Search results for "layered"
showing 10 items of 142 documents
A discontinuous Galerkin formulation for nonlinear analysis of multilayered shells refined theories
2023
A novel pure penalty discontinuous Galerkin method is proposed for the geometrically nonlinear analysis of multilayered composite plates and shells, modelled via high-order refined theories. The approach allows to build different two-dimensional equivalent single layer structural models, which are obtained by expressing the covariant components of the displacement field through-the-thickness via Taylor’s polynomial expansion of different order. The problem governing equations are deduced starting from the geometrically nonlinear principle of virtual displacements in a total Lagrangian formulation. They are addressed with a pure penalty discontinuous Galerkin method using Legendre polynomial…
Ultralow thermal conductivity in 1D and 2D imidazolium-based lead halide perovskites
2021
Low-dimensional hybrid organic–inorganic metal halide perovskites are rapidly emerging as a fascinating sub-class of the three-dimensional parent structures, thanks to their appealing charge and thermal transport properties, paired to better chemical and thermal stabilities. Extensive investigations of the thermal behavior in these systems are of paramount relevance to understand their optoelectronic and thermoelectric applications. Herein, we present a complete thermophysical characterization of imidazolium lead iodide, (IMI)PbI3, a 1D pseudo-perovskite with chains of face-sharing octahedra, and histammonium lead iodide, (HIST)PbI4, a 2D layered perovskite with corner-sharing octahedra. Up…
ChemInform Abstract: Hybrid Materials Based on Magnetic Layered Double Hydroxides: A Molecular Perspective
2015
ConspectusDesign of functional hybrids lies at the very core of synthetic chemistry as it has enabled the development of an unlimited number of solids displaying unprecedented or even improved properties built upon the association at the molecular level of quite disparate components by chemical design. Multifunctional hybrids are a particularly appealing case among hybrid organic/inorganic materials. Here, chemical knowledge is used to deploy molecular components bearing different functionalities within a single solid so that these properties can coexist or event interact leading to unprecedented phenomena. From a molecular perspective, this can be done either by controlled assembly of orga…
Influence of morphology in the magnetic properties of layered double hydroxides
2018
We report the controlled synthesis of magnetic CoAl and NiFe layered double hydroxides (LDHs) endowed with well-defined morphology (hexagonal and flower-like shapes) by means of modified homogeneous precipitation. These layered magnets display high crystallinity and micrometric size, thus offering a perfect scenario for the elucidation of the role exerted by distortion of the layers in their magnetic behaviour. The magnetic properties have been investigated by means of DC and AC magnetic susceptibility measurements and isothermal magnetization, demonstrating that the distortion of the nanosheets induces a magnetically more disordered behaviour, with marked spin-glass nature, independently o…
A comparison between models for the study of static and dynamic behavior of heterogeneous multilayer composite plates
2013
In composite plate structures, it is common to combine different materials with very different Young's moduli and densities. Damping treatments can also be added to prevent high levels of vibration. For discretized problems, the static and dynamic behavior of such heterogeneous structures can be carried out with the 3D elasticity theory but this often leads to very large systems. Therefore, plate theories and particularly equivalent single layer models are often preferred. Classical plate theories have then been adapted to these particular structures using shear correction factors. Higher order shear deformation theories, and more recently transverse shear warping functions, have been propo…
Variable kinematics equivalent single layer theories for magneto-electro-elastic multilayered plates
2014
In recent years, the employment of smart materials able to provide multi-functional capabilities, besides the traditional structural functions, has been gaining attention in several technological fields (automotive, aerospace, biomedical, robotics, etc.). This possibility of coupling different physical fields can be and it has been exploited in transducer applications, structural health monitoring, vibration control, energy harvesting and other applications. In this framework, magneto-electro-elastic (MEE) materials are attracting increasing consideration from academic and industrial audiences: MEE materials have the ability to couple mechanical, electrical and magnetic fields and this make…
Transverse shear warping functions for anisotropic multilayered plates
2012
In this work, transverse shear warping functions for an equivalent single layer plate model are formulated from a variational approach. The part of the strain energy which involves the shear phenomenon is expressed in function of the warping functions and their derivatives. The variational calculus leads to a differential system of equations which warping functions must verify. Solving this system requires the choice of values for the (global) shear strains and their derivatives. A particular choice, which is justified for cross-ply laminates, leads to excellent results. For single layer isotropic and orthotropic plates, an analytical expression of the warping functions is given. They invol…
Growth and characterization of PbI2-decorated ZnO nanowires for photodetection applications
2020
Financial support provided by Scientific Research Project for Students and Young Researchers Nr. SJZ/2017/1 realized at the Institute of Solid State Physics, University of Latvia is greatly acknowledged. The authors are grateful to Liga Bikse for XRD measurements.
Hybrid Magnetic Multilayers by Intercalation of Cu(II) Phthalocyanine in LDH Hosts
2012
The intrinsic flexibility of layered double hydroxides (LDHs) has been here exploited to design hybrid multilayered materials by intercalation of the copper phthalocyaninetetrasulfonate (CuPcTs) complex in the interlamellar space offered by these layered hosts through a simple anion-exchange procedure. Taking advantage of their chemical versatility, two different LDHs, the diamagnetic ZnAl and the ferromagnetic NiAl, have been synthesized and characterized to explore the differences in the magnetic properties of the hybrids introduced by the intercalation of the paramagnetic complex.
Multilayered samples reconstructed by measuring Kα/Kβ or Lα/Lβ X-ray intensity ratios by EDXRF
2013
Abstract In this paper a general method based on energy-dispersive X-ray fluorescence (EDXRF) analysis has been tested to assess its possible use as a tool to reconstruct the structure and determine the thickness of two and/or multi-layered materials. The method utilizes the X-ray intensity ratios of Kα/Kβ or Lα/Lβ peaks (or the ratio of these peaks) for selected elements present in multi-layered objects of various materials (Au alloys, gilded Cu, gilded Ag, gilded Pb, Ag–Au Tumbaga, stone surfaces with protective treatments, Zn or Nickel plating on metals). Results show that, in the case of multi-layered samples, a correct calculation of the peak ratio (Kα /Kβ and/or Lα/Lβ) of relevant ele…