Search results for "impur"
showing 10 items of 349 documents
Impurity analyses of silicon wafers from different manufacturing routes and their impact on LID of finished solar cells
2013
Summarizes the measurements of impurity concentrations in directionally solidified silicon ingots from different feedstocks. The substitutional Carbon and interstitial Oxygen are measured on as-sawn wafers using FTIR. Active iron concentration is mapped on a-Si:H passivated wafers. It is observed that these impurities present in Elkem Solar Grade Silicon (ESS™) concentrations are comparable to the standard polysilicon which are in the acceptable ranges for silicon for solar industry. The measured LID of the finished solar cells is also comparable.
Temperature dependence of recombination radiation in semiconductor nanostructures with quantum dots containing impurity complexes
2021
Temperature dependence of the spectral intensity of recombination radiation in a quasi-zero-dimensional structure, containing impurity complexes “A++e” (a hole localized on a neutral acceptor, interacting with an electron localized in the ground state of a quantum dot), has been investigated in an external electric field in the presence of tunneling decay of a quasistationary A+-state. Probability of dissipative tunneling of a hole has been calculated in the one-instanton approximation, and the influence of tunneling decay and of an external electric field on the A+-state binding energy and on the spectra of recombination radiation, associated with the optical transition of an electron from…
Über Inhibitoren der Korrosion II. Versuche zur Additivität von K- und A-Inhibitoren an Eisen Der Einfluß von Fremdionen auf die Schutzwerte von K-In…
1964
Die Oniumhypothese und der Begriff des „K- und A-Inhibitors” werden erlautert. Mogliche Wechselwirkungen der K- und A-Inhibitoren mit der Metalloberflache werden diskutiert. K- und A-Inhibitoren verhalten sich im Kombinationsversuch mindestens additiv, haufig uberadditiv. Geloste Fremdmetallionen erhohen in der Reihenfolge: Die Schutzwirkung der K-lnhibitoren. Geringe Konzentrationen an FeIII-lonen verstarken, hohere Konzentrationen erniedrigen die Schutzwirkung. Der Einflus von FeII-lonen ist gering und wenig won der Konzentration abhangig. On corrosion inhibitors II: Research on the additivity of K and A inhibitors on iron The influence of impurity ions on the protection characteristics o…
A mesoscopic approach to point-defect clustering in solids during irradiation
1993
Accumulation of point defects in solids during irradiation is often accompanied by self-organization processes which lead to point-defect clustering and thus to the formation of a spatially inhomogeneous defect structure. Within the framework of a mesoscopic phenomenological approach, the conditions for clustering of mobile point defects caused by their elastic interactions are studied. It is shown that differences between the elastic interaction of similar and that of dissimilar defects may lead to such clustering. Further, it is shown that the presence of impurities acting as traps for interstitials may promote the clustering process. The conditions for spatial clustering are studied for …
On the True Indium Content of In-Filled Skutterudites
2015
The incongruently melting single-filled skutterudite InxCo4Sb12 is known as a promising bulk thermoelectric material. However, the products of current bulk syntheses contain always impurities of InSb, Sb, CoSb, or CoSb2, which prevent an unbiased determination of its thermoelectric properties. We report a new two-step synthesis of high-purity InxCo4Sb12 with nominal compositions x = 0.12, 0.15, 0.18, and 0.20 that separates the kieftite (CoSb3) formation from the topotactic filler insertion. This approach allows conducting the reactions at lower temperatures with shorter reaction times and circumventing the formation of impurity phases. The synthesis can be extended to other filled skutteru…
Analytical and mineralogical studies of ore and impurities from a chromite mineral using X-ray analysis, electrochemical and microscopy techniques
2007
A wide analytical study of South African chromite ore, material with high interest in ceramic industry, has been carried out. With this purpose, an accurate chemical identification and mineralogical characterization of the mineral and the gangue have been performed using X-ray fluorescence (XRF), voltammetry, X-ray diffraction (XRD), light microscopy (LM), and scanning electron microscopy (SEM/EDX). The elemental composition of the sample (ore and gangue) has been obtained by XRF. The voltammetric analysis has allowed to demonstrate that iron in the sample was as Fe(II). The main compound of the chromite ore was a spinel (magnesiochromite ferroan), identified by XRD from the sample, which c…
Effects of static and dynamic perturbations on isotropic hyperfine coupling constants in some quinone radicals.
2004
The effects of solvent dielectric response on the isotropic hyperfine coupling constants of the 1,4-benzoquinone, 1,4-naphthoquinone and 9,10-anthraquinone anions and 1,4-naphthalenediol cation radicals were studied by electron spin resonance (ESR) spectroscopy and by the theoretical density functional method within the polarizable continuum model. Experimental results demonstrate that the isotropic hyperfine coupling constants can be obtained with high accuracy and that the effects of solvent impurities can be minimized by careful sample preparation. The results obtained correlate well with theoretical predictions from density functional theory calculations. For 1,4-naphthalenediol both th…
Spherical solid model for muon and hydrogen in metals
1979
The spherical solid model and the spin density functional formalism have been applied to calculate the screening of a positive point charge at different lattice sites in Al, Na and Cu. Results are obtained for the Knight shift, the electric field gradient, the heat of solution and the diffusion barrier. It is found essential to use the spin-polarised form to evaluate the Knight shift, especially at low metallic densities and for impurities with a high nuclear charge. Both the Knight shift and the electric field gradient are found to be markedly different for substitutional and interstitial positions. The calculated heat of solution of hydrogen is lowest for the octahedral position in FCC Al…
Water Adsorption on Clean and Defective Anatase TiO2 (001) Nanotube Surfaces: A Surface Science Approach
2018
We use ab initio molecular dynamics simulations to study the adsorption of thin water films with 1 and 2 ML coverage on anatase TiO2 (001) nanotubes. The nanotubes are modeled as 2D slabs, which consist of partially constrained and partially relaxed structural motifs from nanotubes. The effect of anion doping on the adsorption is investigated by substituting O atoms with N and S impurities on the nanotube slab surface. Due to strain-induced curvature effects, water adsorbs molecularly on defect-free surfaces via weak bonds on Ti sites and H bonds to surface oxygens. While the introduction of an S atom weakens the interaction of the surface with water, which adsorbs molecularly, the presence…
Optical properties of Cr3+ and Ni2+ ions in MgO, LiNbO3 and LMA
1995
Abstract The electronic structures of Co2+ and Ni2+ ions are obtained by the molecular orbital LCGTO-LSD method. Electrostatic matrix calculations are performed for d3 and d8 configurations. Theoretical optical data are discussed in function of the impurity site location in the crystal cell.