Search results for "liquid"

Influence of drag and turbulence modelling on CFD predictions of solid liquid suspensions in stirred vessels

2014

Abstract Suspensions of solid particles into liquids within industrial stirred tanks are frequently carried out at an impeller speed lower than the minimum required for complete suspension conditions. This choice allows power savings which usually overcome the drawback of a smaller particle-liquid interfacial area. Despite this attractive economical perspective, only limited attention has been paid so far to the modelling of the partial suspension regime. In the present work two different baffled tanks stirred by Rushton turbines were simulated by employing the Eulerian-Eulerian Multi Fluid Model (MFM) along with either the Sliding Grid algorithm (transient simulations) or the Multiple Refe…

Liquid-phase Chemistry

2003

From magnetic to nonlinear optical switches in spin-crossover complexes

2013

ISI Document Delivery No.: 109TF Times Cited: 0 Cited Reference Count: 173 Lacroix, Pascal G. Malfant, Isabelle Real, Jose-Antonio Rodriguez, Vincent Wiley-v c h verlag gmbh Weinheim Si; Various attempts to combine magnetic and nonlinear optical (NLO) properties in a molecule are reviewed, with a special focus on the possibility of interplay between the magnetic component and the quadratic (proportional to E-2) NLO response. This multidisciplinary research leads to the idea of spin-crossover-induced (SCO-induced) NLO switching and is evaluated at the synthetic level, with insights provided by computational chemistry. The need for nontraditional experimental setups to record NLO properties i…

Financial Fragility and Interacting Units: an Exercise

2010

This paper assumes that financial fluctuations are the result of the dynamic interaction between liquidity and solvency conditions of individual financial units. The framework is designed as a heterogeneous agent model which proceeds through discrete time steps within a finite time horizon. The interaction at the microlevel between financial units and the market maker, who is in charge of clearing the market, produces interesting complex dynamics. The model is analyzed by means of numerical simulations and agent-based computational economics (ACE) approach. The behaviour and evolution of financial units are studied for different parameter regimes in order to show the importance of the param…

Market reaction to a bid-ask spread change: a power-law relaxation dynamics.

2009

We study the relaxation dynamics of the bid-ask spread and of the midprice after a sudden variation of the spread in a double auction financial market. We find that the spread decays as a power law to its normal value. We measure the price reversion dynamics and the permanent impact, i.e., the long-time effect on price, of a generic event altering the spread and we find an approximately linear relation between immediate and permanent impact. We hypothesize that the power-law decay of the spread is a consequence of the strategic limit order placement of liquidity providers. We support this hypothesis by investigating several quantities, such as order placement rates and distribution of price…

Further improvements of the water-cooled Pb–17Li blanket

2001

Abstract The water-cooled lithium–lead (WCLL) blanket is based on reduced-activation ferritic–martensitic steel as the structural material, the liquid alloy Pb–17Li as breeder and neutron multiplier, and water at typical PWR conditions as coolant. It was developed for DEMO specifications and shall be tested in ITER. In 1999, a reactor parameter optimization was performed in the EU which yielded improved specifications of what could be an attractive fusion power plant. Compared to DEMO, such a power reactor would be different in lay-out, size and performance, thus requiring to better exploit the potential of the WCLL blanket concept in conjunction with a water-cooled divertor. Several new ap…

Sample Preparation to Determine Pharmaceutical and Personal Care Products in an All-Water Matrix: Solid Phase Extraction

2020

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On the use of PET-LCP copolymers as compatibilizers for PET/LCP blends

1996

Copolyesters of poly[ethylene terephthalate) (PET) with a liquid crystalline polymer (LCP), SBH 1:1:2, have been synthesized by the polycondensation, carried out in the melt at temperatures up to 300 degrees C of sebacic acid (S), 4,4'-dihydroxybiphenyl (B), and 4-hydroxybenzoic acid (H) in the presence of PET. The PET-SBH copolyesters have been characterized by differential scanning calorimetry, scanning electron microscopy, X-ray diffraction, etc., and the relationships between properties and preparation conditions are discussed. The copolyesters show a biphasic nature, which is more evident for the products synthesized with a thermal profile comprising relatively lower temperatures (220-…

Fluctuating Interfaces in Liquid Crystals

2008

We review and compare recent work on the properties of fluctuating interfaces between nematic and isotropic liquid-crystalline phases. Molecular dynamics and Monte Carlo simulations have been carried out for systems of ellipsoids and hard rods with aspect ratio 15:1, and the fluctuation spectrum of interface positions (the capillary wave spectrum) has been analyzed. In addition, the capillary wave spectrum has been calculated analytically within the Landau-de Gennes theory. The theory predicts that the interfacial fluctuations can be described in terms of a wave vector dependent interfacial tension, which is anisotropic at small wavelengths (stiff director regime) and becomes isotropic at l…

Probing Physical Properties of Confined Fluids within Individual Nanobubbles

2008

Spatially resolved electron energy-loss spectroscopy (EELS) in a scanning transmission electron microscope (STEM) has been used to investigate as fluidic phase in nanoubbles embedded in a metallic Pd90Pt10 matrix. Using the 1s->2p excitation of the He atoms, maps of the He distribution, in particular of its density an pressure in bubbles of different diameter have been realized, thus providing an indication of the involved bubble formation mechanism. However, the short-range Pauli repulsion mechanism between electrons on neighboring atoms seems insufficient to interpret minute variations of the local local measurements performed at the interface between the metal and the He bubble. Simul…