Search results for "hopping"
showing 10 items of 104 documents
Entrepreneurial Opportunities Created by Electronic Grocery Shopping
2000
Current trading of daily consumer goods, groceries, is based on large chain masters as co-ordinators and extensive use of small companies as subcontractors, stores as customer front-ends and self-service as means for picking-up and home delivery of the goods. Our research aims at sketching what will be their role in the age of Internet storefronts and seamlessly interlinked information system. We use task analysis to reveal the areas of opportunities created for entrepreneurs by changing industry operations and structure. The analysis is based on literature on entrepreneurs, explorative survey on EGSs (Electronic Grocery Shops) around the world on the Internet, and on the experiences of the…
IMPLICACIONES DEL USO DE BUSCADORES EN EL COMPORTAMIENTO DE COMPRA ONLINE
2009
RESUMENEl objetivo del presente trabajo es analizar los factores que influyen en el uso de buscadores y su incidencia en el comportamiento de compra en Internet. El análisis de resultados obtenidos a partir de una muestra representativa de 485 compradores por Internet españoles, pone de manifiesto que los consumidores que consideran la comodidad, reducciones de precio y amplitud de surtido como motivaciones relevantes para realizar compras online presentan una mayor predisposición al uso de buscadores en la realización de sus compras virtuales. La experiencia como internauta y como comprador en Internet son factores que influyen negativamente en el uso de buscadores para la realización de c…
Negative eWOM and perceived credibility : a potent mix in consumer relationships
2022
PurposeBased on the foundations of the schema theory, the elaboration likelihood model (ELM) and customer experience literature, this research examines how the interplay between a consumer's previous shopping experience(s) and perceived credibility of negative online word-of-mouth (PCNWOM) leads to improved consumer–firm relationship quality (RQ).Design/methodology/approachThe authors utilised series of scenario-based experiments (N = 918) to test the research hypotheses.FindingsThe authors show that a focal customer's previous shopping experiences attenuate the perceived credibility of negative word-of-mouth on social media by other customers, which in turn weakens consumer–firm RQ. The au…
Raman, electron microscopy and electrical transport studies of x-ray amorphous Zn-Ir-O thin films deposited by reactive DC magnetron sputtering
2015
Zn-Ir-O thin films on glass and Ti substrates were deposited by reactive DC magnetron sputtering at room temperature. Structural and electrical properties were investigated as a function of iridium concentration in the films. Raman spectrum of Zn-Ir-O (61.5 at.% Ir) resembles the spectrum of rutile IrO2, without any distinct features of wurtzite ZnO structure. SEM images indicated that morphology of the films surface improves with the iridium content. EDX spectroscopy and cross-section SEM images revealed that the films growing process is homogeneous. Crystallites with approximately 2-5 nm size were discovered in the TEM images. Thermally activated conductivity related to the variable range…
On the FCNS⇆FC(NS) reaction: A matrix isolation and theoretical study
2015
Abstract The FCNS ⇆ FC(NS) photoisomerization process is a simple model system for molecular switches. Here, we examined the switching processes by experimental and theoretical methods. Prior matrix-isolation IR spectroscopic studies were complemented by matrix-isolation UV spectroscopic measurements to assist the interpretation of the mechanism of the ring closure and opening processes and to verify the accuracy of the computations on the vertical excitation energies. Vertical excitation energies were computed by the EOMEE-CCSD, MCSCF, and MR-CISD methods. Conical intersections were also searched for and three conical intersections along the reaction path FCNS → FC(NS) were located, one co…
Touch, threats, and transactions: Pandemic influences on consumer responses and the mediating role of touch likelihood when shopping for fruits and v…
2022
The COVID-19 pandemic has influenced consumer behavior in numerous ways. Most of the public health measures have centered around minimizing social contact and physical touch. In the present study, we investigate the impact of such touch restrictions, introduced during the pandemic, on consumers’ shopping responses and payment preferences in the context of a perishable food category amenable to tactile evaluation (fresh fruits and vegetables). The study used a single-factor between-subjects design (during vs. before the COVID-19 pandemic), with the data collected in a scenario-based online experiment from a sample of 729 participants. The results revealed significantly less favorable shoppin…
La durabilité du périurbain dépendant de l'automobile au regard des pratiques d'achat en ligne des ménages
2014
ASRDLF2014 - 51ème colloque de l'Association de Science Régionale de Langue Française : Métropolisation, cohésion et performances : quels futurs pour nos territoires ?, CHAMPS-SUR-MARNE, FRANCE, 07-/07/2014 - 09/07/2014; International audience; La dépendance automobile des territoires périurbains liée à une absence de commerces et de services pose la question de leur soutenabilité, voire de leur durabilité à l'aube probable d'une augmentation importante et continue des prix des carburants. Internet et plus particulièrement la vente en ligne sont en mesure de fournir une alternative propice au maintien des ménages dans ces territoires. En effet, grâce au e-commerce, les ménages n'auraient pl…
The azulene scaffold from a medicinal chemist's perspective: Physicochemical and in vitro parameters relevant for drug discovery.
2022
Azulene is a bicyclic scaffold rarely applied in medicinal chemistry. Here we report physicochemical and in vitro parameters relevant for drug discovery for a series of diversely substituted azulenes. We synthesized and characterized several scaffold hopping series of analogously substituted azulenes, indoles and naphthalenes. This enabled a comparison of azulene with the more common scaffolds indole and naphthalene. Our data indicates that undesirably low photostability of azulenes is restricted to certain substitution patterns. Generally, we conclude that azulene is an underused lipophilic bicycle and should be considered as a valuable complement to the collection of medicinal chemistry s…
Surface Hopping Dynamics Including Intersystem Crossing using the Algebraic Diagrammatic Construction Method
2017
We report an implementation for employing the algebraic diagrammatic construction to second order [ADC(2)] ab initio electronic structure level of theory in nonadiabatic dynamics simulations in the framework of the SHARC (surface hopping including arbitrary couplings) dynamics method. The implementation is intended to enable computationally efficient, reliable, and easy-to-use nonadiabatic dynamics simulations of intersystem crossing in organic molecules. The methodology is evaluated for the 2-thiouracil molecule. It is shown that ADC(2) yields reliable excited-state energies, wave functions, and spin-orbit coupling terms for this molecule. Dynamics simulations are compared to previously re…
Quantum fluctuations of the conductance in the hopping regime
1992
Abstract The results of the numerical scaling approach for localization are used to discuss the statistical behaviour of the zero-temperature conductance of disordered systems of finite size. In the asymptotic regime of strong localization, where transport is dominated by hopping processes, explicit expressions for the temperature dependence of the fluctuations of the conductance and the resistance are obtained by assuming that the phase coherence length is given by the Mott hopping law. It is shown that the temperature dependence of the fluctuations of the logarithm of the conductance/resistance does not depend on the assumptions concerning the statistics of the hopping processes. The resu…