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RESEARCH PRODUCT
From magnetic to nonlinear optical switches in spin-crossover complexes
Isabelle MalfantIsabelle MalfantVincent RodriguezPascal G. LacroixPascal G. LacroixJosé Antonio Realsubject
Computational chemistryNonlinear opticsroom-temperaturetransition-metal-complexesSolid-stateNanotechnology02 engineering and technology010402 general chemistry01 natural scienceselectrical-conductivityInorganic ChemistryNonlinear opticalQuadratic equationSpin crossoverbinuclear iron(iii) complexesMagnetic componentsMoleculenlo propertiesNuclear Experimentliquid-crystalCondensed matter physicsChemistryNonlinear optics021001 nanoscience & nanotechnologySpin crossoverMaterials science0104 chemical sciences2nd-harmonic generationHigh Energy Physics::Experimentschiff-base ligandsray crystal-structure0210 nano-technologyFocus (optics)hyper-rayleigh scatteringMolecular devicesdescription
ISI Document Delivery No.: 109TF Times Cited: 0 Cited Reference Count: 173 Lacroix, Pascal G. Malfant, Isabelle Real, Jose-Antonio Rodriguez, Vincent Wiley-v c h verlag gmbh Weinheim Si; Various attempts to combine magnetic and nonlinear optical (NLO) properties in a molecule are reviewed, with a special focus on the possibility of interplay between the magnetic component and the quadratic (proportional to E-2) NLO response. This multidisciplinary research leads to the idea of spin-crossover-induced (SCO-induced) NLO switching and is evaluated at the synthetic level, with insights provided by computational chemistry. The need for nontraditional experimental setups to record NLO properties in the solid state is discussed.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2013-01-10 |