Search results for "luminescence."

Technique for routine output verification of Leipzig applicators with a well chamber

2005

The H-type Leipzig applicators are accessories of the microSelectron-HDR system (Nucletron, Veenendaal, The Netherlands) for treatment of superficial malignancies. Recently, the dose rate distributions in liquid water for the whole set of applicators using both source models available for the microSelectron-HDR afterloaders have been obtained by means of the experimentally validated Monte Carlo (MC) code GEANT4. Also an output table (cGy/hU) at 3 mm depth on the applicator central axis was provided. The output verification of these applicators by the user, prior to their clinical use, present practical problems: small detectors such as thermoluminescent dosimeters or parallel-plate ionizati…

Spectroscopic properties of pure and Coumarin 153-doped thin films of sol-gel silica xerogels

1999

Abstract Thin-films doped with Coumarin 153, an important laser dye, have been prepared by the sol-gel method. Spectroscopic properties of the entrapped dye are studied by electronic absorption, diffuse reflectance, electronic excitation, emission and time-resolved emission techniques. The obtained results indicate that the entrapment of the dye results in formation of molecular aggregates having absorption and emission characteristics different from those of the monomeric dye. The blue matrix emission band (at approx. 450 nm) is relatively short-lived while the red band (at approx. 700 nm) displays a very long lifetime. Electronic excitation spectra of the sol-gel thin-films suggest that t…

Thermal and optical properties of red luminescent glass forming symmetric and non symmetric styryl-4H-pyran-4-ylidene fragment containing derivatives

2012

Abstract Dyes with amorphous structure deposited from organic solvents and having good fluorescence properties show potential for photonic device applications. Organic glass-forming symmetric and non symmetric styryl- derivatives of 2(2,6-substituted-4H-pyran-4-ylidene)-malononitrile (it has backbone of known laser dye 4-(dicyanomethylene)-2-methyl-6-[p-(dimethylamino)styryl]-4H-pyran), 2(2,6-substituted-4H-pyran-4-ylidene)-1H-indene-1,3(2H)-dione and 2(2,6-substituted-4H-pyran-4-ylidene)-pyrimidine-2,4,6(1H,3H,5H)-trione were synthesized and investigated. Glass transition temperatures higher than 110 °C were achieved. The absorption bands in dichloromethane solution cover the spectral regi…

Photophysical Properties of Charged Cyclometalated Ir(III) Complexes: A Joint Theoretical and Experimental Study

2011

The photophysical properties of a series of charged biscyclometalated [Ir(ppy)(2)(N boolean AND N)](1+) complexes, where ppyH is 2-phenylpyridine and N boolean AND N is 2,2'-bipyridine (bpy), 6-phenyl-2,2'-bipyridine (pbpy), and 6,6'-dipheny1-2,2'-bipyridine (dpbpy) for complexes 1, 2, and 3, respectively, have been investigated in detail. The photoluminescence performance in solution decreases from 1 to 3 upon attachment of phenyl groups to the ancillary ligand. The absorption spectra recorded over time suggest that complex 3 is less stable compared to complexes 1 and 2 likely due to a nucleophilic-assisted ancillary ligand-exchange reaction. To clarify this behavior, the temperature depen…

Luminescence of gamma-radiation-induced defects in alpha-quartz

2004

Optical transitions associated with gamma-radiation-induced defects in crystalline a-quartz were investigated by photoluminescence excited by both pulsed synchrotron radiation and steady-state light. After a 10 MGy gamma-dose we observed two emissions at 4.9 eV (ultraviolet band) and 2.7 eV (blue band) excitable in the range of the induced absorption band at 7.6 eV. These two luminescence bands show a different temperature dependence: the ultraviolet band becomes bright below 80 K; the blue band increases below 180 K, but drops down below 80 K. Both emissions decay in a timescale of a few ns under pulsed excitation, however the blue band could also be observed in slow recombination processe…

Band-to-Band and Band-to-Acceptor Photoluminescence Studies in InSe under Pressure

1999

We report on photoluminescence (PL) measurements under pressure on p-type N-doped InSe at 10 K and on n-type Si-doped InSe at room temperature. Low-temperature PL of N-doped InSe is dominated by a band-to-acceptor peak. From the pressure dependence of the ionization energy of the N related shallow acceptor, the pressure change of the hole effective mass is estimated through the Gerlach-Pollmann model for hydrogenic levels in uniaxial crystals and discussed in the framework of a k p model. Room temperature PL in Si-doped InSe is dominated by a band-to-band peak exhibiting a pressure shift in agreement with previous works. This PL peak has been measured up to 7 GPa and a steep reversible decr…

Back Cover: Electrical Conductivity and Strong Luminescence in Copper Iodide Double Chains with Isonicotinato Derivatives (Chem. Eur. J. 48/2015)

2015

Electroluminescence TPCs at the thermal diffusion limit

2019

Artículo escrito por un elevado número de autores, solo se referencian el que aparece en primer lugar, el nombre del grupo de colaboración, si le hubiere, y los autores pertenecientes a la UAM

Near-intrinsic energy resolution for 30-662 keV gamma rays in a high pressure xenon electroluminescent TPC

2013

We present the design, data and results from the NEXT prototype for Double Beta and Dark Matter (NEXT-DBDM) detector, a high-pressure gaseous natural xenon electroluminescent time projection chamber (TPC) that was built at the Lawrence Berkeley National Laboratory. It is a prototype of the planned NEXT-100 Xe-136 neutrino-less double beta decay (0 nu beta beta) experiment with the main objectives of demonstrating near-intrinsic energy resolution at energies up to 662 keV and of optimizing the NEXT-100 detector design and operating parameters. Energy resolutions of similar to 1% FWHM for 662 keV gamma rays were obtained at 10 and 15 atm and similar to 5% FWHM for 30 keV fluorescence xenon X-…

Preliminary application of thermoluminescence and single aliquot regeneration method for dose reconstruction in soda lime glass

2013

The research described in this paper shows that the use of the single aliquot regeneration (SAR) method for thermoluminescence (TL) measurements applied to soda lime glasses allows to carry out a retrospective dose evaluation. We have followed a fast and efficient sample preparation procedure which permits measurements without powdering and sieving processes. We have analyzed the TL signal of commercial soda lime watch glass irradiated with 6 Mega Volts (MV) LINAC photons, 10 MeV LINAC electrons and 62 MeV protons. After the initial exposure and following TL reading, the samples are successively irradiated with increasing doses of photons. Therefore, for each sample its calibration curve is…