Search results for "interface"
showing 10 items of 2139 documents
Gibbs' Dividing Surface between a Fixed-Charge Membrane and an Electrolyte Solution. Application to Electrokinetic Phenomena in Charged Pores
1999
The Gibbs model for the boundary between two phases consists of replacing the finite interfacial region, where the properties of the system change gradually, by a dividing surface which acts as a third phase of zero volume in which some magnitudes change abruptly. This thermodynamic concept was recently applied to a planar interface between a fixed charge membrane and an electrolyte solution.1 The continuous decrease of counterions with the distance from the charged surface is replaced by a step function, so that the diffuse double layer is ideally represented by a charged region depleted of all co-ions. Here the cylindrical geometry is analyzed, and the planar case is revisited by proposin…
Silica Entrapment for Significantly Stabilized, Energy-Conducting Light-Harvesting Complex (LHCII)
2014
The major light-harvesting chlorophyll a/b complex (LHCII) of the photosynthetic apparatus in green plants consists of a membrane protein and numerous noncovalently bound pigments that make up about one-third of the molecular mass of the pigment-protein complex. Due to this high pigment density, LHCII is potentially interesting as a light-harvesting component in synthetic constructs. However, for such applications its stability needs to be significantly improved. In this work, LHCII was dramatically stabilized by enclosing it within polymerizing colloidal silica. The entrapped LHCII stayed functional at 50 °C for up to 24 h instead of a few minutes in detergent solution and clearly showed e…
The Role of the Liquid Chromatography-Mass Spectrometry in Pesticide Residue Determination in Food
2008
The use of liquid chromatography (LC) in pesticide residue determination was usually limited to groups of compounds or single compounds for which no suitable gas chromatographic (GC) conditions were available. However, recent developments have significantly enlarged the LC scope in this field of analysis. One of the most important advances was the on-line coupling of efficient LC separation with mass spectrometry detectors (LC-MS and LC-MS/MS) that makes this technique an excellent method for the determination of pesticides and their transformation products in complex matrices such as food. This review considers the application of LC-MS/MS in this field. Emphasis is placed on the tandem MS …
The dependence of circular dichroism in photoemission on the optical properties of Cs monolayers on Pt(111)
1997
We report on the dependence of dichroic photoemission excited by circularly polarised light on the angle of photon incidence. We measured the difference in the angle-resolved photoemission intensities from Cs 5p semi-core levels excited by photons of opposite helicity, which is known as CDAD. We found that the dependence of the measured differences on the angle of light incidence deviates strongly from the model of CDAD for free atoms, as expected. Using the Fresnel equations and a complex index of refraction, one finds that not only the third component but also the second component of the Stokes vector is responsible for the excitation process. Both Stokes components change sign if the ini…
Dichroism in VUV photoemission from the (0001)-surfaces of ultrathin Gd and Nd films on W(110)
1997
Abstract Ultrathin layers of Gd and Nd epitaxially grown on W(110) have been investigated using linearly and circularly polarised light at the 6.5 m NIM beamline at the BESSY storage ring in Berlin. The high quality of the films was monitored by the sharp and dispersionless surface state just below the Fermi energy. The CDAD (circular dichroism in the angular distribution of photoelectrons) measurements showed strong effects in the surface states as well as in the valence bands. The LMDAD (linear magnetic dichroism in…) from Gd(0001) showed a small, but significant splitting of the surface state. This splitting can be reproduced by numerical one-step calculations based on spin-dependent sur…
Circular dichroism in angular resolved photoemission from pure and Rb-doped C60 and C22H14 layers on platinum and tungsten
1997
Abstract Polycrystalline C60 and Pentacene films grown on W(110) and Pt(111) have been studied in valence band photoemission using circularly polarised synchrotron radiation from BESSY with special emphasis on circular dichroism in photoemission. For thin films of C60, dichroic asymmetries of about 10% occur independent of the temperature and the substrate hinting that the rotation of the topmost layer is hindered even at room temperature. For Pentacene we found asymmetries up to 50% in the region of the σ-electrons. Moreover, we found for this molecule a dichroic asymmetry in normal emission, that is a forbidden geometry. This hints on adsorption with the molecules perpendicularly oriented…
Magnesium alloys laser (Nd:YAG) cladding and alloying with side injection of aluminium powder
2003
International audience; The development of the high purity magnesium alloys (such as WE43) incites the designers to reconsider them, and the car industry appears, these days, the most interested to use this kind of alloy. However, due to their ignitability and tendency to oxidation, magnesium alloys require surface treatments. A series of experiments was carried out in order to improve the corrosion resistance of two types of magnesium alloys, WE43 and ZE41. In most cases, the substrate surface was treated before laser interaction. Side injection of aluminium powder under a 3 kW cw Nd:YAG laser was employed. The deposited layers present very good bond properties. The resulting microstructur…
Magnesium alloys (WE43 and ZE41) characterisation for laser applications
2004
International audience; One of the most important parameters in laser treatment is the quantity of beam energy absorbed by the substrate. Despite its important role played in laser processes, this factor is rarely available for the laser sources wavelengths and at high temperatures reached during such treatments. A series of experiments were carried out in order to characterise, from this point of view, two types of magnesium alloys, WE43 and ZE41, often used in laser applications (cladding, alloying, welding, etc.). The results represent an important step in order to understand Mg-alloys behaviour under laser beam action.
MoSi2 laser cladding—A new experimental procedure: double-sided injection of MoSi2 and ZrO2
2003
International audience; In the last decade, development of low density advanced material systems for service at temperatures up to 1300 °C was one of the goals of many researches. This kind of material should mainly have moderate fracture toughness and should exhibit oxidation resistant behaviour at low and intermediate temperature. One of the most studied materials continues to be the intermetallic compound MoSi2. The molybdenum disilicide has been considered as an attractive candidate due to its melting point (2030 °C) and excellent oxidation resistance at high temperatures. The main problem associated with the MoSi2 layer synthesized using laser beam is the layer fragility. To avoid this…
SAUCE: A Web-Based Automated Assessment Tool for Teaching Parallel Programming
2015
Many curricula for undergraduate studies in computer science provide a lecture on the fundamentals of parallel programming like multi-threaded computation on shared memory architectures using POSIX threads or OpenMP. The complex structure of parallel programs can be challenging, especially for inexperienced students. Thus, there is a latent need for software supporting the learning process. Subsequent lectures may cover more advanced parallelization techniques such as the Message Passing Interface (MPI) and the Compute Unified Device Architecture (CUDA) languages. Unfortunately, the majority of students cannot easily access MPI clusters or modern hardware accelerators in order to effectivel…