Search results for "layer"

Variable Thickness Porous Anodic Alumina/Metal Film Bilayers for Optimization of Plasmonic Scattering by Nanoholes on Mirror

2018

Continuously variable thickness porous anodic aluminum oxide (PAAO) films were obtained using electrochemical oxidation of bulk aluminum sheet while both electrodes were simultaneously withdrawn from the electrolyte solution. The thickness gradient was controlled by the withdrawal rate (1–10 mm/min range) and thickness variation demonstrated from below 50 nm to above 1 micrometer. The thickness increased linearly with the sample lateral coordinate, whereas the nanopore structure (diameter and interpore distance) remained unchanged. Effects of the initial pore growth and capillary forces are discussed. The presented method can be used for tuning optimal PAAO thickness for optical and other a…

Experimental investigation of the cutting temperature when turning with coated indexable inserts

1999

Abstract This paper deals with an experimental investigation into the different factors which influence the temperature which occur at the coating/substrate–chip interface when machining a medium carbon steel and an austenitic stainless steel. Both flat-faced and grooved inserts coated with TiC, TiC/TiN and TiC/Al 2 O 3 /TiN were used. A standard K-type thermocouple embedded in the workpiece was used to convert measured efms to the interfacial temperature. Some optimal coating structures for high speed machining of these steels corresponding to the minimum interface temperature were selected. In particular, it was observed that by the proper selection of the thermal properties of the coatin…

Friction and wear properties of titanium and oxidised titanium in dry sliding against hardened C45 steel

2004

Abstract The aim of the paper is to present the results of conformal pin-on-disc tribological tests concerning the hard oxidised zone created in superficial layer of a titanium specimen sliding against the hardened to a hardness of 690 HV carbon C45 steel counterspecimen. Tribological testing was carried out at room temperature and at unlubricated conditions. After tests the structures and chemical compositions of the wear debris and worn surfaces were a subject of SEM and X-ray investigations. In comparison with the baseline the technical quality titanium/C45 steel couple, the wear and lifetime performance of the oxidised titanium/steel C45couple was markedly superior. Dominant wear debris…

Carbonization of disclike molecules in porous alumina membranes: toward carbon nanotubes with controlled graphene-layer orientation.

2005

Plasmonic Nanosensors for the Label-Free Imaging of Dynamic Protein Patterns.

2020

We introduce a new approach to monitor the dynamics and spatial patterns of biological molecular assemblies. Our molecular imaging method relies on plasmonic gold nanoparticles as point-like detectors and requires no labeling of the molecules. We show spatial resolution of up to 5 μm and 30 ms temporal resolution, which is comparable to wide-field fluorescence microscopy, while requiring only readily available gold nanoparticles and a dark-field optical microscope. We demonstrate the method on MinDE proteins attaching to and detaching from lipid membranes of different composition for 24 h. We foresee our new imaging method as an indispensable tool in advanced molecular biology and biophysic…

Atomic layer deposition of Ti-Nb-O thin films onto electrospun fibers for fibrous and tubular catalyst support structures

2018

Here, the authors report on the preparation of core-shell carbon-ceramic fibrous as well as ceramic tubular catalyst supports utilizing electrospinning and atomic layer deposition (ALD). In this paper, ALD of Ti-Nb-O thin films using TiCl4, Nb(OEt)5, and H2O as precursors is demonstrated. According to the time-of-flight-elastic recoil detection analysis and Rutherford backscattering spectrometry, carbon and hydrogen impurities were relatively low, but depend on the pulsing ratio of the precursors. Optimized ALD process was used for coating of sacrificial electrospun polyvinyl alcohol (PVA) template fibers to yield tubular Ti-Nb-O structures after thermal or solution based PVA removal. Anoth…

Catenanes and threaded systems: from solution to surfaces

2009

Functional catenanes and threaded systems able to perform controllable mechanical motions are ideally suited for the design of molecular devices displaying mechanical, electronic, information or sensing functions. These systems have been extensively studied in solution phase and numerous examples of stimuli-driven molecular shuttles have been reported. However, for fully developing their potential applications, they must be interfaced with the macroscopic world. To achieve this objective, in the last few years catenanes and rotaxanes have been organized over surfaces in the form of chemisorbed monolayers or physisorbed monolayers, multilayers and thin films. This tutorial review summarizes …

The phase composition of the passive layer on iron

1988

Layer-by-Layer Grafting of Molecularly Imprinted Polymers via Iniferter Modified Supports

2002

Probing the Atomic-Scale Structure of Monolayer-Protected Au38 Clusters

2010

Extended abstract of a paper presented at Microscopy and Microanalysis 2010 in Portland, Oregon, USA, August 1 – August 5, 2010.