Search results for "layer"

Langmuir-Blodgett films of indandione-1,3 pyridinium betaine. III: Linear dichroism and non-linear optical properties

1996

Linear dichroism and second-harmonic generation (SHG) have been measured in Langmuir-Blodgett (LB) multilayers of Z-type structure of amphiphilic indandione-1,3 pyridinium betaine (IPB) with an aliphatic tail containing 17 carbon atoms (C171PB). The dichr

Electrochemistry of methylene blue at an alkanethiol modified electrode

2012

International audience; Gold surfaces were derivatized with decanethiol. The electrochemistry of methylene blue at these modified electrodes was investigated in function of the gold cleaning process and compared with the results obtained at a bare gold electrode. Cyclic voltammetry at low methylene blue concentrations (c(MB) <= 16 mu M) yielded surface behavior data. The properties of the film vary with the electrode pretreatment. Without electrochemical cleaning step, the standard potential at a gold electrode modified with 1-decanethiol is nearly the same as on a bare gold electrode. On the other hand, when the electrode is electrochemically cleaned before adsorption of the alkanethiols, …

Electrochemical response of ferrocenium filled calix[4]arene capsules in solution and immobilized on gold

2008

Abstract Hydrogen-bonded dimers of tetra-urea calix[4]arenes are able to include ferrocenium ions as a guest. Heterodimeric capsules are exclusively formed in 1:1 mixtures of tetra-arylurea calix[4]arene 1 with tetra-tosylurea calix[4]arene 2. Sulfide groups attached via spacers on the urea rim of 1 allow their binding to metal surfaces rendering simultaneously their dissociation more difficult. Thus, the electrochemical response of encapsulated ferrocenium could be studied in a self-assembled monolayer (SAM) in addition to the solution electrochemistry with cyclic voltammetry. The stability of the electrochemically active monolayers was tested after a heat treatment (225 °C for 30 min in N…

Trimesic acid on Cu in ethanol: Potential-dependent transition from 2-D adsorbate to 3-D metal-organic framework

2017

We report the potential-dependent interactions of trimesic acid with Cu surfaces in EtOH. CV experiments and electrochemical surface-enhanced Raman spectroscopy show the presence of an adsorbed trimesic acid layer on Cu at potentials lower than 0 V vs Cu. The BTC coverage increases as the potential increases, reaching a maximum at 0 V. Based on molecular dynamics simulations, we report adsorption geometries and possible structures of the organic adlayer. We find that, depending on the crystal facet, trimesic acid adsorbs either flat or with one or two of the carboxyl groups facing the metal surface. At higher coverages, a multi-layer forms that is composed mostly of flat-lying trimesic acid…

Evaluation of Physicochemical Properties of Amphiphilic 1,4-Dihydropyridines and Preparation of Magnetoliposomes

2021

This study was focused on the estimation of the targeted modification of 1,4-DHP core with (1) different alkyl chain lengths at 3,5-ester moieties of 1,4-DHP (C12, C14 and C16)

Ab initio simulations on AgCl(111) surface and AgCl(111)/α-Al2O3(0001) interface

2005

The defect chemistry and ionic transport properties of the AgCl(111)/α-Al 2 O 3 (0001) interface were consid by using ab initio slab calculations. These calculations were performed in the framework of plane-wave basis combined with the density functional theory (DFT), as implemented into the VASP computer code, and Gaus basis set combined with the Hartree-Fock method (CRYSTAL-98 code). We analyze the electron density distribu on the interface and the electrostatic potential distribution near the AgCl surface. The size of the silver ion is great to enter the corundum surface layer and to create excess silver ions in this way. This is in agreement the experiments on heterogeneous doping of Ag…

An efficient data model for energy prediction using wireless sensors

2019

International audience; Energy prediction is in high importance for smart homes and smart cities, since it helps reduce power consumption and provides better energy and cost savings. Many algorithms have been used for predicting energy consumption using data collected from Internet of Things (IoT) devices and wireless sensors. In this paper, we propose a system based on Multilayer Perceptron (MLP) to predict energy consumption of a building using collected information (e.g., light energy, day of the week, humidity, temperature, etc.) from a Wireless Sensor Network (WSN). We compare our system against four other classification algorithms, namely: Linear Regression (LR), Support Vector Machin…

Safeguarding the Ultra-dense Networks with the aid of Physical Layer Security: A review and a case study

2016

In the wake of the extensive application of the fourth generation system, investigations of new technologies have been moving ahead vigorously to embrace the next generation communications in 2020. Thereinto, the technique of ultra-dense networks (UDNs) serves as a key enabler in meeting the roaring mobile traffic demands. With the prevalence of mobile Internet services especially those involve the mobile payment, security has gained an unprecedented amount of attention and become a highlighted feature for the fifth generation. Resource allocation, one of the most significant tools on getting over the obstacle of ubiquitous interference as well as elevating the spectrum/energy efficiency, h…

Antiferromagnetism-Induced Spin Splitting in Systems Described by Magnetic Layer Groups

2021

Short Photoluminescence Lifetimes Linked to Crystallite Dimensions, Connectivity, and Perovskite Crystal Phases.

2022

Time-correlated single photon counting has been conducted to gain further insights into the short photoluminescence lifetimes (nanosecond) of lead iodide perovskite (MAPbI3) thin films (∼100 nm). We analyze three different morphologies, compact layer, isolated island, and connected large grain films, from 14 to 300 K using a laser excitation power of 370 nJ/cm2. Lifetime fittings from the Generalized Berberan-Santos decay model range from 0.5 to 6.5 ns, pointing to quasi-direct bandgap emission despite the three different sample strains. The high energy band emission for the isolated-island morphology shows fast recombination rate centers up to 4.8 ns–1, compared to the less than 2 ns–1 for…