Search results for "intermediate"
showing 10 items of 440 documents
Can Green Dimethyl Carbonate Synthesis be More Effective? A Catalyst Recycling Study Benefiting from Experimental Kinetics and DFT Modeling
2014
Dibutyldimethoxystannanes are known to catalyze the reaction between carbon dioxide and methanol leading to dimethyl carbonate. Despite similarities between din-butyl- and ditert-butyldimethoxystannane, the recycled complexes have different structural features. In the din-butyl series, a decatin(IV) complex has been characterized and is less active than the stannane precursor. Kinetic experiments likely indicate that all the tin centers are not active, which is confirmed in comparing with the related dinuclear 1,3-dimethoxytetran-butyldistannoxane complex. In the ditert-butyl series, the tritin(IV) complex isolated upon recycling features the steric effect of bulky tBu ancillary ligands. In…
Properties of Swift's intermediate bursts
2011
Based on their prompt, high-energy emission, gamma-ray bursts are usually classified into short-duration and long-duration classes. A third intermediate group has been identified on statistical grounds but its individual properties have not yet been studied in detail. Using the large sample of follow-up observations of GRBs produced during the Swift era we analyze the individual characteristics of this group. We find that intermediate bursts are significantly different from short GRBs but share many properties with long bursts, probably pointing to a common progenitor type. However, we find that intermediate bursts are significantly dimmer and have on average lower redshifts. Based on their…
Morphometry and comparative histology of sinus and atrioventricular nodes in humans and pigs and their relevance in the prevention of nodal arrhythmi…
2019
The cardiac conduction system is a network structure that allows the initiation and fast propagation of electrical impulses that trigger the electrical depolarization of the myocardial tissue. The purpose of this work is to study the histological and morphometric characteristics of the different components of the sinus and atrioventricular nodes in humans and pigs and their relationship with supraventricular arrhythmias. In this study, we describe the morphometry of the sinus and atrioventricular nodes of 10 adult humans and 10 pig hearts. A computerized morphometric study has been carried out, where we determined the number of cells that compose the nodes as well as different parameters re…
Echinostomes: systematics and life cycles
2008
This chapter provides a review of the most significant literature in the last decade on the systematics and biology of echinostomes and echinostome-like digeneans. This review is primarily concerned with members of the genus Echinostoma, although members of other genera (Echinoparyphium, Echinochasmus, Himasthla, Hypoderaeum, Petasiger, Euparyphium, Stephanoprora, Isthmiophora, and Acanthoparyphium) and echinostome-related genera (Parorchis, Philophthalmus and Ribeiroia) are also considered. The literature on molecular systematics and morphometrics of these trematodes is reviewed. Specific mention is made of the life cycle patterns of echinostome and echinostome-like digeneans along with an…
Focal adhesions are hotspots for keratin filament precursor formation
2006
Recent studies showed that keratin filament (KF) formation originates primarily from sites close to the actin-rich cell cortex. To further characterize these sites, we performed multicolor fluorescence imaging of living cells and found drastically increased KF assembly in regions of elevated actin turnover, i.e., in lamellipodia. Abundant KF precursors (KFPs) appeared within these areas at the distal tips of actin stress fibers, moving alongside the stress fibers until their integration into the peripheral KF network. The earliest KFPs were detected next to actin-anchoring focal adhesions (FAs) and were only seen after the establishment of FAs in emerging lamellipodia. Tight spatiotemporal …
Abelian varieties and theta functions associated to compact Riemannian manifolds; constructions inspired by superstring theory
2012
We look into a construction of principal abelian varieties attached to certain spin manifolds, due to Witten and Moore-Witten around 2000 and try to place it in a broader framework. This is related to Weil intermediate Jacobians but it also suggests to associate abelian varieties to polarized even weight Hodge structures. The latter construction can also be explained in terms of algebraic groups which might be useful from the point of view of Tannakian categories. The constructions depend on moduli much as in Teichm\"uller theory although the period maps in general are only real analytic. One of the nice features is how the index for certain differential operators canonically associated to …
Nanoporous alumina membranes filled with solid acid for thin film fuel cells at intermediate temperatures
2004
Thin film fuel cells have been fabricated by impregnation of inorganic porous membranes with inorganic proton conductor. Anodic alumina membranes (50 μm thick and pore diameter of 200 nm), filled with CsHSO4 salt have been used as protonic conductor in a hydrogen-oxygen fuel cell working between 423 and 443 K in dry atmosphere. Polarization curves at 433 K showing ohmic control with open circuit values near 0.8 V and short circuit current around 8 mA cm−2 have been obtained. Possible causes of degradation as well as alternative routes to overcome some of the problems encountered with this approach will be reported. Keywords: Solid acid, Anodic alumina membranes, Pore filling, Thin film fuel…
Il lavoro etero-organizzato prima e dopo il caso Foodora Italia.
2019
l contributo ripropone la discussione sull’esegesi della fattispecie disciplinata dall’art. 1 comma 2 del d. lgs. n. 81 del 2015 (nel testo anteriore alla riforma del 2019) trattata dall’autore nei Colloqui Giuridici sul Lavoro del 2015 (a cura) di Antonio Vallebona per il Massimario di Giurisprudenza del Lavoro. Lo studio rigettava la tesi che il lavoro organizzato dal committente fosse la terza fattispecie e anzi con riferimento delle condizioni di applicazione dimostrava la necessità di una lettura includente. La conclusione era che la nuova disciplina aveva natura antifraudolenta e determinava un allargamento (relativo) dell’area della subordinazione conseguente alla riduzione del cam…
De novo formation of cytokeratin filament networks originates from the cell cortex in A-431 cells
2001
Of the three major cytoskeletal filament systems, the intermediate filaments are the least understood. Since they differ fundamentally from the actin- and microtubulebased networks by their lack of polarity, it has remained a mystery how and where these principally endless filaments are formed. Using a recently established epithelial cell system in which fluorescently labeled intermediate filaments of the cytokeratin type can be monitored in living cells, we address these issues. By multidimensional time-lapse fluorescence microscopy, we examine de novo intermediate filament network formation from non-filamentous material at the end of mitosis and show that it mirrors disassembly. It is dem…
Desmosomes: interconnected calcium-dependent structures of remarkable stability with significant integral membrane protein turnover
2002
Desmosomes are prominent cell adhesion structures that are major stabilizing elements, together with the attached cytoskeletal intermediate filament network, of the cytokeratin type in epithelial tissues. To examine desmosome dynamics in tightly coupled cells and in situations of decreased adhesion, fluorescent desmosomal cadherin desmocollin 2a (Dsc2a) chimeras were stably expressed in human hepatocellular carcinoma-derived PLC cells (clone PDc-13) and in Madin-Darby canine kidney cells (clone MDc-2) for the continuous monitoring of desmosomes in living cells. The hybrid polypeptides integrated specifically and without disturbance into normal-appearing desmosomes that occurred in associati…