Search results for "liquid"
showing 10 items of 4351 documents
Aldicarb residues in citrus soil, leaves and fruits
1990
Aldicarb was applied to the soil of Late Valencia orange field plots. A comparative study between four analytical methods is reported, the NPD-gas chromatography method being the best choice. The work also reports the study of accumulation and persistence of aldicarb and its biologically active metabolites in the soil, leaves and fruits (rind and pulp, separately). Residue content, at the ppb level, was found in the order leaves much greater than rind greater than pulp. Carbamate was found to accumulate mainly in its oxidized forms. Residues had reached a maximum level in about 90 days after application.
ANTIPROLIFERATIVE ACTIVITY OF CITRUS JUICES AND HPLC EVALUATION OF THEIR FLAVONOID COMPOSITION
2007
The antiproliferative activity of fresh fruit juices extracted from Citrus sinensis (cv. Washington Navel and cv. Sanguinello), C. deliciosa cv. Avana, C. clementina cv. Nules, C. aurantium subsp. myrtifolia , was evaluated against K562 (human chronic myelogenous leukemia), HL-60 (human leukemia) and MCF-7 (human breast adenocarcinoma) cell lines. All the juices tested showed antiproliferative activity. Moreover, the pattern of the main flavanone compounds in the juices has been determined by HPLC analysis.
Liquid chromatography/atmospheric pressure chemical ionization-mass spectrometric analysis of benzoylurea insecticides in citrus fruits.
2000
A liquid chromatography (LC) method for the quantitative determination of three benzoylurea insecticide residues (diflubenzuron, flufenoxuron and hexaflumuron) in citrus fruits is described. Residues were successfully separated on a C18 column by methanol/water gradient elution. Detection was by negative-ion, selected-ion monitoring atmospheric pressure chemical ionization-mass spectrometry (APCI-MS); the main ions were [M - H]-, and the secondary fragment ions were [M - H - HF]-. Useful confirmatory information can thus be obtained at low extraction voltages from losses of HF. Detection limits for standard solutions were 10 fg injected and good linearity and reproducibility were obtained. …
Pesticide residues in oranges from Valencia (Spain)
2001
One hundred and fifty citrus samples from an agricultural co-operative of the Valencian Community (Spain) were analysed for pre- and post-harvest pesticide residues using high performance liquid chromatography and gas chromatography. Among the residues from post-harvest treatments, imazalil was detected in 112 (74.7%) samples at a mean level of 1.2 mg/kg, thiabendazole in 21 (14.0%) samples at a mean level of 0.47 mg/kg and carbendazim in 5 (3.3%) samples at a mean level of 1.05 mg/kg. Among the residues from pre-harvest treatment, dicofol was detected in 28 (18.7%) samples at a mean level of .28 mg/kg chlorpyriphos in 19 (12.7% samples at a mean level of 0.16 mg/kg and endosulfan in 11 (7.…
Liquid chromatographic–mass spectrometric determination of post-harvest fungicides in citrus fruits
2001
Liquid chromatography (LC)-atmospheric pressure ionisation (API)-mass spectrometry (MS) has been used to determine residues of five fungicides in oranges with a minimum sample cleanup. Atmospheric pressure chemical ionisation (APCI) and electrospray (ES) were compared and both gave similar results in terms of sensitivity and structural information. The main ions were [M+H]+ for carbendazim, imazalil, thiophanate methyl and thiabendazole, and [M+H-C4H9NHCO]+ for benomyl. Samples were extracted with sodium sulphate and ethyl acetate. Although benomyl and thiophanate methyl were transformed through the extraction procedure to carbendazim, the method showed good precision (13%) and recovery (70…
Structure Effect of Imidazolium-Based Dicationic Ionic Liquids on Claisen Rearrangement
2014
A large group of imidazolium-based dicationic ionic liquids (DILs) has been prepared in good yields. Thermal stability of all DILs has been determined. The effects of the reaction time, cation, imidazolium C2–H acidity, and anion on the Claisen rearrangement of allyl phenyl ether have been investigated. Type of anion and the presence of the acidic C2–H bond in the imidazolium moieties have proven to be essential for this reaction. The simple procedure and the possibility of avoiding the use catalysts and volatile organic solvents make this synthetic method environmentally benign and adaptable for large-scale applications.
Electrohydrodynamic instabilities and orientation of dielectric ellipsoids in low-conducting fluids.
2000
We study the dynamics of an ellipsoidal particle in a weakly conducting dielectric liquid when submitted to a dc electric field. At low field intensities, the particle long axis is aligned in the field direction. When the field strength is increased, we show that, depending on the initial orientation of the particle, there exist two stable orientations: the one with the long axis parallel to the field direction remains possible while a spinning state with the long axis perpendicular to the field appears. This last striking orientation is due to the finite Maxwell-Wagner polarization relaxation time. For sufficiently high field intensities, each state loses its stability and the particle dyn…
Réserve de propriété. Médicaments ou produits parapharmaceutiques. Conditionnement et indications permettant de les individualiser. Solutions diverses
2000
International audience; (CA Paris, 3e ch. C, 12 mai 2000, Sté OCP Repartition c/ Appourchaux ; CA Lyon, 3e ch., 5 nov. 1999, Ayanian c/ Bourely Repartition Gaspa ; Com. 15 févr. 2000, Sté C. Bernard diffusion c/ Pfister)
Clause de réserve de propriété. Choses fongibles. Revendication de biens semblables (oui). Confusion des sommes revendiquées avec d'autres valeurs du…
2000
International audience; (CA Paris, 3 avr. 1998, Me Du Buit, ès qualités et autres c/ Sté OCP Répartition SAS ; CA Paris, 12 mai 1998, Sté Cie nationale Air France c/ Girard ès qualités ; CA Paris, 26 juin 1998, Pharmacie Riffault et autres c/ SA OCP Répartition)
La Cour de cassation prend parti sur la portée de la revendication de choses fongibles
2002
International audience; (Com. 5 mars 2002, pourvoi n° P 98-17.585, arrêt n° 535 FS-P, Du Buit c/ Sté OCP Répartition SAS, D.2002.1139, obs. A. Lienhard)