Search results for "light emission"
showing 10 items of 70 documents
A new flow cell design for chemiluminiscence analysis.
2001
The present study proposes a new flow cell called a bundle cell for chemiluminescence analysis. The results obtained were compared with those achieved by manual and automated batch procedures and flow manifolds with different cells: an common quartz flow cell, a helix cell and the most used spiral cell. Figures of merit such as limit of detection, sensitivity, accuracy and precision for the Cr(III) determination were established with light emission produced by catalysed Cr(III) luminol oxidation by hydrogen peroxide in a basic aqueous solution. An improvement in sensitivity about 50% as compared with the spiral cell and even larger with respect to the other flow cells tested was observed. T…
A tandem-flow assembly for the chemiluminometric determination of hydroquinone
2003
A direct chemiluminescent procedure for determination of hydroquinone based on the emergent flow methodology known as multicommutation or tandem-flow is presented for first time. The manifold was based on a set of three channels and three solenoid valves; and, the determination was performed at 60degreesC and at flow-rate of 7.5 ml min(-1). The complete cycle lasted 35 s, which resulted in a sample flow trough of 103 h(-1). The chemical process was the hydroquinone oxidation with the system sulphuric acid-potassium permanganate; and the light emission was clearly enhanced by the presence of quinine sulphate and benzalkonium chloride reaching a detection limit of 30 Rg l(-1). The dynamic int…
Theoretical prediction of the chemiluminescence behaviour of the ergot alkaloids
2004
Abstract The present manuscript is dealing with the application of molecular connectivity calculations to predict the chemiluminescent behaviour of ergot alkaloids when they react with common strong oxidants in liquid phase. Twenty compounds were theoretically studied by means of a discriminant equation formerly published, being 19 of them predicted as chemiluminescent with a high probability. Empirical confirmation of the chemiluminometric behaviour is performed with the few soluble and commercially available ergot alkaloids. On the basis of these results, a new FIA-direct chemiluminescent method is proposed for the determination of the ergot presenting the higher light emission, the pharm…
Influence of water sample storage protocols in chemiluminescence detection of trace elements.
2002
This paper shows the influence of different sample storage protocols, on the chemiluminescence signal of some metal ions. The storage protocols studied were: acid addition (HCl or HNO(3)) and no reagent addition to filtered and refrigerated (T=4 degrees C) samples. Light emission was produced for the chemiluminescence reaction between luminol and hydrogen peroxide in buffer carbonate conditions (pH 10.8) catalysed by Cr(III), Co(II) and Cu(II). Batch and/or flow modes in different conditions were tested. Fe(II), Fe(III), Ni(II) and Mn(II) did not give chemiluminescence in the studied conditions. A parallel study of sensitivity and selectivity was performed. Then the presence or absence of t…
Optical Plasmonic Yagi-Uda Nano-Antennas Array for Energy Harvesting Applications
2020
Optical nanoantennas have been of great interest recently due to their ability to support a highly efficient, localized surface plasmon resonance and produce significantly enhanced and highly confined electromagnetic fields. The Yagi-Uda nanoantenna, an optical analogue of the well-established radiofrequency Yagi-Uda antenna, stands out by its efficient unidirectional light emission and enhancement. In this paper, the design of an optical plasmonic Yagi-Uda nanoantenna for energy harvesting application is proposed. The enhancement of the directivity is reached by means of an organization in array. The simulation results, carried out by 3D code CST Studio, show that the proposed nanoantenna …
Frequency mapping in dynamic light emission with wavelet transform
2013
International audience; Dynamic photon emission microscopy is an e cient tool to analyse today's integrated circuit. Nevertheless, the reduction of transistor's dimensions leads to more complex acquisitions where many spots can be seen. A frequency characterization of the whole acquired area can help to have a better understanding of it. With that purpose in mind, a new methodology to draw frequency mapping of dynamic light emission acquisition is reported. It is fully automated and based on wavelet transform and autocorrelation function. Regarding the possible use in an industrial context, the suggested method can help to localize abnormal emission activity and it gives some perspectives o…
Theoretical study of the dark photochemistry of 1,3-butadiene via the chemiexcitation of Dewar dioxetane.
2015
Excited-state chemistry is usually ascribed to photo-induced processes, such as fluorescence, phosphorescence, and photochemistry, or to bio-and chemiluminescence, in which light emission originates from a chemical reaction. A third class of excited-state chemistry is, however, possible. It corresponds to the photochemical phenomena produced by chemienergizing certain chemical groups without light - chemiexcitation. By studying Dewar dioxetane, which can be viewed as the combination of 1,2-dioxetane and 1,3-butadiene, we show here how the photo-isomerization channel of 1,3-butadiene can be reached at a later stage after the thermal decomposition of the dioxetane moiety. Multi-reference mult…
Experimental study of hydrogen plasma breakdown in a 2.45 GHz microwave discharge
2013
Temporal evolution of microwave-plasma coupling, vacuum ultraviolet (VUV) light emission and plasma electron temperature and density is reported for a 2.45GHz microwave hydrogen discharge pulsed at 50Hz. Directional couplers, a VUV spectrometer and a Langmuir probe are used for the diagnostics of the plasma breakdown. A 5‐10 µs transient peak of light emission exceeding the steady-state intensity by a factor of 3.3 is observed in coincidence with an abrupt drop in the microwave electric field. Observed light emission intensities combined with cross section data indicate that the electron temperature during the breakdown transient exceeds the steady-state value of 4‐6eV by a factor 3, which …
Plasma distributions observed in a 2.45 GHz hydrogen discharge
2014
The existence of various spatial distributions of hydrogen plasma in a pulsed 2.45 GHz microwave discharge is demonstrated. The data has been obtained through optical emission diagnostics utilizing an ultra-fast CCD camera system with multi-channel plate (MCP) intensifiers, and a wavelength-filtered photodiode recording temporal light emission signals of hydrogen atoms and molecules. It has been observed that the magnetic field topology and strength are determining the transitions between different plasma patterns and spectral saturation times while neutral gas pressure and microwave power show a weaker influence on the profiles but affect the emitted light intensity.
A Novel Enzyme-Triggered Domino Reaction Producing Fluorescent Quinoxalin-2(1H)-One-Based Heterocycles
2020
A simple and effective biocompatible domino reaction triggered by a model protease and leading to formation of strongly fluorescent quinoxalin-2(1H)-one N-heterocycles is described. Some positive attributes including versatility and ability to provide outstanding fluorescence "OFF-ON" responses were revealed by this work. They open the way for practical applications of this novel type of "covalent-assembly" based fluorescent probes in the fields of sensing and bioimaging.; A simple and effective biocompatible domino reaction triggered by a model protease and leading to formation of strongly fluorescent quinoxalin-2(1H)-one N-heterocycles is described. Some positive attributes including vers…