Search results for "init"

Czy polskość jest (słownikowo) definiowalna?

2017

Autor wychodzi z założenia, że istota polskości kondensuje się w języku (polskim) i w stworzonych w nim tekstach, z systemu języka więc i z tekstów może zostać odtworzona, a następnie przedstawiona w postaci definicji. Dotychczasowe definicje konceptu polskość w słownikach języka polskiego nic nie mówią o składowych tego konceptu. Autor proponuje metody ekscerpcji cech składowych polskości z tekstów różnych gatunków oraz ramę definicji syntetycznej, w którą te wyekscerpowane cechy powinny być w przyszłości wbudowane.

Conformations and Energetics of Sulfur and Selenium Diimides

2003

The geometries and energetics of different conformations of sulfur and selenium diimides E(NR) 2 (E = S, Se; R = H, Me, 'Bu, C 6 H 3 Me 2 -2,6, SiMe 3 ) have been studied by using various ab initio and DFT molecular orbital techniques. The syn,syn conformation is found to be most stable for parent E(NH) 2 , but in general, the preferred molecular conformation for substituted chalcogen diimides is syn,anti. In the case of E(NH) 2 the present calculations further confirm that syn,syn and syn,anti conformations lie energetically close to each other. From the three different theoretical methods used, B3PW91/6.31G * proved to be the most suitable method for predicting the geometries of chalcogen…

Trace eyeblink conditioning and extinction contingent to hippocampal ripples in rabbits

2014

Crystallization and preliminary crystallographic analysis of the major capsid proteins VP16 and VP17 of bacteriophage P23-77.

2012

The major capsid proteins VP16 and VP17 of bacteriophage P23-77 have been crystallized using both recombinant and purified virus and preliminary diffraction analyses have been performed.

Kunniaan tuomitut : kunniakoodiston hallitsema karoliinisotureiden elämä 1600-1700 -lukujen vaihteessa

2004

Taistelu ja karoliinien soturikunnia

2015

Trans-(2,5)-disubstituoitujen pyrrolidiiniyhdisteiden enantioselektiivinen synteesi

2018

2,5-disubstituoitujen pyrrolidiinien enantioselektiivistä synteesiä on tutkittu paljon, sillä pyrrolidiinirakenne löytyy monista alkaloideista ja on täten tärkeä osa luonnonainesynteesiä. Lisäksi ne toimivat tärkeinä asymmetrisen synteesin työkaluina. Erityisen kiinnostavia tässä suhteessa ovat erilaiset trans-2,5-bisaryylipyrrolidiinit katalyyttisten ominaisuuksiensa vuoksi. Tässä tutkielmassa käydään läpi eräitä tapoja niiden syntetisoimiseksi. Tutkielmassa keskitytään erityisesti trans-2,5-difenyylipyrrolidiinin enantioselektiiviseen synteesiin.

One-Pot Synthesis, X-ray Single Crystal and Molecular Insight of Enaminone-Based β-Morpholino-/N-Methylpiperazinyl-/Pyrrolidinylpropiophenone

2020

One-pot synthesis of three enaminones, (E)-1-(4-chlorophenyl)-3-morpholinoprop-2-en-1-one 1, (E)-1-(4-chlorophenyl)-3-(4-methylpiperazin-1-yl)prop-2-en-1-one 2, and (E)-1-(4-chlorophenyl)-3-(pyrrolidin-1-yl)prop-2-en-1-one 3 were achieved. The synthetic protocol via three components reaction of p-chloroacetophenone with DMFDMA (N,N-dimethylformamid-dimethylacetal) and the corresponding secondary amines (morpholine/N-methylpiperazine/pyrrolidine) in dioxane under heating for 2.5–4 h at 102 °C yielded the requisite enaminones. This protocol has the advantage of no separation of intermediate, no need for column purification with quantitative yield for the target compounds. The chemical feature…

N-Heterocyclic Carbene Catalyzed Quadruple Domino Reactions through α,β-Unsaturated Acyl Azolium Intermediates : Asymmetric Synthesis of Cyclopenta[c…

2018

An N‐heterocyclic carbene catalyzed domino sequence via α,β‐unsaturated acyl azolium intermediates has been developed. This strategy provides a convenient enantioselective route to functionalized tricyclic coumarin derivatives and cyclopentanes. DFT studies and control experiments were performed to gain better insight into the reaction mechanism. peerReviewed

Materiality assessment in sustainability reporting : case study of the airline industry

2017

Materiality has been heavily emphasized in different sustainability reporting guidelines to increase the quality of the sustainability reports and report issues that are most aligned with the company’s most significant economic, environmental and social issues. In this thesis materiality analysis in sustainability reporting is analyzed. Firstly, in the theoretical part, the concept of sustainability reporting and materiality is explained along with the provision of materiality in different reporting guidelines. In this research section, fifteen different airlines’ sustainability reports are analyzed to find out how the materiality analysis is carried out in the airlines. The study is focuse…