil and Structural EngineeringSettore ING-IND/11 - Fisica Tecnica AmbientaleMathematical modelbusiness.industry020208 electrical & electronic engineeringlcsh:Naval architecture. Shipbuilding. Marine engineeringlinear generatorMagnetElectricityEnergy sourcebusinessEnergy harvestingVoltageJournal of Marine Science and Engineering
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An Energy-Autonomous Wireless Sensor with Simultaneous Energy Harvesting and Ambient Light Sensing

2021

Wireless sensor nodes (WSNs) are generally powered by batteries, which results in a substantial limitation to the places where the nodes can be installed, to the maximum number of deployable devices, and to the node lifetime. To meet the demand for Internet-of-Things (IoT) applications that require a large number of maintenance-free, low cost, wireless sensor nodes, this paper proposes a wireless sensor platform with a single photovoltaic transducer that performs the dual role of harvesting energy and sensing ambient light. This dual use allows even smaller and cheaper nodes that do not require any form of supporting external power, with a reduced component count. The device implements off-…

energy harvestingComputer sciencetime measurementsensors01 natural sciencesSettore ING-INF/01 - Elettronicaphase measurementpowerPrinted circuit boardwireless sensor networkbluetooth low energyWirelessBluetooth Low Energy Energy harvesting Internet of Things (IoT) light sensors low power Microcontroller Wireless Sensor Network Wireless Sensor Node Home AutomationElectrical and Electronic Engineeringwireless sensor networksInstrumentationlow powerbusiness.industry010401 analytical chemistryPhotovoltaic systemElectrical engineeringlight sensorswireless communication0104 chemical sciencesMicrocontrollerinternet of things (iot)Transducermicrocontrollerphotovoltaic systemswireless sensor nodehome automationNode (circuits)businessEnergy harvestingWireless sensor network
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