Search results for "heterojunction"
showing 10 items of 227 documents
Structural characterization of relaxor ferroelectric PbMg 1/3 Nb 2/3 O 3 -PbTiO 3 thin film heterostructures deposited by pulsed laser ablation
2000
Highly oriented and epitaxial films of relaxor ferroelectric PbMg1/3Nb2/3O3-PbTiO3 (PMN-PT) with a composition (68/32) near the morphotropic phase boundary were deposited by pulsed laser ablation on La0.5Sr0.5CoO3 bottom electrodes, deposited on MgO (100) and LaAlO3 (100). The formation of crystalline phases, epitaxy, film–electrode–substrate orientation relationships and crystal perfection were studied by X-ray diffraction and scanning electron microscopy. The structural properties were found to depend on the deposition conditions and substrate. Correlation of both the dielectric and relaxor properties in the heterostructures and the structural properties of the PMN-PT films was observed.
Propagation and scattering of light in opal heterojunctions
2006
The directionality of the polarised light transmission has been studied in heterogeneous photonic crystals based on double-film opal in comparison to homogeneous crystals on single-film opals. In spite of additional scattering at the photonic bandgap interface, ballistic propagation has been preserved. Changes of the polarisation anisotropy in hetero-opal compared to homogeneous opal have been assigned to specific mode matching conditions at the photonic bandgap interface.
Revisiting the electronic properties of Molecular Semiconductor – Doped Insulator (MSDI) heterojunctions through impedance and chemosensing studies
2015
Abstract The core activity of this work was to give a new interpretation of the electronic behavior of Molecular Semiconductor – Doped Insulator heterojunctions (MSDI), a new organic device combining two molecular materials with very different electronic properties. We focused on understanding the phenomenon occurring at the interface of fluorinated and non-fluorinated phthalocyanines that appears to be a determining factor for the electronic charge transport in the two-component thin film and ultimately deciding the nature of gas sensing, as illustrated with ozone and ammonia chosen as examples of accepting and donating gases. The impedance measurements showed that the Schottky contact bet…
Molecular Semiconductors — Doped Insulator (MSDI) heterojunctions as new conductometric devices for chemosensing in wet atmosphere.
2015
Most of the gas sensors are based on resistors with inorganic materials and more rarely on other conductometric devices (diodes or transistors). Conductometric sensors have also been designed with molecular materials. Thus, in 2009, Molecular Semiconductor — Doped-insulator (MSDI) heterojunctions were built around a heterojunction between a molecular semiconductor (MS) and a doped-insulator (DI). The MS must be more conductive than the sublayer to take advantage of the heterojunction. The MS is generally of p-type and DI can be of p-type (p-MSDI) or n-type (n-MSDI) material. The energy barrier at the interface depends on the difference in the charge carrier density in the two layers, leadin…
Photonic crystals based on two-layer opaline heterostructures
2002
AbstractOptical properties of several heterostructures representing two-layer opaline photonic crystals have been examined. Two separate stop-bands have been observed both in transmission and emission spectra. The effect of the interface disorder on the optical spectra was not observed, probably, due to the insufficient degree of order of the opaline layers.
Surface properties of AlInGaN/GaN heterostructure
2016
Abstract Surface structural, electronic and electrical properties of the quaternary alloy AlInGaN/GaN heterostructures are investigated. Surface termination, atomic arrangement, electronic and electrical properties of the (0001) surface and (10–11) V-defect facets have been experimentally analyzed using various surface sensitive techniques including spectroscopy and microscopy. Moreover, the effect of sub-band gap (of the barrier layer) illumination on contact potential difference (VCPD) and the role of oxygen chemisorption have been studied.
Conducting Polymers for Ammonia Sensing: Electrodeposition, Hybrid Materials and Heterojunctions
2017
International audience; Polyaniline (PANI) with electrodonating and electrowithdrawing substituents were electrodeposited and studied as sensing materials in resistors and heterojunctions. Whereas the dimethoxyaniline leads to a highly conductive material, the tetrafluoroaniline leads to a poor conducting polymer. However, this latter was used in heterojunctions, associated with a highly conductive material, the lutetium bisphthalocyanine LuPc2. Elsewhere, hybrid materials combining polypyrrole (PPy) with ionic macrocycles as counterions were also electrosynthesized and used as sensing material in resistors, for the detection of ammonia. They exhibit a higher sensitivity compared to PPy pre…
Inkjet Printable ZnO/PEDOT:PSS Heterojunction for Thin Flexible Semi-Transparent Optoelectronic Sensors
2020
International audience; Flexible sensors play an increasing role in printed electronics and are of interest for optoelectronic applications in flexible robotics and industrial automation. Thus, we have investigated the hybrid inorganic-organic junction between ZnO and PEDOT:PSS (poly(3,4-ethylenedioxythiophene) polystyrene sulfonate). A thin ITO (indium tin oxide) layer on PET (polyethylene terephthalate) foils was used as substrate electrode. ZnO was deposited from a nanoparticle (NP) suspension by electrophoretic deposition. For comparison, we have used three different methods for the deposition of PEDOT:PSS, namely (i) drop casting, (ii) dip-coating, (iii) inkjet printing. For the result…
Energy level determination in bulk heterojunction systems using photoemission yield spectroscopy: case of P3HT:PCBM
2018
Financial support provided by Scientific Research Project for Students and Young Researchers Nr. SJZ2015/20 realized at the Institute of Solid State Physics, University of Latvia, is greatly acknowledged. This work has been supported by the Latvian State Research Program on Multifunctional Materials IMIS2. Jennifer Mann from Physical Electronics is greatly acknowledged for providing UPS data.
Hybrid paper–TiO2 coupled with a Cu2O heterojunction: an efficient photocatalyst under sun-light irradiation
2016
Hybrid paper-TiO2, paper-Cu2O-TiO2 and paper-TiO2-Cu2O photocatalysts were prepared via a non-hydrolytic sol-gel process followed by mild hydrothermal treatment to generate the TiO2 layer, and a reduction process to form the Cu2O nanoparticles. The hybrid photocatalysts have been characterized by Raman, TGA, FE-SEM, UV-Vis and XPS. The immobilized TiO2 was found to form a homogeneous thin layer composed of nanoparticles with a size smaller than 10 nm. The Cu2O nanoparticles with sizes of 30-100 nm were generated either on the top of the TiO2 layer or by reduction of Cu2+ ions. All the prepared hybrid catalysts showed efficient photocatalytic properties for the degradation of toluidine when …