Search results for "layered"
showing 10 items of 142 documents
Generalised bisection method for optimum ultrasonic ray tracing and focusing in multi-layered structures
2021
Ultrasonic testing has been used for many decades, proving itself very efficient for detecting defects in many industrial sectors. The desire to apply ultrasonic testing to geometrically complex structures, and to anisotropic, inhomogeneous materials, together with the advent of more powerful electronics and software, is constantly pushing the applicability of ultrasonic waves to their limits. General ray tracing models, suitable for calculating the proper incident angle of single element probes and the proper time delay of phased array, are currently required. They can support the development of new imaging techniques, as Full Matrix Capture and Total Focusing Method, and the execution of …
Unveiling the Occurrence of Co(III) in NiCo Layered Electroactive Hydroxides: The Role of Distorted Environments
2020
Co- and Ni-based layered hydroxides constitute a unique class of two-dimensional inorganic materials with exceptional chemical diversity, physicochemical properties and outstanding performance as supercapacitors and overall water splitting catalysts. Recently, the occurrence of Co(III) in these phases has been proposed as a key factor that enhance their electrochemical performance. However, the origin of this centers and control over its contents remains as an open question. We employed the Epoxide Route to synthesize a whole set of α-NiCo layered hydroxides. The PXRD and XAS characterization alert about the occurrence of Co(III) as a consequence of the increment in the Ni content. DFT+U si…
Halide-Mediated Modification of Magnetism and Electronic Structure of α-Co(II) Hydroxides: Synthesis, Characterization, and DFT+U Simulations.
2019
The present study introduces a comprehensive exploration in terms of physicochemical characterization and calculations based on density functional theory with Hubbard's correction (DFT+U) of the whole family of α-Co(II) hydroxyhalide (F, Cl, Br, I). These samples were synthesized at room temperature by employing a one-pot approach based on the epoxide route. A thorough characterization (powder X-ray diffraction, X-ray photoelectron spectroscopy, thermogravimetric analysis/mass spectroscopy, and magnetic and conductivity measurements) corroborated by simulation is presented that analyzes the structural, magnetic, and electronic aspects. Beyond the inherent tendency of intercalated anions to …
Emerging switchable ultraviolet photoluminescence in dehydrated Zn/Al layered double hydroxide nanoplatelets
2019
AbstractLayered double hydroxides show intriguing physical and chemical properties arising by their intrinsic self-assembled stacking of molecular-thick 2D nanosheets, enhanced active surface area, hosting of guest species by intercalation and anion exchanging capabilities. Here, we report on the unprecedented emerging intense ultraviolet photoluminescence in Zn/Al layered double hydroxide high-aspect-ratio nanoplatelets, which we discovered to be fully activated by drying under vacuum condition and thermal desorption as well. Photoluminescence and its quenching were reproducibly switched by a dehydration–hydration process. Photoluminescence properties were comprehensively evaluated, such a…
The internally layered foot in Dutch
2017
AbstractRecent metrical studies have proposed that, under certain circumstances, a weak syllable may be adjoined to a binary foot, giving rise to a minimally recursive foot. Adding to a growing body of research from metrical stress and foot-conditioned phenomena in various languages, the goals of this paper are twofold. First, we aim at providing empirical evidence for internally layered feet based on the distribution of three foot-conditioned processes of Dutch: vowel reduction, glottal stop /ʔ/ insertion and /h/ licensing/deletion. Second, we explore a less studied theoretical and descriptive advantage of internally layered feet: their potential to predict phonological strength distinctio…
Specific separation and recovery of phosphate anions by a novel NiFe-LDH/rGO hybrid film based on electroactivity-variable valence
2022
Phosphorus is a non-renewable resource. Supplies are limited and much phosphorus is currently wasted during the production and utilization process, causing concerns about future supplies and widespread environmental problems. To solve these problems, a new type of NiFe-LDH/rGO electrically switched ion-selective (ESIX) film is designed, based on the dominant mechanism of inner-sphere complexation. An ESIX process allows the NiFe-LDH/rGO hybrid film to achieve a controllably selective uptake and release of the phosphate anions. This route involves tuning potential steps to regulate the redox states of the composite film and the variable metal (e.g., Ni, Fe (II)/(III)) in coordination centers…
From measuring to revealing. 7 Paradigmatic actions for the construction of models as tools of representation
2017
L’esperienza maturata nel corso della ricerca: Progettazione, Organizzazione e Gestione di un nuovo Laboratorio di modellistica: metodologie, materiali e strumenti, (piani cazione, organizzazione e gestione di un nuovo laboratorio di modellazione: metodologie, materiali e strumenti), presso il Politecnico di Milano, è il background di questo articolo proposto per la giornata di studi. Da questa esperienza il testo si concentra sul set-up della seguente dichiarazione: il modello architettonico come strumento di rappresentazione. L’obiettivo è quello di formulare alcune procedure metodologiche, attraverso sette diverse azioni di progetto: scavo, taglio, piegatura, stratificazione, intaglio, m…
MZ-35, a new layered pentasil borosilicate synthesized in the presence of large alkali cations
2013
Abstract A new layered borosilicate has been synthesized in the presence of cesium and sodium cations and its structure has been solved by a combination of automated diffraction tomography (ADT) and X-ray powder diffraction (XRPD). MZ-35 has a composition NaCs 2 [BSi 7 O 16 (OH) 2 ](OH) 2 ·4H 2 O and features space group P-4m2. The unusually small unit cell ( a 7.3081 A, c 10.7520 A) is shared by two random-stacked configurations of the structure: a network of connected pentasil units related to the layer of RUB-18 and a bidimensional checkerboard of intersecting ladders of 4-membered rings. The two configurations are related by the simple face-sharing inversion of a hydroxyl-bearing tetrah…
A beam theory for layered composites subjected to uniformly distributed load
2015
A theory for multilayered composite beams undergoing transverse uniformly distributed loads is presented. The formulation starts by assuming a layer-wise kinematical model characterized by third order approximation of the axial displacements and fourth order approximation of the transverse displacements. By enforcing the point-wise balance equations as well as the interface continuity conditions, the layer-wise kinematical model is rewritten in terms of a set of generalized kinematical variables associated with the beam as a whole. Stress resultants are then obtained in terms of the generalized variables derivatives and of the normal stresses applied to the top and bottom surfaces of the la…
Multilayered cultural identity and the perception of the self
2012
This qualitative study examines the reciprocal relationship between a person’s multilayered cultural identity (MCI) and the concept of self (CoS), that is presented purely on a theoretical level and encompasses various theories. Nowadays, in an increasingly globalising world, it is not enough to merely look at a national, ethnic or other type of identity. It is important to realise that there are different layers in an identity that one can view themselves through. The ways an individual perceives themselves through their multicultural background can also be different. This thesis helps identify the ways a person can see themselves. The thesis also attempts to explain the varied nature of o…