Search results for "kompleksi"
showing 10 items of 201 documents
Kompleksie skaitļi vidusskolai
2020
Sākot ar 2020. gada 1. septembri, tiek ieviestas izmaiņas vidusskolas mācību saturā, kā rezultātā skolēniem turpmāk ir jāapgūst sasniedzamie rezultāti par kompleksajiem skaitļiem. Autors apkopoja tematam atbilstošu teorētisko materiālu, izstrādāja mācību saturu, atbilstoši saturam izstrādāja stundu plānus un tos aprobēja. Pētījuma rezultātā ir iegūts materiāls, kuru izmantojot, ir iespējams sekmīgi mācīt tematu un apgūt sasniedzamos rezultātus — gan temata apguvei nepieciešamos, gan papildu padziļinātai satura apguvei. Darbs ir izstrādāts kā pamata materiāls, kuru iespējams pielāgot atbilstoši skolēnu grupas spējām un prasībām — 1. nodaļā ir komplekso skaitļu teorija un vēsturiskais konteks…
Electronic spectroscopy of I2-Xe complexes in solid Krypton
2012
In the present work, we have studied ion-pair states of matrix-isolated I2 with vacuum-UV absorption and UV-vis-NIR emission, where the matrix environment is systematically changed by mixing Kr with Xe, from pure Kr to a more polarizable Xe host. Particular emphasis is put on low doping levels of Xe that yield a binary complex I2–Xe, as verified by coherent anti-Stokes Raman scattering (CARS) measurements. Associated with interaction of I2 with Xe we can observe strong new absorption in vacuum-UV, redshifted 2400 cm−1 from the X → D transition of I2. Observed redshift can be explained by symmetry breaking of ion-pair states within the I2–Xe complex. Systematic Xe doping of Kr matrices shows…
Iodination of antipyrine with [N–I–N]+ and carbonyl hypoiodite iodine(i) complexes
2023
A series of iodine(I) complexes, both known and new, were synthesised and the dependence of iodination reactivity on the identity of the Lewis bases and anions present was investigated. Using a previously established screening protocol based on the iodination of antipyrine to iodo-antipyrine, the capability of the iodine(I) species to perform the iodination was tested and compared, especially in relation to Barluenga's reagent, [I(pyridine)2]BF4. The results indicated that the identity of both the Lewis bases and the anion influence the iodination capability of the iodine(I) species, and that the less efficient reagents can deliver favourably comparable percentage conversions with longer re…
Carbonyl hypoiodites from pivalic and trimesic acid and their silver(I) intermediates
2022
The first tris(O–I–N) carbonyl hypoiodites have been synthesised based on trimesic acid and pyridine or 4-methylpyridine, with their structures definitively confirmed by single crystal X-ray diffraction (SCXRD). The more soluble carbonyl hypoiodites based on pivalic acid have also been studied via NMR, SCXRD, and computational analyses, enabling the study of the direct silver(I) precursor and intermediates of the resulting carbonyl hypoiodites generated using a range of substituted pyridines. peerReviewed
Halogen-Bonded [N–I–N]− Complexes with Symmetric or Asymmetric Three-Center–Four-Electron Bonds
2023
A series of LH[Z–I–Z] halogen(I) complexes, where Z = saccharinato or phthalimido anions and LH = pyridinium, pyrazinium, tetrabutyl (TBA)- or tetramethylammonium (TMA) cations, were prepared, structurally characterized, and discussed as complexes consisting of a [N–I–N]− anion with a three-center–four-electron (3c-4e) halogen bond, and a hydrogen-bonding (pyridinium or pyrazinium) or inert (TBA or TMA) cation. The symmetric [N–I–N]− anion, reminiscent of the triiodide [I–I–I]− anion, is found to be structurally equivalent to its cationic analogue [N–I–N]+ with N–I bond lengths of 2.26 Å. In contrast to the homoleptic [N–I–N]+ complexes, asymmetry of the N–I bond lengths (2.21 and 2.28 Å) w…
Macrocyclic complexes based on [N⋯I⋯N]+ halogen bonds
2021
New 1–2 nm macrocyclic iodine(I) complexes prepared VIA a simple ligand exchange reaction manifest rigid 0.5–1 nm cavities that bind the hexafluorophosphate anion in the gas phase. The size of the cavities and the electrostatic interactions with the iodine(I) cations influence the anion binding properties of these macrocyclic complexes. peerReviewed
Ligand exchange among iodine(I) complexes
2022
A detailed investigation of ligand exchange between iodine(I) ions in [N⋯I⋯N]+ halogen-bonded complexes is presented. Ligand exchange reactions were conducted to successfully confirm whether iodine(I) complex formation, via the classical [N⋯Ag⋯N]+ to [N⋯I⋯N]+ cation exchange reaction from their analogous Ag+ complexes, could be determined solely by using 1H NMR spectroscopy. In instances where the formation of the iodine(I) complex was unclear or in low yield by the traditional cation exchange reaction, a ligand exchange reaction was used to form the desired iodine(I) complexes in a quantitative manner. Mixing two homoleptic [N⋯I⋯N]+ iodine(I) complexes in 1 : 1 ratio was found to undergo a…
Ulomman reisilihaksen ja -kaksoiskantalihaksen toiminta erilaisissa ponnistuksissa kovalla ja kimmoisalla alustalla
2002
Koivunen, Joni. Ulomman reisilihaksen ja -kaksoiskantalihaksen toiminta erilaisissa ponnistuksissa kovalla ja kimmoisalla alustalla. Liikuntabiologian laitos. Jyväskylän Yliopisto, 2002. Pro gradu -tutkielma, 66 sivua. UltraääIlitekniikan käyttöönotto on mahdollistanut lihasjännekompleksin entistä tarkemman in vivo -tutkimuksen luonnollisen liikkeen aikana. Tämän tutkimuksen tarkoituksena oli tarkastella ponnistuksessa tärkeiden alaraajan ojentajalihasten, ulomman kaksoiskantalihaksenja ulomman reisilihaksen, toimintaa erilaisissa ponnistuksissa sekä kovalla että kimmoisalla alustalla. Tutkimukseen osallistui kaksi maajoukkuetason miestelinevoimistelijaa, jotka suorittivat pudotushyppyjä ko…
Synthesis and Solid-State X-ray Structure of the Mononuclear Palladium(II) Complex Based on 1,2,3-Triazole Ligand
2022
Herein, we described the synthesis and X-ray crystal structure of the new [Pd(3)2Cl2] complex with 1,2,3-triazole-based ligand (3). In the unit cell, there are two [Pd(3)2Cl2] molecules, and the asymmetric unit comprised half of this formula due to the presence of an inversion symmetry element at the Pd(II) center. The monoclinic unit cell volume is 1327.85(6) Å3, with crystal parameters of a = 10.7712(2) Å, b = 6.8500(2) Å, and c = 18.2136(6) Å, while β = 98.851(2)°. The structure comprised two trans triazole ligand units coordinated to the Pd(II) ion via one of the N-atoms of the triazole moiety. In addition, the Pd(II) is further coordinated with two tran…
Experimental and computational investigation on the formation pathway of [RuCl2(CO)2(ERR′)2] (E = S, Se, Te; R, R′ = Me, Ph) from [RuCl2(CO)3]2 and E…
2022
The pathways to the formation of the series of [RuCl2(CO)2(ERR′)2] (E = S, Se, Te; R, R′ = Me, Ph) complexes from [RuCl2(CO)3]2 and ERR′ have been explored experimentally in THF and CH2Cl2, and computationally by PBE0-D3/def2-TZVP calculations. The end-products and some reaction intermediates have been isolated and identified by NMR spectroscopy, and their crystal structures have been determined by X-ray diffraction. The relative stabilities of the [RuCl2(CO)2(ERR′)2] isomers follow the order cct > ccc > tcc > ttt ≈ ctc (the terms c/t refer to cis/trans arrangement of the ligands in the order of Cl, CO, and ERR′). The yields were rather similar in both solvents, but the reactions were signi…