Search results for "layer"

From determination of the fugacity coefficients to estimation of hydrogen storage capacity: A convenient theoretical method

2015

Abstract The equation of state (EOS) from virial expansion (VE) is used in this work to pave the way for determining the fugacity coefficients of the hydrogen fluid at arbitrary temperature and pressure. The fugacity coefficients from our VE method have more physical meanings than the empirical values. In this way, the hydrogen storage capacity of a novel material model can be estimated by using few density functional theory (DFT) calculations with the aid of a continuum model. The efficient continuum model can provide a more accurate estimation of the hydrogen storage capacity than the pure DFT calculations. Furthermore, the expensive grand canonical ensemble (μNT) simulations combining wi…

Rapid Surface Functionalization of Hydrogen-Terminated Silicon by Alkyl Silanols

2017

Surface functionalization of inorganic semiconductor substrates, particularly silicon, has focused attention toward many technologically important applications, involving photovoltaic energy, biosensing and catalysis. For such modification processes, oxide-free (H-terminated) silicon surfaces are highly required, and different chemical approaches have been described in the past decades. However, their reactivity is often poor, requiring long reaction times (2-18 h) or the use of UV light (10-30 min). Here, we report a simple and rapid surface functionalization for H-terminated Si(111) surfaces using alkyl silanols. This catalyst-free surface reaction is fast (15 min at room temperature) and…

Landslides as Important Disturbance Regimes — Causes and Regeneration

2008

Procesos fluviales en lechos con materiales gruesos

2013

Fluvíal processes ingravel-bed rívers. The bedload transport processes ingravel-bed rívers are not very known. The two most frequent features that characterize these rívers are the presence of a scour layer and the pavement. The coarse surface layer causes a great resistance to flow in gravel-bed rívers. So, flow resítance equations for computing average velocity can be applíed.

Soils Along the Altitudinal Transect and in Catchments

2008

Nutrient Status and Fluxes at the Field and Catchment Scale

2008

Hydrological effects of a layer of vegetation ash on underlying wettable and water repellent soil

2012

Abstract Hydrological processes after a wildfire may take place under soil conditions altered by heat and by the presence of ash. Soil and ash interact as a two-layer system with poorly understood hydrological properties, especially when ash covers water repellent soil. Here we quantify the effect of an ash layer (0, 5, 15 and 30 mm depth) covering wettable and water repellent soil on (i) the hydrological response and the mechanism of runoff generation and (ii) the water repellency dynamics, for a rainfall event followed by different drying periods and a second rainfall event. Laboratory rainfall simulation experiments (82.5 mm h − 1 during 40 min) at small plot-scale (0.09 m 2 ) were perfo…

Flow resistance ofPosidonia oceanicain shallow water

2006

Management of coastal waters and lagoons by mathematical circulation models requires determination of the hydraulic resistance of submerged vegetation. A plant typical of sandy coastal bottoms in the Mediterranean Sea is Posidonia oceanica, which is constituted by very thin and flexible ribbon-like leaves, about 1 cm wide and up to 1.5 m long, and usually covers the bottom with a density of 500-1000 plants/ m2. From the hydraulic viewpoint, P. oceanica constitutes a particular roughness, because, as the velocity increases, the leaves bend more and more until they lie down on the bottom. Although P. oceanica is widespread, in the technical literature it is difficult to find indications about…

Biopolymeric bilayer films produced by co-extrusion film blowing

2018

Abstract Biodegradable packaging promises a more environmentally friendly future. Nevertheless, a single biopolymer often lacks of some important properties. In order to contribute to this challenge, biodegradable bilayer films from poly(lactic acid) (PLA) and MaterBi® were prepared in this work and compared with monolayer films obtained with both the polymers. The prepared films were fully characterized through morphological, mechanical, thermal, chemical, optical and water contact angle analyses. Furthermore, the hydrolytic degradation of monolayer and bilayer films was studied by performing tests at three different pH. The morphological analysis revealed that PLA/MaterBi bilayer films sh…

XPS study of leached glass surfaces

1990

Abstract By use of a special deconvolution algorithm, it was possible to decompose the XPS O 1s signal into several components reflecting different oxygen bonds. The influence of exposure in vacuo, environmental atmosphere, distilled water, and in a polish solution as corrosive media on the surface of different glasses has been studied. The O 1s signals of fused silica, Na 2 O· n SiO 2 glasses, a BaO·SiO 2 and a BaOB 2 O 3 SiO 2 glass (Schott SK 16) were analyzed. On the glass surfaces, leached layers were formed and analyzed qualitatively and semiquantitatively by XPS and optical and infrared methods. As a reference, virgin surfaces of samples broken in ultrahigh vacuum have been used. T…