Search results for "liquid crystal"

Nucleation in suspensions of anisotropic colloids

2005

We report Monte Carlo studies of liquid crystal nucleation in two types of anisotropic colloidal systems: hard rods and hard ellipsoids. In both cases we find that nucleation pathways differ strongly from the pathways in systems of spherical particles. Short hard rods show an effect of self-poisoning. This part of the article is based on a previous publication [T. Schilling, D. Frenkel, Self-poisoning of crystal nuclei in hard-rod liquids, Phys. Rev. Lett. 92 (2004) 085505]. When a crystallite forms, its surfaces are covered preferentially by rods which align perpendicular to the surface. Therefore subsequent growth is stunted. Hard, almost spherical ellipsoids can be compressed to very hig…

Characterization of different regimes in nonlinear liquid crystal models

2012

[EN] The range of validity of two models for nonlocal nonlinear optics in Nematic Liquid Crystals (NLC) is studied. Particularly the influence of the optical power and the initial position of the beam over its trajectory is studied when launching the beam with an offset in a planar cell. The main difference between both models is the dependence of the orientational angle with the optical field, either linear or nonlinear. The results demonstrate the critical role of the nonlinearity in the propagation of nematicons in NLC planar cells. © 2012 World Scientific Publishing Company.

FERROELECTRIC LIQUID CRYSTAL GLASSES FOR AMBLYOPIA RESEARCH

2008

ABSTRACT Ferroelectric Liquid Crystal (FLC) filters offer the speed of electronic light shutters and the vibration free operation. These characteristics make them ideal for applications requiring short exposure times and minimal blur, offering switching times of 0.0002 of a second. FLC filters can be used as the optical shutters for machine vision purposes, also in vision research. On the basis of FLC filters we have developed ferroelectric glasses, allowing temporal separation of optical information for both eyes. In the case of amblyopia (“lazy eye”) the only way to oblige the “lazy” eye to work is to close the other better-seeing eye. We advice an appliance for dynamic visual system trai…

Mesomorphic and electrooptical properties of viologens based on non-symmetric alkyl/polyfluoroalkyl functionalization and on an oxadiazolyl-extended …

2019

Two different sets of ionic liquid crystals based on bistriflimide salts of non-symmetrically substituted polyfluorinated bipyridinium (viologens) and bent symmetrically substituted dialkyl-oxadiazolyl-bipyridinium have been synthesized, in order to study the effect on the mesomorphic and electrooptical properties of the non-symmetric functionalization (alkyl chain and fluoroalkyl chains of different lengths) on the two pyridinium rings and additionally the effect of a bent conjugated spacer among the two pyridinium units of the viologen. POM and DSC characterization show that the synthesized salts have a mesomorphic and, in some cases, polymesomorphic behaviour in a wide thermal range, als…

A New Opto-dielectric Effect Based on the Photoisomerization of Azo Compounds in Ferroelectric Liquid Crystals

1995

Tradition and innovation in science

2006

A Commentary on the paper ”Self‐organization of substituted azacrowns based on their discoid and amphiphilic nature„, by C. Mertesdorf and H. Ringsdorf. First published in Liquid Crystals, 5, 1757‐1772 (1989).

Development and In Vitro Evaluation of Lyotropic Liquid Crystals for the Controlled Release of Dexamethasone.

2017

Made available in DSpace on 2018-12-11T17:33:26Z (GMT). No. of bitstreams: 0 Previous issue date: 2017-08-02 Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) In this study, amphiphilic polymers were investigated as biomaterials that can control dexamethasone (DXM) release. Such materials present interfacial properties in the presence of water and an oily phase that can result in lyotropic liquid crystalline systems (LLCS). In addition, they can form colloidal nanostructures similar to those in living organisms, such as bilayers and hexagonal and cubic phases, which can be exploited to solubilize lipophilic drugs to sustain their release and enhance bioavailability. It was…

Capillary Nematization of Semiflexible Polymers

2016

emiflexible polymers under good solvent conditions confined by two planar parallel repulsive walls are investigated for a wide range of monomer concentrations and distances between the walls, for a case where persistence length and contour length of the macromolecules are almost equal. Chain conformations and local nematic ordering near the walls are studied by both molecular dynamics methods and density functional theory, putting it in perspective with the recent work where the isotropic phase of semiflexible polymer solutions in the vicinity of a single repulsive wall in semi-infinite geometry is considered. Profiles of the total density of monomers as well as densities of end- and middle…

Macromol. Chem. Phys. 21/2013

2013

Densely packed semiflexible macromolecules in a rigid spherical capsule

2018

The ordering of semiflexible polymers with persistence length lp and contour length L confined in a sphere of radius R is studied by molecular dynamics simulations of a coarse-grained model. Monomer densities are chosen where the corresponding bulk lyotropic solution or melt is a well-ordered nematic, and purely repulsive walls of the rigid confining sphere are considered. It is found that polymers close to the walls are bent according to the curvature of the confining spheres with all their monomers in a few layers parallel to the sphere surface, whereas the remaining macromolecules closer to the sphere center have one chain end and their center of mass far from the surface. The latter cha…