Search results for "magnesium"
showing 10 items of 490 documents
Thalassocella blandensis gen. nov., sp. nov., a novel member of the family Cellvibrionaceae
2020
9 pages, 1 figure, 3 tables
Phosphinotripeptidic Inhibitors of Leucylaminopeptidases
2021
Phosphinate pseudopeptide are analogs of peptides containing phosphinate moiety in a place of the amide bond. Due to this, the organophosphorus fragment resembles the tetrahedral transition state of the amide bond hydrolysis. Additionally, it is also capable of coordinating metal ions, for example, zinc or magnesium ions. These two properties of phosphinate pseudopeptides make them an ideal candidate for metal-related protease inhibitors. This research investigates the influence of additional residue in the P2 position on the inhibitory properties of phosphinopeptides. The synthetic strategy is proposed, based on retrosynthetic analysis. The N-C-P bond formation in the desired compounds is …
Effect of NaCl road salt on the ionic composition of soils and Aesculus hippocastanum L. foliage and leaf damage intensity.
2021
AbstractWe investigated the accumulation of sodium chloride in roadside soils and common horse chestnut Aesculus hippocastanum L. under urban conditions to evaluate changes in soil and leaf ionic content and their relationship with foliar damage, considering the visual assessment of trees of the same health status. A total of 15 field sites were assessed in late June 2016. The analysis included soil granulometric composition, pH, electrical conductivity, and the content of Cl−, Na+, K+, Ca2+, and Mg2+ ions in soil and foliage samples. The results showed increased salinity and alkalization of roadside soils together with the decreased magnesium content. Foliage samples manifested significant…
Magnesium ions promote assembly of channel-like structures from beticolin 0, a non-peptide fungal toxin purified from Cercospora beticola.
1998
Beticolins are toxins produced by the fungus Cercospora beticola. Using beticolin 0 (B0), we have produced a strong and Mg(2+)-dependent increase in the membrane conductance of Arabidopsis protoplasts and Xenopus oocytes. In protein-free artificial bilayers, discrete deflexions of current were observed (12 pS unitary conductance in symmetrical 100 mM KCl) in the presence of B0 (approximately 10 microM) and in the presence of nominal Mg2+. Addition of 50 microM Mg2+ induced a macroscopic current which could be reversed to single channel current by chelating Mg2+ with EDTA. Both unitary and macroscopic currents were ohmic. The increase in conductance of biological membranes triggered by B0 is…
Looking for Hidden Enemies of Metabarcoding: Species Composition, Habitat and Management Can Strongly Influence DNA Extraction while Examining Grassl…
2021
Despite the raising preoccupation, the critical question of how the plant community is composed belowground still remains unresolved, particularly for the conservation priority types of vegetation. The usefulness of metabarcoding analysis of the belowground parts of the plant community is subjected to a considerable bias, that often impedes detection of all species in a sample due to insufficient DNA quality or quantity. In the presented study we have attempted to find environmental factors that determine the amount and quality of DNA extracted from total plant tissue from above- and belowground samples (1,000 and 10,000 cm2). We analyzed the influence of land use intensity, soil properties…
Effects of magnesium deprivation on development and biomineralization in the sea urchin Arbacia lixula
2019
Echinoderms have an extensive endoskeleton composed of magnesian calcite and occluded matrix proteins. As biomineralization in sea urchin larvae is sensitive to the Magnesium:Calcium ratio of seawater, we investigated the effects of magnesium deprivation on development and skeletogenesis in the sea urchin Arbacia lixula. We focused on the localization of the skeletogenic cells (primary mesenchyme cells) and the spatial expression of associated genes. Embryos reared in Mg-free seawater exhibited developmental delay from 6-h post-fertilization and at 24 h embryos showed complete lack of biomineral formation. Larvae (48–72 h) exhibited severe skeleton malformations. Fluorescent labelling revea…
Process mechanics in Friction Stir Extrusion of magnesium alloys chips through experiments and numerical simulation
2017
Abstract Friction Stir Extrusion (FSE) is a novel process designed to directly recycle machining chips. An experimental campaign was carried out on AZ31 milling chips using variations in extrusion ratio, force and tool rotation rate. The process mechanics were studied and correlated to the material flow, which was elucidated through use of a copper marker. A 3D, Lagrangian, thermo-mechanically coupled dedicated numerical model was set up and validated through temperature measurements. The combination of experimental and numerical results permitted to reconstruct the complex 3D material flow induced by tool rotation and plunge into the extrusion billet chamber.
A numerical model for Wire integrity prediction in Friction Stir Extrusion of magnesium alloys
2017
Abstract A numerical model for the prediction of the wire quality produced by the novel direct machining chip recycling technique known as Friction Stir Extrusion (FSE) is presented. Wire microstructure and wire integrity have been predicted by embedding in the code the equations enabling the calculation of the Zener-Hollomon parameter as well as the W parameter of the Pivnik-Plata solid bonding criterion. The proposed model, developed for the AZ31 magnesium alloy using the commercial simulation package DEFORM, is 3D Lagrangian, thermo-mechanically coupled with visco-plastic material behavior. The model was first validated against experimental temperature measurements and then used to predi…
In-process control strategies for friction stir welding of AZ31 sheets with non-uniform thickness
2017
Two different in-process control strategies were developed and compared with the aim to produce AZ31 magnesium alloy joints by friction stir welding on sheet blanks with a non-uniform thickness. To this purpose, sheets with dip or hump zones were welded by either changing the rotational speed or the tool plunging in order to keep constant the value of the vertical force occurring during the welding stage of the process. The influence of the main process parameters on the tool force, the micro- and macromechanical properties, and the joints microstructures in the dip and hump zones were analyzed. The results showed that using the rotational speed change-based approach, the hump zones are sub…
Influence of Process Parameters on the Product Integrity in Friction Stir Extrusion of Magnesium Alloys
2016
Friction Stir Extrusion is an innovative direct-recycling technology for metal machining chips. During the process a specifically designed rotating tool is plunged into a cylindrical matrix containing the scraps to be recycled. The stirring action of the tool prompts solid bonding related phenomena allowing the back extrusion of a full dense rod. This process results to be particularly relevant because allows the reuse of the scrap without any previous treatment. Experiments have been carried out in order to investigate the influence of the process parameters on the extrudes quality and a numerical model has been developed in order to simulate the evolution of the material flow.