Search results for "init"

Synthesis, Structure and Solvatochromism of the Emission of Cyano-Substituted Oligo(phenylenevinylene)s

2001

Strongly luminescent and highly soluble oligo(phenylenevinylene)s with five benzene rings and cyano groups in different positions of the terminal styrene units were prepared by means of Horner and Knoevenagel reactions. The substitution pattern − cyanide moieties on the vinyl or on the aromatic regions, together with the effect of auxochromic groups − has distinct influences on the electronic spectra, particularly on the fluorescence. Polar solvents induce red shifts and strongly reduce the fluorescence intensity of the vinyl-substituted oligomers. Cyano substitution increases the electron affinity of the oligomers; this effect is more pronounced for molecules with vinyl cyanides and can be…

Towards a routine-based view of interfirm rivalry

2022

Although organizational routines have attracted increasing attention in strategy and organization research, they have received surprisingly limited attention in competitive dynamics scholarship. Our essay seeks to advance a routine-based view of interfirm rivalry by bridging the competitive dynamics and routine literatures. We put forward a conceptual model of the routine-based view of interfirm rivalry that is centered on “competitive action routines.” The model clarifies the roles that managers play in driving a firm’s competitive behavior, challenges the assumption of routine-based rigidity in competitive behavior, and adds nuance to our understanding of managerial cognition in competiti…

Developing Primary School Students’ Formal Geometric Definitions Knowledge by Connecting Origami and Technology

2019

In this paper, we present opportunities with the uses of origami and technology, in our case GeoGebra, in teaching formal geometric definitions for fifth-grade primary school students (11-12yrs). Applying origami in mathematical lessons is becoming to be recognized as a valuable tool for improving students’ mathematical knowledge. In previous studies, we developed origami and technology activities for high-school mathematics, but we wanted to explore if such approach would work in primary school as well. For this reason, we chose a flat origami model оf the crane and we used this model to introduce students to basic geometrical notions and definitions, such as points, lines, intersections o…

Functional a posteriori error estimates for boundary element methods

2019

Functional error estimates are well-established tools for a posteriori error estimation and related adaptive mesh-refinement for the finite element method (FEM). The present work proposes a first functional error estimate for the boundary element method (BEM). One key feature is that the derived error estimates are independent of the BEM discretization and provide guaranteed lower and upper bounds for the unknown error. In particular, our analysis covers Galerkin BEM and the collocation method, what makes the approach of particular interest for scientific computations and engineering applications. Numerical experiments for the Laplace problem confirm the theoretical results.

Guaranteed error bounds and local indicators for adaptive solvers using stabilised space-time IgA approximations to parabolic problems

2019

The paper is concerned with space–time IgA approximations to parabolic initial–boundary value problems. We deduce guaranteed and fully computable error bounds adapted to special features of such type of approximations and investigate their efficiency. The derivation of error estimates is based on the analysis of the corresponding integral identity and exploits purely functional arguments in the maximal parabolic regularity setting. The estimates are valid for any approximation from the admissible (energy) class and do not contain mesh-dependent constants. They provide computable and fully guaranteed error bounds for the norms arising in stabilised space–time approximations. Furthermore, a p…

Nanopiattaforme di Ossido di Grafene perfluorurate: materiali biocompatibili con affinità per l'ossigeno

L’attacco covalente di molecule perfluorurate su ossido di graphene (GO) via sostituzione nucleofila aromatica ha consentito una facile funzionalizzazione delle lamelle di GO.1,2 La performance delle nanopiattaforme perluorurate (GOF) nell’uptake e rilascio di ossigeno è stata valutata in condizioni di pH fisiologico a differenti concentrazioni e temperature, dimostrando una maggiore affinità del materiale perfluorurato GOF rispetto al GO pristino. Anche a basse concentrazioni GOF ha mostrato valori di uptake di ossigeno a saturazione e velocità di diffusione superiori ad altri materiali proposti in letteratura per ingegneria tissutale, per l’ossigenazione cellulare durante la rigenerazione…

Oxymetazoline modulates proinflammatory cytokines and the T‐cell stimulatory capacity of dendritic cells

2007

The nasal decongestant oxymetazoline (OMZ) is frequently used in the topical treatment of rhinitis/sinusitis. As proinflammatory cytokines play a critical role in the development and maintenance of local inflammation, the aim of this study was to investigate the influence of OMZ on immune cells in order to diminish the mucosal infiltration of the nose. Peripheral blood mononuclear cells (PBMC) from buffy coats of healthy volunteers were isolated and stimulated in the presence or absence of OMZ. In addition, monocyte-derived dendritic cells (DC) were generated and different concentrations of OMZ were added. DC phenotype and their T-cell stimulatory properties were analysed. The vasoactive su…

[60]Fullerene l -Amino Acids and Peptides: Synthesis under Phase-Transfer Catalysis Using a Phosphine–Borane Linker. Electrochemical Behavior

2017

International audience; A new method to link amino acid and peptide derivatives to [60]fullerene is described. It uses hydrophosphination with a secondary phosphine borane. First, the stereoselective synthesis of secondary phosphine borane amino acid derivatives was achieved by alkylation of phenylphosphine borane with gamma-iodo-alpha-amino ester reagents under phase transfer catalysis (PTC). Second, a sec-phosphine borane amino ester was saponified and coupled with alpha,gamma-diamino esters to afford the corresponding dipeptide derivatives in good yields. Finally, the hydrophosphination reaction of [60]fullerene by the sec-phosphine borane compounds was performed under PTC to obtain C-60…

Group Identities on Units of Group Algebras

2000

Abstract Let U be the group of units of the group algebra FG of a group G over a field F . Suppose that either F is infinite or G has an element of infinite order. We characterize groups G so that U satisfies a group identity. Under the assumption that G modulo the torsion elements is nilpotent this gives a complete classification of such groups. For torsion groups this problem has already been settled in recent years.

Abelian Sylow subgroups in a finite group, II

2015

Abstract Let p ≠ 3 , 5 be a prime. We prove that Sylow p-subgroups of a finite group G are abelian if and only if the class sizes of the p-elements of G are all coprime to p. This gives a solution to a problem posed by R. Brauer in 1956 (for p ≠ 3 , 5 ).