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Preliminary investigation into temporal variation of volcanic ash adherent water-soluble components at Stromboli volcano during 2004-2009 eruptive ac…

2009

A change in the chemical compositions of volcanic gases is one of the noticeable phenomena that frequently occurs prior to an eruption. Tephra in plumes can absorb and thereby rapidly deposit volatiles including sulphur, halogen and metal species. These may then be leached (e.g. by rainfall), potentially releasing heavy loads into soils and water bodies. Their analysis is a suitable supplement for remote monitoring of volcanic gases from inaccessible volcanoes. Freshly fallen ashes of the eruptive activity from 2004 to 2009 at Stromboli volcano were sampled, leached and analysed for major and trace elements. This study is aimed at determining the causes of the compositional variations of th…

Ash-leachatesulphur.volcanic plumetephraSettore GEO/08 - Geochimica E Vulcanologia
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Leachate analyses of volcanic ashes from Stromboli volcano: A proxy for the volcanic gas plume composition?

2011

[1] Many volcanoes show a change in chemical composition of the gas phase prior to periods of eruptive activity. Fine-grained tephra erupted from active vents and transported through volcanic plumes can adsorb, and therefore rapidly scavenge, volatile elements such as sulfur, halogens, and metal species in the form of soluble salts adhering to ash surfaces. Analysis of such water-soluble surface materials is a suitable supplement for remote monitoring of volcanic gases at inaccessible volcanoes. In this work, ash samples of the 2004 to 2009 eruptive activity of Stromboli volcano were sampled, leached, and analyzed for major and trace elements. Data analysis and interpretation was focused on…

Atmospheric ScienceGeochemistrySoil ScienceAquatic ScienceOceanographyash leacheates; StromboliVolcanic GasesGeochemistry and PetrologyEarth and Planetary Sciences (miscellaneous)eventStromboliLeachateTephraVolatilesChemical compositionEarth-Surface ProcessesWater Science and Technologyevent.disaster_typegeographygeography.geographical_feature_categoryEcologyPaleontologyForestryPlumeGeophysicsVolcanoSpace and Planetary Scienceash leacheateGeologyVolcanic ashJournal of Geophysical Research
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Mixing relationships and the effects of secondary alteration in the Wishstone and Watchtower Classes of Husband Hill, Gusev Crater, Mars

2006

[1] The Wishstone and Watchtower Class rocks on Husband Hill preserve evidence for a geochemical relationship consistent with two-component mixing between a high Al 2 O 3 , TiO 2 , CaO, Na 2 O, P 2 O 5 end-member and a second end-member enriched in the elements MgO, Zn, S, Br, and Cl. The first end-member appears to be reasonably well represented by rocks of the Wishstone Class, while the second end-member is consistent with a chemical component, not represented by any lithology encountered by Spirit. The Watchtower Class appears to be an intermediate in the mixture. The concentration of the redox sensitive elements Fe and Mn display no systematic variation between rock classes, and the Fe-…

Atmospheric ScienceLithologyAnalytical chemistrySoil ScienceMineralogyWeatheringAquatic ScienceOceanographychemistry.chemical_compoundImpact craterGeochemistry and PetrologyEarth and Planetary Sciences (miscellaneous)SulfateDissolutionEarth-Surface ProcessesWater Science and TechnologyEcologyPaleontologyForestryPhosphateGeophysicschemistrySpace and Planetary ScienceSoil waterSedimentary rockGeologyJournal of Geophysical Research: Planets
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The primary volcanic aerosol emission from Mt Etna: Size-resolved particles with SO2 and role in plume reactive halogen chemistry

2018

International audience; Volcanoes are an important source of aerosols to the troposphere. Within minutes after emission, volcanic plume aerosol catalyses conversion of co-emitted HBr, HCl into highly reactive halogens (e.g. BrO, OClO) through chemical cycles that cause substantial ozone depletion in the dispersing downwind plume.This study quantifies the sub-to-supramicron primary volcanic aerosol emission (0.2-5 μm diameter) and its role in this process. An in-situ ground-based study at Mt Etna (Italy) during passive degassing co-deployed an optical particle counter and Multi-Gas SO2 sensors at high time resolution (0.1 Hz) enabling to characterize the aerosol number, size-distribution and…

Atmospheric chemistry010504 meteorology & atmospheric sciencesParticle010502 geochemistry & geophysicsAtmospheric sciences01 natural sciences7. Clean energyTroposphereEmissionGeochemistry and Petrology[SDU.STU.VO]Sciences of the Universe [physics]/Earth Sciences/VolcanologyRelative humidityimpactsVolcano0105 earth and related environmental sciences[SDU.OCEAN]Sciences of the Universe [physics]/Ocean Atmospheregeographygeography.geographical_feature_categoryChemistryTroposphereOzone depletionSulfatesulphatePlumeAerosolImpactVolcano13. Climate actionAtmospheric chemistryChArMExHalogenParticle counter
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Inhibition by oxotremorine of acetylcholine resting release from guinea pig-ileum longitudinal muscle strips

1975

1. Longitudinal muscle strips of the guinea-pig ileum were incubated in Tyrode solution containing either DFP or physostigmine as cholinesterase inhibior. After a 90 min preincubation period the acetylcholine resting release into the medium was determined. Acetylcholine was estimated by gas chromatography. 2. The resting release was 0.39 nmol/g×min irrespective of the cholinesterase inhibitor used. In the presence of hexamethonium, or after omission of external calcium, the resting release fell by 50 and 55%, respectively. 3. Oxotremorine (10−5 and 10−4 M) significantly inhibited the resting release of acetylcholine by 25 and 33%, respectively. The inhibitory effect of oxotremorine was comp…

AtropineMalePhysostigminemedicine.medical_specialtyChromatography GasIsoflurophatePhysostigmineGuinea PigsHexamethonium CompoundsIn Vitro Techniqueschemistry.chemical_compoundIleumInternal medicineMuscarinic acetylcholine receptormedicineOxotremorineAnimalsReceptors CholinergicCholinesterasePharmacologybiologyOxotremorineMuscle SmoothGeneral MedicineAcetylcholineAtropineEndocrinologychemistryDepression Chemicalbiology.proteinCholinergicCalciumFemaleHexamethoniumAcetylcholinemedicine.drugNaunyn-Schmiedeberg's Archives of Pharmacology
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Delivering Inorganic and Organic Reagents and Enzymes from Zein and Developing Optical Sensors.

2018

Nowadays, interest in using environmentally friendly materials is increasing in many fields. However, the rational design of sensors with biodegradable materials is a challenge. The main aim of this work is to show the possibility of using zein, a protein from corn, as a biodegradable and low-cost material for immobilizing, stabilizing, and delivering different kind of reagents for developing optical sensors. Enzymes, metallic salts, and aromatic and small organic compounds were tested. In addition, different techniques of immobilization, entrapment and adsorption, were used, and different formats, such as solid devices and also multiwell platforms, were proposed. The capacity of zein for i…

AtropineZein02 engineering and technologyBiosensing Techniques01 natural sciencesZea maysAnalytical ChemistryPhosphatesAdsorptionHumanschemistry.chemical_classificationFerric hydroxamateChemistry010401 analytical chemistryRational designA proteinSubstrate (chemistry)021001 nanoscience & nanotechnologyEnzymes ImmobilizedCombinatorial chemistryEnvironmentally friendly0104 chemical sciencesEnzymeSpectrometry FluorescencePharmaceutical PreparationsReagentColorimetryIndicators and Reagents0210 nano-technologyAnalytical chemistry
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Receptor phosphorylation does not mediate cross talk between muscarinic M(3) and bradykinin B(2) receptors.

1999

This study examined cross talk between phospholipase C-coupled muscarinic M3and bradykinin B2receptors coexpressed in Chinese hamster ovary (CHO) cells. Agonists of either receptor enhanced phosphoinositide signaling (which rapidly desensitized) and caused protein kinase C (PKC)-independent, homologous receptor phosphorylation. Muscarinic M3but not bradykinin B2receptors were also phosphorylated after phorbol ester activation of PKC. Consistent with this, muscarinic M3receptors were phosphorylated in a PKC-dependent fashion after bradykinin B2receptor activation, but muscarinic M3receptor activation did not influence bradykinin B2receptor phosphorylation. Despite heterologous phosphorylatio…

Atropinemedicine.medical_specialtyReceptor Bradykinin B2PhysiologyGene ExpressionCHO CellsInositol 145-TrisphosphateMuscarinic AntagonistsBiologyMuscarinic AgonistsBradykininTransfectionTritiumInternal medicineCricetinaeMuscarinic acetylcholine receptor M5Muscarinic acetylcholine receptormedicineMuscarinic acetylcholine receptor M4AnimalsHumansBradykinin receptorPhosphorylationReceptorMethacholine ChlorideReceptor Muscarinic M3Receptors BradykininMuscarinic acetylcholine receptor M3Muscarinic acetylcholine receptor M2Cell BiologyMuscarinic acetylcholine receptor M1Receptor Cross-TalkReceptors MuscarinicRecombinant ProteinsEndocrinologyType C PhospholipasesCalciumInositolSignal TransductionThe American journal of physiology
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Characterization of automotive shredder residues before and five years after landfill disposal

2015

The paper illustrates the results of an extensive analytical characterization study of automotive shredder residues (ASR), also known as "fluff". The analyses concerned material fractions and their content, with special reference to heavy metals (e.g. Cd, Cr, Hg, Pb, Cu) and arsenic. Elution tests on the original materials were also conducted. Moreover, chemical concentrations of ASR samples after about five years' landfill residence was assessed, in order to verify possible changes resulting from both in-situ leaching and organic matter degradation phenomena. Results show that lead seems to be the most critical element in view of possible ASR acceptance in non-hazardous waste landfills bec…

Automotive industryteste de eluiçãochemistry.chemical_elementAquatic Sciencemetais pesadosOrganic matteraterros sanitáriosArseniclcsh:Environmental sciencesGeneral Environmental ScienceHigh concentrationchemistry.chemical_classificationlcsh:GE1-350leachateWaste managementbusiness.industryresíduos de automóveislandfillchorume fluffPublic Health Environmental and Occupational HealthHeavy metalsheavy metalautomotive shredder residueelution testchemistryEnvironmental sciencefluffLeaching (metallurgy)businessRevista Ambiente & Água
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The inhibition of Ca2+-ATPases of human erythrocyte membranes by covalent binding of ATP derivatives.

1982

AzidesErythrocytesChemistryUltraviolet RaysGeneral NeuroscienceErythrocyte MembraneCovalent bindingBiological Transport ActiveCa2 atpasesCalcium-Transporting ATPasesGeneral Biochemistry Genetics and Molecular BiologyKineticsMembraneAdenosine TriphosphateHistory and Philosophy of ScienceBiophysicsHumansEthenoadenosine TriphosphateProtein BindingAnnals of the New York Academy of Sciences
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UV-induced cross-linking of Tet repressor to DNA containing tet operator sequences and 8-azidoadenines.

1990

The synthesis of 8-azido-2'-deoxyadenosine-5'-triphosphate is described. The photoreactive dATP analog was characterized by thin layer chromatography, proton resonance spectroscopy, infrared spectroscopy and UV spectroscopy. Its photolysis upon UV irradiation was studied. After incorporation of this dATP analog into DNA containing the tet operator sequence the investigation of the interactions between tet operator DNA and Tet repressor protein by UV photocross-linking becomes possible. Photocross-linking of protein to DNA was demonstrated by the reduced migration of the DNA in SDS polyacrylamide gel electrophoresis. Addition of the inducer tetracycline prior to UV irradiation significantly …

AzidesOperator (biology)Operator Regions GeneticPhotolysisUltraviolet RaysRepressorInfrared spectroscopyDNABiologyMolecular biologyRepressor Proteinschemistry.chemical_compoundUltraviolet visible spectroscopyAdenosine TriphosphateCross-Linking ReagentschemistryGeneticsBiophysicsInducerAdenosine triphosphatePolyacrylamide gel electrophoresisDNANucleic acids research
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