Search results for "kinetic energy"

OPKINE, a multipurpose program for kinetics

1991

The program OPKINE is presented for the study of reaction mechanisms and multicomponent analysis in dynamic conditions. This program is written in FORTRAN-77 for IBM 30/90 and VAX 8300 computers, and permits the simultaneous evaluation of both rate constants and initial reagent concentrations or, alternatively, rate constants and sensitivities. Up to 20 kinetic curves, with up to 400 points each, can be treated to evaluate up to 40 parameters. Integration of the system of differential equations is performed by means of the Runge–Kutta–Fehlberg method. OPKINE is provided with the Simplex, and modified versions of the Davidon–Fletcher–Powell and Gauss–Newton–Marquardt optimization methods. A …

Designing an innovative system for sea wave utilization

2018

For the sea wave energy exploitation, the department of Energy of Palermo University is investigating a new approach based on the mechanical motion conversion from a linear motion into a unidirectional rotary motion. This mechanical output can be used to run alternators, producing electrical power with a very simplified energy conversion chain. First preliminary tests have been realized in laboratory using a small-scale prototype.

Defect-Induced Orbital Polarization and Collapse of Orbital Order in Doped Vanadium Perovskites

2018

We explore mechanisms of orbital order decay in doped Mott insulators $R_{1-x}$(Sr,Ca)$_x$VO$_3$ ($R=\,$Pr,Y,La) caused by charged (Sr,Ca) defects. Our unrestricted Hartree-Fock analysis focuses on the combined effect of random, charged impurities and associated doped holes up to $x=0.5$. The study is based on a generalized multi-band Hubbard model for the relevant vanadium $t_{2g}$ electrons, and includes the long-range (i) Coulomb potentials of defects and (ii) electron-electron interactions. We show that the rotation of occupied $t_{2g}$ orbitals, induced by the electric field of defects, is a very efficient perturbation that largely controls the suppression of orbital order in these com…

Observation of classical optical wave condensation

2010

We demonstrate the nonlinear condensation of classical optical waves. The condensation is observed directly, as a function of nonlinearity and wave kinetic energy, in a self-defocusing photorefractive crystal.

Theory of warm ionized gases: Equation of state and kinetic Schottky anomaly

2013

Based on accurate Lennard-Jones type interaction potentials, we derive a closed set of state equations for the description of warm atomic gases in the presence of ionization processes. The specific heat is predicted to exhibit peaks in correspondence to single and multiple ionizations. Such kinetic analogue in atomic gases of the Schottky anomaly in solids is enhanced at intermediate and low atomic densities. The case of adiabatic compression of noble gases is analyzed in detail and the implications on sonoluminescence are discussed. In particular, the predicted plasma electron density in a sonoluminescent bubble turns out to be in good agreement with the value measured in recent experiment…

Observation of the condensation of classical waves

2010

We report a theoretical, numerical and experimental study of condensation of classical optical waves. The condensation of observed directly, as a function of nonlinearity and wave kinetic energy, in a self-defocusing photorefractive crystal.

Condensation of classical optical waves

2010

We demonstrate the nonlinear condensation of classical optical waves. The condensation is observed directly, as a function of nonlinearity and wave kinetic energy, in a self-defocusing photorefractive crystal.

1981

The dynamical region of the measured calibration curves is investigated using the results of the theory published previously. The kinetic constants of the flow-equilibrium are calculated from the measurements according to two different models for a spontaneous polymer diffusion of the transported P-mer from sol into gel of the Phase Distribution Chromatography (PDC)-column. The corresponding lateral concentration profiles in the gel are found by analytical integration of Fick's second law under the corresponding boundaries. An energetic model of this flow-equilibrium is stated, giving the activation enthalpy and -entropy of the rediffusion of the polymer from gel into sol after some retarda…

Magnetic exchange interaction in a pair of orbitally degenerate ions: Magnetic anisotropy of [Ti2Cl9]−3

2001

The theory of the kinetic exchange in a pair of orbitally degenerate ions developed by the authors [J. Phys. Chem. A 102, 200 (1998)] is applied to the case of face-shared bioctahedral dimer (overall D3h-symmetry). The effective kinetic exchange Hamiltonian is found for a 2T2–2T2 system taking into account all relevant transfer pathways and charge-transfer crystal field states. The influence of different transfer integrals involved in the kinetic exchange on the energy pattern and magnetic properties of the system is examined. The role of other related interactions (trigonal crystal field, spin–orbit coupling) is also discussed in detail. Using the pseudoangular momentum representation and …

Fuzzy logic approach to predict vehicle crash severity from acceleration data

2015

Vehicle crash is a complex behavior to be investigated as a challenging topic in terms of dynamical modeling. On this aim, fuzzy logic can be utilized to analyze the crash dynamics rapidly and simply. In this paper, the experimental data of the frontal crash is recorded using an accelerometer located at the centre of the gravity of the vehicle. The acceleration signal was the raw data from which the collision intensity expressed by the kinetic energy and the jerk were derived. The fuzzy logic model was then developed from the two inputs namely kinetic energy and jerk. The output variable is the crash severity expressed as the dynamic crash. The result shows that the jerk contributes much to…