Search results for "init"

Lower mantle hydrogen partitioning between periclase and perovskite : a quantum chemical modelling

2016

Abstract Partitioning of hydrogen (often referred to as H2O) between periclase (pe) and perovskite (pvk) at lower mantle conditions (24–80 GPa) was investigated using quantum mechanics, equilibrium reaction thermodynamics and by monitoring two H-incorporation models. One of these (MSWV) was based on replacements provided by Mg2+ ↔ 2H+ and Si4+ ↔ 4H+; while the other (MSWA) relied upon substitutions in 2Mg2+ ↔ Al3+ + H+ and Si4+ ↔ Al3+ + H+. H2O partitioning in these phases was considered in the light of homogeneous (Bulk Silicate Earth; pvk: 75%–pe:16% model contents) and heterogeneous (Layered Mantle; pvk:78%–pe:14% modal contents) mantle geochemical models, which were configured for lower…

Potential-vorticity dynamics of troughs and ridges within Rossby wave packets during a 40-year reanalysis period

2020

Rossby wave packets (RWPs) are fundamental to midlatitude dynamics and govern weather systems from their individual life cycles to their climatological distributions. Renewed interest in RWPs as precursors to high-impact weather events and in the context of atmospheric predictability motivates this study to revisit the dynamics of RWPs. A quantitative potential vorticity (PV) framework is employed. Based on the well established PV-thinking of midlatitude dynamics, the processes governing RWP amplitude evolution comprise group propagation of Rossby waves, baroclinic interaction, the impact of upper-tropospheric divergent flow, and direct diabatic PV modification by nonconservative processes.…

A process-based anatomy of Mediterranean cyclones: from baroclinic lows to tropical-like systems

2021

Abstract. In this study, we address the question of the atmospheric processes that turn Mediterranean cyclones into severe storms. Our approach applies on-line potential vorticity (PV) budget diagnostics and piecewise PV inversion to WRF model simulations of the mature stage of 100 intense Mediterranean cyclones. We quantify the relative contributions of different processes to cyclone development and therefore deliver, for the first time, a comprehensive insight into the variety of cyclonic systems that develop in the Mediterranean from the perspective of cyclone dynamics. In particular, we show that all 100 cyclones are systematically influenced by two main PV anomalies: a major anomaly in…

Reactive oxygen species formed in aqueous mixtures of secondary organic aerosols and mineral dust influencing cloud chemistry and public health in th…

2017

Mineral dust and secondary organic aerosols (SOA) account for a major fraction of atmospheric particulate matter, affecting climate, air quality and public health. How mineral dust interacts with SOA to influence cloud chemistry and public health, however, is not well understood. Here, we investigated the formation of reactive oxygen species (ROS), which are key species of atmospheric and physiological chemistry, in aqueous mixtures of SOA and mineral dust by applying electron paramagnetic resonance (EPR) spectrometry in combination with a spin-trapping technique, liquid chromatography-tandem mass spectrometry (LC-MS/MS), and a kinetic model. We found that substantial amounts of ROS includi…

2019

Abstract. The flow of fluids through porous media such as groundwater flow or magma migration is a key process in geological sciences. Flow is controlled by the permeability of the rock; thus, an accurate determination and prediction of its value is of crucial importance. For this reason, permeability has been measured across different scales. As laboratory measurements exhibit a range of limitations, the numerical prediction of permeability at conditions where laboratory experiments struggle has become an important method to complement laboratory approaches. At high resolutions, this prediction becomes computationally very expensive, which makes it crucial to develop methods that maximize …

Controlled treatment of a high velocity anisotropic aquifer model contaminated by hexachlorocyclohexanes

2020

International audience; Xanthan gels were assessed to control the reductive dechlorination of hexachlorocyclohexanes (HCHs) and trichlorobenzenes (TCBs) in a strong permeability contrast and high velocity sedimentary aquifer. An alkaline degradation was selected because of the low cost of NaOH and Ca(OH)2. The rheology of alkaline xanthan gels and their ability to deliver alkalinity homogeneously, while maintaining the latter, were studied. Whereas the xanthan gels behaved like non-Newtonian shear-thinning fluids, alkalinity and Ca(OH)2 microparticles had detrimental effects, yet, the latter decreased with the shear-rate. Breakthrough curves for the NaOH and Ca(OH)2 in xanthan solutions, ca…

The influence of rock heterogeneity on the scaling properties of simulated and natural stylolites

2009

International audience; Stylolites are among the most prominent deformation patterns in sedimentary rocks that document localized pressure solution. Recent studies revealed that stylolite roughness is characterized by two distinct scaling regimes. The main goal of the present study is to decipher whether this complex scaling behavior of stylolites is caused by the composition of the host-rock, i.e. heterogeneities in the material, or is governed by inherent processes on respective scales, namely the transition from a surface energy to an elastic energy dominated regime, as theoretically predicted. For this purpose we have developed a discrete numerical technique, based on a lattice spring m…

Modelling of stylolite geometries and stress scaling

2012

International audience; In this contribution we present numerical simulations of stylolite growth to decipher the effects of initial rock heterogeneity and stress on their morphology. We show that stylolite growth in a rock with a uniform grain size produces different patterns than stylolite growth in a rock with a bimodal grain size distribution. Strong pinning of large heterogeneities produce stylolite structures that are dominated by pronounced teeth, whereas a uniform grain size leads to spikes and a roughness that shows variable wavelengths. We compare the simulated stylolites with natural examples and show that the model can reproduce the real structures. In addition we show that stro…

An improved understanding of the Alaska Coastal Current: the application of a bivalve growth-temperature model to reconstruct freshwater-influenced p…

2011

Shells of intertidal bivalve mollusks contain sub-seasonally to interannually resolved records of temperature and salinity variations in coastal settings. Such data are essential to understand changing land-sea interactions through time, specifically atmospheric (precipitation rate, glacial meltwater, river discharge) and oceanographic circulation patterns; however, independent temperature and salinity proxies are currently not available. We established a model for reconstructing daily water temperatures with an average standard error of ∼1.3 °C based on variations in the width of lunar daily growth increments of Saxidomus gigantea from southwestern Alaska, United States. Temperature explai…

Thermal and structural modeling of the Scillato wedge-top basin source-to-sink system. Insights into the Sicilian fold-and-thrust belt evolution (Ita…

2019

AbstractTemperature-dependent clay mineral assemblages, vitrinite reflectance, and one-dimensional (1-D) thermal and three-dimensional (3-D) geological modeling of a Neogene wedge-top basin in the Sicilian fold-and-thrust belt and its pre-orogenic substratum allowed us to: (1) define the burial history of the sedimentary succession filling the wedge-top basin and its substratum, (2) reconstruct the wedge-top basin geometry, depocenter migration, and sediment provenance through time in the framework of a source-to-sink system, and (3) shed new light into the kinematic evolution of the Apennine-Maghrebian fold-and-thrust belt.The pre-orogenic substratum of the Scillato basin shows an increase…