Search results for "hollow fiber"

showing 2 items of 12 documents

Single hollow fiber SLM extraction of polyamines followed by tosyl chloride derivatization and HPLC determination

2007

Determination of polyamines in biological fluids possesses medical diagnostic relevance. Despite the vast panel of analytical methods developed for polyamines they are not applied in routine clinical usage, mainly due to the time and labor consuming sample preparation step and complicated derivatization procedures. Thus, new simpler methods are needed. This paper describes a single hollow fiber SLM extraction method of polyamines followed by simple pre-column derivatization with tosyl chloride and HPLC-UV analysis. The influence of different parameters such as the extraction time, organic phase composition, acceptor pH, donor pH, acceptor volume, donor volume and stirring speed on the trans…

hollow fiber membraneTime FactorspolyaminesBiochemistryHigh-performance liquid chromatographyAnalytical ChemistryTosyl Compoundschemistry.chemical_compoundEnvironmental ChemistryHumansSample preparationFibersupported liquid membraneDerivatizationSpectroscopyChromatography High Pressure LiquidChromatographyextraction techniqueExtraction (chemistry)Reproducibility of ResultsMembranes ArtificialHydrogen-Ion ConcentrationAcceptor2 × 2 real matriceschemistryHollow fiber membraneAnalytica Chimica Acta
researchProduct

Influence of temperature on mass transfer in an incomplete trapping single hollow fibre supported liquid membrane extraction of triazole fungicides.

2008

The influence of temperature in a single hollow fibre supported liquid membrane extraction of triazole fungicides with a stagnant acceptor phase was investigated. The mass transfer parameters such as diffusion coefficient, flux and apparent viscosity were determined at temperature ranging from 278 K to 313 K. Increase in temperature led to an increase in diffusion coefficient and flux. The apparent viscosity also decreased with an increase in temperature. The degree of trapping in the acceptor phase influenced the mass transfer at higher temperature. At lower temperature, the transport of analytes from the donor solution through the donor-membrane interface and through the membrane mainly a…

hollow fiber membraneextraction techniqueChemistryDiffusionAnalytical chemistryApparent viscosityBiochemistryAcceptorAnalytical ChemistrySLMPartition coefficientMembraneHollow fiber membraneMass transferPhase (matter)triazinesEnvironmental ChemistrySpectroscopyAnalytica chimica acta
researchProduct